• Korean Journal of Food Science and Technology
• /
• v.42 no.4
• /
• pp.414-419
• /
• 2010

Hyphenated-HPLC techniques combine the separation power of HPLC with the structural and bioactivity information provided by NMR, ESI/MS, and an on-line antioxidant screening system. The major advantages over the traditional off-line techniques are rapidity and efficiency. In this study, we used hyphenated HPLC techniques including online HPLC-ABTS, LC-NMR, and LC-MS todirectly identify the major antioxidants of safflower (Carthamus tinctorius L.) seeds. The results demonstrated that the major antioxidant compounds from on-line HPLC-ABTS analysis were identified as 8'-hydroxyarcgenin-4'-O-$\beta$-D-glucoside, N-(p-coumaroyl) serotonin, and N-feruloylserotonin. Among them, N-feruloylserotonin accounted for almost 50% of the ABTS radical scavenging activity of the total extract. The results demonstrate that HPLC hyphenated techniques can be used to rapidly screen and structurally identify antioxidants from crude plant extracts.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.29 no.1
• /
• pp.73-83
• /
• 1997

Most of the materials used in various industrial fields and also in our daily life are multi-component materials or composite materials, and it is well known that there are many cases where adhesion between the constituents within the bonded systems plays an important role. There are various types of performance evaluation tests for the bonded materials, among which tests for evaluating the bond performance under various conditions may be regarded as the most interesting ones for those engaged in work related to adhesion. I have studied on the mechanism of adhesion form the rheological standpoint with my colleagues, including some students from Korea, and I am very happy to be able to have a talk on some of our research works. In Japan, the so-called "adhesives" are usually classified into two categories;adhesives and pressure sensitive adhesives (PSA). Adhesives are the materials which solidify after bonding and are after used as the structural adhesives because the adhesive strength is comparatively strong. On the other hand, the pressure sensitive adhesives never solidify and are used as PSA tapes, labels or decals. About the adhesives, we have examined the dependence of adhesive strength(shear, tensile, peel) upon both temperature and rate of deformation, and found out some empirical rules which are applicable to most of the adhesive systems. We have also developed a simplified theory of adhesion, which is deseribed in terms of mechanical equivalent mode1 and a few failure criteria. Although some of the common rules can be accounted for according to this theory, it must be pointed out that a fracture mechanical approach ms inevitable especially in the region where the meehanical relaxation time of the adhesive is extremely large [W. W. Lim and H. Mizumachi]. About the pressure sensitive adhesives, we have studied on the PSA performance (peel, tack, holding power) as a function of both the viscoelastic properties and surface chemical properties of the materials, and found out some rules, and again we have developed a theory which deseribes the mechanism. And in addition, we have studied on the miscibility between linear polymers and oligomers, because PSA is generally manufactured by blending gums and tackifier resins. Many phase diagrams have been found and some of them have been analyzed on thermodynamic basis, and it became evident that the miscibility is a very important factor in PSA [H. J. Kin and H. Mizumachi]. In this presentation, I want to emphasize the fact that the adhesion performance is closely related to the structure/property of the adhesives.adhesives.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.43 no.8
• /
• pp.699-705
• /
• 2015

Aircraft needs high lift-to-drag ratio and weight reduction of the structure for long endurance flight with a small power. Generally high aspect ratio wing is applied to HALE(High Altitude Long Endurance) aircraft. Also high modulus, and high strength CFRP(Carbon Fiber Reinforced Plastic) has been used in primary structures. and thin mylar(membrane material) film has been applied to skin of wing. As a result, wing is more flexible than the other structures. and the stiffness of thin mylar film has an affect on dynamic stability. In this study, the membrane characteristic of mylar film has been simulated using nonlinear gap elements. And equivalent modeling method using shell elements is presented using the nonlinear simulation result. The linear equivalent model has verified using the results of nonlinear membrane method. Proposed linear equivalent shell model has applied to mode analysis for estimate the effect of mylar mechanical properties on natural frequency.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.32 no.5
• /
• pp.285-295
• /
• 2020

