• Analytical Science and Technology
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• v.12 no.5
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• pp.421-427
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• 1999

Two shapes of crystals have been isolated by the interdiffusion of $Co(NCS)_2$ dissolved in methanol with 1,2-bis(2,2'-bipyridyl-6-yl)ethane (bbpe) dissolved in chloroform. The two crystals have been elucidated as $trans-Co^{II}(NCS)_2(bbpe)$ and $trans-Co^{II}(NCS)_2(bbpe){\cdot}2CHCl_3$, by X-ray crystallography, elemental analysis, IR, and thermal analysis. The two molecular structures are very similar except for the absence or presence of chloroform solvate molecules. The bbpe ligand coordinates to the cobalt(II) ion in an open-ended tetradentate mode, resulting in discrete mononuclear cobalt(II) complex. The cobalt atom adopts a typical octahedral arrangement with six nitrogen donating atoms with two NCS groups in trans positions. A significant solid-to-solid phase transition occurs presumably due to the change of conformationally flexible bbpe ligand. The formation of both crystals oeeurs in a successive two-step process, the formation of $trans-Co^{II}(NCS)_2(bbpe)$ and its transformation into $trans-Co^{II}(NCS)_2(bbpe){\cdot}2CHCl_3$. The thermal stability and favorable formation of the solvate crystals may be ascribed to the interaction between S atom of NCS group and Cl of chloroform.

• Geomechanics and Engineering
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• v.15 no.5
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• pp.1113-1124
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• 2018

Geological dynamic hazards during deep coal mining are caused by the failure of a composite system consisting of the rock and coal layers, whereas the joint in coal affects the stability of the composite system. In this paper, the compression test simulations for the rock-coal combined body with single joint in coal were conducted using $PFC^{2D}$ software and especially the effects of joint length and joint angle on strength and failure characteristics in a rock-coal combined body were analyzed. The joint length and joint angle exhibit a deterioration effect on the strength and affect the failure modes. The deterioration effect of joint length of L on the strength can be neglected with a tiny variation at ${\alpha}$ of $0^{\circ}$ or $90^{\circ}$ between the loading direction and joint direction. While, the deterioration effect of L on strength are relatively large at ${\alpha}$ between $30^{\circ}$ and $60^{\circ}$. And the peak stress and peak strain decrease with the increase of L. Additionally, the deterioration effect of ${\alpha}$ on the strength becomes larger with the increase of L. With the increase of ${\alpha}$, the peak stress and peak strain first decrease and then increase, presenting "V-shaped" curves. And the peak stress and peak strain at ${\alpha}$ of $45^{\circ}$ are the smallest. Moreover, the failure mainly occurs within the coal and no apparent failure is observed for rock. At ${\alpha}$ between $30^{\circ}$ and $60^{\circ}$, the secondary shear cracks generated in or close to the joint tips, cause the structural instability failure of the combined body. Therefore, their failure models present as a shear failure along partial joint plane direction and partially cutting across the coal body or a shear failure along the joint plane direction. However, at ${\alpha}$ of $60^{\circ}$ and L of 10 mm, the "V-shaped" shear cracks cutting across the coal body cause its final failure. While crack nucleations at ${\alpha}$ of $0^{\circ}$ or $90^{\circ}$ are randomly distributed in the coal, the failure mode shows a V-shaped shear failure cutting across the coal body.

• Journal of Oral Medicine and Pain
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• v.24 no.4
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• pp.397-410
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• 1999

In order to obtain the basic data concerning the optimal parameters in using Nd:YAG laser as a therapeutic modality to dentinal hypersensitivity, the author prepared 3 sections of sound dentin and 10 sections of sclerotic dentin with thickness of $0.5mm{\pm}0.1mm$ from human extracted teeth of anteriors and premolars, and applied the laser energy from a fiberoptic delivered, free running, pulsed Nd:YAG laser (wavelength 1064nm, pulse duration $120{\mu}sec$, fiber diameter $320{\mu}m$) to surfaces of sound and sclerotic dentin sections for 1 second with contact/unidirectional moving mode of the fiber under speed of 3mm~4mm/sec and parameters of 0.5W/10Hz, 1.0W/10Hz, 1.5W/10Hz, 2.0W/10Hz: $62J/cm^2$, $124J/cm^2$, $187J/cm^2$, $249J/cm^2$. The author comparatively evaluated the characteristics of ultrastructural changes on surfaces of sound and sclerotic dentin sections irradiated by the pulsed Nd:YAG laser using the scanning electron microscopy. A fairly ill-defined bordered surface of partially closed and melted dentinal tubules can be seen on the scanning electron microscopic feature of the sound dentin surface irradiated by the pulsed Nd:YAG laser with energy density of $62J/cm^2$. The physical modification of sound dentin surface extensively occurred depended on the increase of energy density from $62J/cm^2$ to $124J/cm^2$, $187J/cm^2$, $249J/cm^2$. While, a fairly well-defined bordered surface of partially closed and melted dentinal tubules with thickened peritubular dentin can be seen on the scanning electron microscopic feature of the sclerotic dentin surface irradiated by the pulsed Nd:YAG laser with energy density of $62J/cm^2$. The physical modification of sclerotic dentin surface of a fairly rough, shallow depression with many cracks, thickened peritubular dentin and structureless dentinal tubules extensively occurred depended on the increase of energy density from $62J/cm^2$ to $124J/cm^2$, $187J/cm^2$, $249J/cm^2$ compared to those of sound dentin surface irradiated by the pulsed Nd:YAG laser under the same parameters. Therefore, it is recommended that the pulsed Nd:YAG laser as a therapeutic modality to dentinal hypersensitivity should be applied with the less energy density than $62J/cm^2$ on the sound dentin surface, and its energy density on the partially sclerotic dentin surface should be lower than that on the sound dentin surface to preserve tooth from unnecessary excessive structural destruction.