In the case of small observation towers located at sea, it is necessary to confirm the change in dynamic characteristics due to the influence of environmental loads. In this study, the dynamic characteristics were analyzed and the numerical analysis model was designed through field dynamic response measurement on the Mangyeong Offshore Observation Tower (Mangyeong Tower) located near the Saemangeum Embankment. As a result of the measurement, the natural frequency was found to increase slowly as the tide level is lowered. In addition, it was confirmed that the same mode has two frequencies, which was judged to be a phenomenon in which the natural frequency was partially increased when the pile and the ground contacted by scouring. For numerical analysis, the upper mass, artificial fixity point, scour depth and fluid influences are reflected in the structural characteristics of the Mangyeong Tower. In addition, the model updating from the estimated natural frequency and pattern search algorithm was performed. From the model updating, it is expected that it can be applied to future studies on stability of Mangyeong Tower.

• Journal of the Korean Geographical Society
• /
• v.42 no.1 s.118
• /
• pp.41-62
• /
• 2007

This paper aims to interpret the changes of the regional inequality between Seoul Metropolitan Area(SMA) and Non-SMA after 1981 on the regulationist approaches that examine institution changes and power dynamics that motivate regional disparities in South Korea. Despite the restrict laws and aims that alms to reduce the concentration into SMA before 1988, the acts were not executed effectively due to the structural selectivity of the bureaucratic authoritarian state of those years. Thus, the regional concentration phenomena of SMA was intensified in the 1980s. However, the democratization in 1987 invoked Non-SMA regions to claim their regional development and it also forced the state to mediate the conflicting interests between the regional agents protesting the SMA concentration and the Capital agents supporting the SMA deregulation. From the early 1990s. the state launched a series of national strategies and policies to diminish regional inequality. They included execution of the existing acts mitigating SMA concentration and construction of industrial complexes in the underdeveloped areas of Non-SMA. Thus, the equalizing polities led the reduction of the concentration of SMA from 1989 to 1997. However, the financial crisis of Korea in 1997 intensified the claims of the Capital agents to deregulate the SMA control. The circumstance also forced the state towards the Capital side that request the deregulation of SMA control. As the result, the regional disparity between SMA and Non-SMA has been enlarged again since 1998.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.34 no.6
• /
• pp.713-719
• /
• 2001

The aim of this study is to check the application criteria of the conventional techniques and clarify the effects of breaker depth, seabed conditions on the stability in relation to the effects of uncertainty of storm duration and directional irregular waves. The typical damage modes were divided by the direct wave force on the armor unit and by the local scouring around the toe of a breakwater head by the model experiments. The destruction modes are defined, and some criteria on the damage modes and scouring/deposition at the toe of a breakwater head in relating the wave-bottom-structural conditions can be checked using the multi-directonal irregular wave generator system. According to the results, it is emphasized that the 3-D effects on the stability should be analyzed in the design of multi-purpose/function coastal structures in consideration of the evaluation of spatial variation of damage modes and hydraulic characteristics as well as the wave distribution along the structures.

• Structural Engineering and Mechanics
• /
• v.31 no.2
• /
• pp.181-210
• /
• 2009

This paper presents the theoretical developments of an exact finite strip for the buckling and initial post-buckling analyses of isotropic flat plates. The so-called exact finite strip is assumed to be simply supported out-of-plane at the loaded ends. The strip is developed based on the concept that it is effectively a plate. The present method, which is designated by the name Full-analytical Finite Strip Method in this paper, provides an efficient and extremely accurate buckling solution. In the development process, the Von-Karman's equilibrium equation is solved exactly to obtain the buckling loads and the corresponding form of out-of-plane buckling deflection modes. The investigation of thin flat plate buckling behavior is then extended to an initial post-buckling study with the assumption that the deflected form immediately after the buckling is the same as that obtained for the buckling. It is noted that in the present method, only one of the calculated out-of-plane buckling deflection modes, corresponding to the lowest buckling load, i.e., the first mode is used for the initial post-buckling study. Thus, the postbuckling study is effectively a single-term analysis, which is attempted by utilizing the so-called semi-energy method. In this method, the Von-Karman's compatibility equation governing the behavior of isotropic flat plates is used together with a consideration of the total strain energy of the plate. Through the solution of the compatibility equation, the in-plane displacement functions which are themselves related to the Airy stress function are developed in terms of the unknown coefficient in the assumed out-of-plane deflection function. These in-plane and out-of-plane deflected functions are then substituted in the total strain energy expressions and the theorem of minimum total potential energy is applied to solve for the unknown coefficient. The developed method is subsequently applied to analyze the initial postbuckling behavior of some representative thin flat plates for which the results are also obtained through the application of a semi-analytical finite strip method. Through the comparison of the results and the appropriate discussion, the knowledge of the level of capability of the developed method is significantly promoted.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.12 no.5
• /
• pp.47-56
• /
• 2008

This study was performed to evaluate the effect of Response modification factors (R-factor) in 3-, 9- and 20- story steel Moment Resisting Frame (MRF) buildings. Each structure was designed using a R-factor of 8, as tabulated in the 2000 International Building Code provision (IBC 2000) and Korea Building Code (KBC) 2008. In order to evaluate the maximum and minimum performance expected for such structures, an upper bound and lower bound design were adopted for each model. Next, each analytical model was designed using different R-factors (8, 9, 10, 11, 12) and four different structural periods with the original fundamental period. For a detailed case study, a total of 150 analytical models were subjected to 20 ground motions representing a hazard level with a 2% probability of being exceeded in 50 years. In order to evaluate the performance of the structures, static push-over and non-linear time history analysis (NTHA) were performed, and displacement ductility demand was investigated to consider the ductility capacity of the structures. The results show that the dynamic behaviors for the 3- and 9-story buildings are relatively stable and conservative, while the 20-story buildings show a large displacement ductility demand due to dynamic instability factors. (e.g. P-delta effect and high mode effect)

• Journal of the Earthquake Engineering Society of Korea
• /
• v.12 no.5
• /
• pp.11-21
• /
• 2008

In recent years, time history analysis has been the method generally used for the seismic analysis of tall buildings with damping devices. When T is the natural period of the first vibration mode of the structure, the sum of the spectral acceleration of the earthquake ground motion is usually adjusted to that of the design response spectrum in the period ranging from 0.2T to 1.5T to meet the requirements of design code. However, when the ground motion is scaled according to the design code, the differences in the responses obtained by response spectrum analysis (RSA) and time history analysis (THA) of the structures increase as the natural period of the structure becomes longer. When time history analysis is performed by using ground accelerations that are scaled according to the design code, base shear is similar to that obtained from RSA, but other responses, such as displacements, drifts and member forces, are underestimated compared to RSA. If these results are adjusted by multiplying with the scale-up factor, the scaled responses become much smaller. Therefore, a scaling method of ground motions corresponding with the design code is proposed in this study, as a way of assisting structural engineers in generating artificial ground motions.

• Applied Biological Chemistry
• /
• v.7
• /
• pp.1-13
• /
• 1966

1) Three ${\beta}-1$, 4-mannanases were isolated from germinated guar bean through extraction, ammonium sulfate fractionation, column chromatography on cellulose derivatives and gel filltration on Sephadex G-100. They were designated as ${\beta}-1$, 4-mannanase A,B and C, respectively, in the order of isolation. 2) These enzymes were different in several aspects such as pH optimum, effect of metal ions, adsorbability on cellulose derivatives, molecular weight, Michaelis constant toward reduced ivory nut mannan A, mode of action and extent of hydrolysis of the mannan. 3) ${\beta}-1$, 4-Mannanases A and C were proposed to be two different endo-enzymes of random-splitting type producing a series of oligosaccharides from ${\beta}-1$, 4-mannans. ${\beta}-1$, 4-Mannanase B was suggested to be possibly an exe-type enzyme catalyzing a stepwise splitting from the non-reducing end of ${\beta}-1$, 4-mannans to produce mannose. 4) Guaran was subjected to hydrolysis by the purified enzymes and the consequence was discussed in connection with structural requirements of the enzymes toward substituted ${\beta}-1$, 4-mannans and their role in germinating guar seeds.