• Journal of the Korea Institute of Building Construction
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• v.16 no.3
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• pp.237-245
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• 2016

Structural performance and durability of ultra high performance concrete could demonstrate optimal performance when unity was kept. Accordingly, it is necessary to involve the characteristics and quantitative surface treatment at the same time in order to retain oneness of Ultra-High-Performance Concrete(UHPC) according to construction joint occurrence. Therefore, this study derives a reasonable surface treatment method in a material's point of view through the shear adhesion performance evaluation according to the construction joints surface processing method as a part for securing the adhesion performance of the construction joints when casting UHPC. 180 MPa of required average strength was used for mix of UHPC and surface treatment method was set to totally 7 level that MN, GR-10-0, GR-20-0, GR-30-0, SH-30-5, SH-30-10. After the specimen were manufactured to a size of $150{\times}150{\times}150mm$, Direct shear test was performed to evaluate the shear adhesion strength. As a result, it was confirmed that the adhesion performance was improved when executing a surface treatment for the construction joint interface and standard of failure mode of specimen was over Type C. Also, It was considered that interface of cross section and depth of concavo-convex should be concerned.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.11
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• pp.1265-1272
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• 2014

This study performed the progressive failure analysis of adhesive joints of a composite pressure vessel with a separated dome by using a cohesive zone model. In order to determine the input parameters of a cohesive element for numerical analysis, the interlaminar fracture toughness values in modes I and II and in the mixed mode for the adhesive joints of the composite pressure vessel were obtained by a material test. All specimens were manufactured by the filament winding method. A mechanical test was performed on adhesively bonded double-lap joints to determine the shear strength of the adhesive joints and verify the reliability of the cohesive zone model for progressive failure analysis. The test results showed that the shear strength of the adhesive joints was 32MPa; the experiment and analysis results had an error of about 4.4%, indicating their relatively good agreement. The progressive failure analysis of a composite pressure vessel with an adhesively bonded dome performed using the cohesive zone model showed that only 5.8% of the total adhesive length was debonded and this debonded length did not affect the structural integrity of the vessel.

• Journal of Korean Society of Steel Construction
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• v.21 no.5
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• pp.451-459
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• 2009

The purpose of this study was to evaluate the in-plane bending moment for T-joints made of cold-formed square hollow steel sections. In the previous studies, the T-joint was shown not to have an obvious peak load, and the failure mode was the main chord flange failure at the branch-width-to-chord-width ratio ($\beta$) of below 0.71. Based on the experimental results, including the tests conducted by Zhao, the deformation limit of 1% B was proposed for ${16.7{\leq}2{\gamma}(=B/T){\leq}33}$ and ${0.34{\leq}{\beta}(=b_{1}/B){\leq}0.71}$. Then, the ultimate in-plane bending strength was shown to be Mu=1.5${\cdot}$M1% B. The existing strength formulae for the original T-joint were investigated and were determined to be the main chord flange failure for the branch-squared T-joint. The bending strength formulae of CIDECT and other researchers were compared with the test results. Finally, a reasonably good agreement with Zhao's formula was found. Therefore, the design guidelines were presented based on Zhao's strength formula for T-joints.

• Journal of Korean Society of Steel Construction
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• v.26 no.6
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• pp.523-535
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• 2014

According to the capacity design concept underlying current steel seimsic provisions, the braces in concentrically braced frames should dissipate seismic energy through cyclic tension yielding and compression buckling. On the other hand, the beams and the columns in the braced bay should remain elastic for gravity load actions and additional column axial forces resulting from the brace buckling and yielding. However, due to the difficulty in accumulating the yielding and buckling-induced column forces from different stories, empirical and often conservative approaches have been used in design practice. Recently a totally different approach was proposed by Cho, Lee, and Kim (2011) for the prediction of column axial forces in inverted V-braced frames by explicitly considering brace buckling. The idea proposed in their study is extended to X-braced seismic frames which have structural member configurations and load transfer mechanism different from those of inverted V-braced frames. Especially, a more efficient rule is proposed in combining multi-mode effects on the column axial forces by using the modal-mass based weighting factor. The four methods proposed in this study are evaluated based on extensive inelastic dynamic analysis results.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.269-280
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• 1998

Recently, application of composite materials such as fiber reinforced concretes(FRCs) and fiber reinforced plastics(FRPs) in conjunction with conventional structural components has become one of the main research areas. A proper use of advanced composite materials requires understanding their resistance mechanism and failure mode when they are applied to structures or their components. Particular considerations are given in this research to develop an analytical model which can predict the nonlinear flexural responses of bonded and unbonded prestressed concrete beams possibly having layers of different cementitious composite matrices in a section and/or FRP tendons. The block concept is used, which can be regarded as an intermediate modeling method between the couple method with one block and the layered method with multiply sliced layers in a section. In order to find a particular deflection point of a beam under load, solutions to the 2N-variables are found numerically by using approximate N-force equilibrium equations and N-moment equilibirum equations. The model is shown to successfully predict the flexual behavior of variously reinforced bonded and unbonded prestressed concrete beams. The model is also successful in simulating a gradually increasing load after sudden drop inload resistance due to fracture of one or more FRP tendons. This feature is useful in tracing the overall load-deflection response of a beam prestressed with brittle FRP tendons.

• Journal of Korean Society of Steel Construction
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• v.29 no.6
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• pp.411-422
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• 2017

In this study, to investigate the seismic performance of beam-column joints using concrete-encased and -filled circular steel tube(CEFT) columns, two types of tests were performed: (1) column - flange tension test and (2) beam - column joint cyclic load test. In column - flange tension test, test parameters were concrete encasement and connection details: flange width and strengthening rebar. Five specimens were tested to investigate the load-carrying capacity and the failure mode. Test results showed that increase of flange width from 200mm to 350mm result in increase of connection strength and stiffness by 61% and 56%, respectively. Structural performances were further improved with addition of tensile rebars by 35% and 92%, respectively. In cyclic loading test, three exterior beam-column joints were prepared. Test parameters were strengthening details including additional tensile rebars, thickened steel tube, and vertical plate connection. In all joint specimens, flexural yielding of beam was occurred with limited damages in the connection regions. In particular, flexural capacity of beam-column joint was increased due to additional load transfer through tube - beam web connection. Also, connection details such as increase of tube thickness and using vertical plate connection were effective in improving the resistance of panel zone.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.334-334
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• 2013

In the past decade, the infrared detectors based on intersubband transition in quantum dots (QDs) have attracted much attention due to lower dark currents and increased lifetimes, which are in turn due a three-dimensional confinement and a reduction of scattering, respectively. In parallel, focal plane array development for infrared imaging has proceeded from the first to third generations (linear arrays, 2D arrays for staring systems, and large format with enhanced capabilities, respectively). For a step further towards the next generation of FPAs, it is envisioned that a two-dimensional metal hole array (2D-MHA) structures will improve the FPA structure by enhancing the coupling to photodetectors via local field engineering, and will enable wavelength filtering. In regard to the improved performance at certain wavelengths, it is worth pointing out the structural difference between previous 2D-MHA integrated front-illuminated single pixel devices and back-illuminated devices. Apart from the pixel linear dimension, it is a distinct difference that there is a metal cladding (composed of a number of metals for ohmic contact and the read-out integrated circuit hybridization) in the FPA between the heavily doped gallium arsenide used as the contact layer and the ROIC; on the contrary, the front-illuminated single pixel device consists of two heavily doped contact layers separated by the QD-absorber on a semi-infinite GaAs substrate. This paper is focused on analyzing the impact of a two dimensional metal hole array structure integrated to the back-illuminated quantum dots-in-a-well (DWELL) infrared photodetectors. The metal hole array consisting of subwavelength-circular holes penetrating gold layer (2DAu-CHA) provides the enhanced responsivity of DWELL infrared photodetector at certain wavelengths. The performance of 2D-Au-CHA is investigated by calculating the absorption of active layer in the DWELL structure using a finite integration technique. Simulation results show the enhanced electric fields (thereby increasing the absorption in the active layer) resulting from a surface plasmon, a guided mode, and Fabry-Perot resonances. Simulation method accomplished in this paper provides a generalized approach to optimize the design of any type of couplers integrated to infrared photodetectors.