• 제목/요약/키워드: Strong acids

검색결과 309건 처리시간 0.033초

Composite Nanofilm of Polypyrrole and Mycosporine-like Amino Acids for UV sensor

  • Jin, Yinhua;Kulkarni, Atul;Qin, Hongyi;Kim, Dae-hwan;Yu, Yeong Wook;Lee, Joon Chul;Kim, Taesung;Moh, Sang Hun
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
    • /
    • pp.354.2-354.2
    • /
    • 2016
  • Mycosporine-like amino acids (MAAs) are small secondary metabolites produced by organisms that live in environments with high volumes of sunlight, is an important group of novel bioactive compounds having immense biotechnological poten-tials due to their UV screening properties and Polypyrrole (PPy) is a type of organic polymer formed by polymerization of pyrrole. A novel composite nanofilm (~60 nm) of mycosporine-like amino acid (MAA) and polypyrrole is synthesized by interfacial polymerization technique. This composite nanofilm is conductive and has strong photoresponse. A photoelectric UV sensor is fabricated by depositing the composite film onto a silicon chip. This UV sensor shows good sensitivity, selectivity and stability for UV detection.

  • PDF

Porphyromonas gingivalis의 독성, 대사산물 및 유전자이종성과의 관련성 (RELATIONSHIP BETWEEN VIRULENCE, METABOLIC ACID AND GENETIC HETEROGENEITY OF PORPHYROMONAS GINGIVALIS)

  • 김강주;정종평
    • Journal of Periodontal and Implant Science
    • /
    • 제23권1호
    • /
    • pp.1-15
    • /
    • 1993
  • P. gingivalis has been implicated as a strong pathogen in periodontal disease and known to have three serotypes of P. gingivalis. The purpose of this study is to investigate on the relationship between virulence, metabolic acids and genetic heterogeneity of P. gingivalis. P. gingivalis W50 standard strain and five strains of P. gingivalis serotype b Korean isolates were used in this study. For in vitro virulence test, lyophilized whole cell P. gingivalis were suspended, and sonicated with ultrasonic dismembranometer. Sonicated samples were applied to cultured cells derived from periodontal ligament, and cell activity was assayed with growth and survival assay. The metabolic acids were also extracted, and determined by High Performance Liquid Chromatography. Pst I-digested bacterial genomic DNA was electrophoresed, and densitometric analysis was performed to study the genetic heterogeneity. All of the P. gingivalis serotype b produced butyric acid. In cell activity study, butyric acid inhibited the cell activity irrespective of its concentration. Densitometric analysis showed restriction fragment length polymorphism. These results suggested that there existed heterogeneity of the metabolic acids and the virulence of P. gingivalis and such heterogeneity might be related to genetic heterogeneity.

  • PDF

Amino 산-Xylose 갈변반응 물질의 항산화성 2. TLC와 투석을 이용한 항산화성 갈변물질의 분리 (Antioxidant Activity of Amino Acid-Xylose Browning Reaction Products 2. Isolation of Antioxigenic Substrates from Browning Reaction Products by TLC and Dialysis)

  • 유병진;이강호;이종호
    • 한국수산과학회지
    • /
    • 제19권3호
    • /
    • pp.212-218
    • /
    • 1986
  • In order to isolate antioxigenic substrates, the browning reaction products of xylose and various amino acids were analysed by TLC and dialysis. Rf values of browning reaction products of xylose and hydrophobic amino acids separated on silica gel TLC plate were shown in the range of 0.38 to 0.56 and that of basic amino acids was around 0.2. Browning reaction products made from xylose and Trp were separated on TLC into four bands with Rf values of 0.25, 0.55, 0.81 and 0.91 respectively. Among these the bands with Rf values of 0.25 and 0.55 appeared having strong antioxidant activity. The band of Rf 0.55 which showed the highest activity was positive to Prochazka reagent and had an absorption maximum at 275 nm. In dialysis of the xylose-Trp browning reaction products, the undialysed fraction (inner solution) was repsponsible to the antioxidant activity, which was separated into two bands with Rf values of 0.25 and 0.55 on TLC. The inner fractions of the browning products of xylose and His or Arg were also apparent in antioxdant activity.

  • PDF

Inhibition of Compylobacter jejuni in Chicken by Ethanol, Hydrogen Peroxide, and Organic Acids

  • Shin, Soon-Young;Hwang, Han-Joon;Kim, Wang-June
    • Journal of Microbiology and Biotechnology
    • /
    • 제11권3호
    • /
    • pp.418-422
    • /
    • 2001
  • Growth inhibition of Compylobacter jejuni ATCC 33291 was observed in the presence of various preservatives at various temperatures. The addition of ethanol (0.5% to 5%), hydrogen peroxide (0.05%), acetic acid (1%), propionic acid, benzoic acid, and sorbic acid showed strong antibacterial activities against C. jejuni at pH 5.5 or 6.5. The addition of 1% acetic acid and lactic acid were most effective at $42{\circ}C, followed by $25{\circ}C$ and $4{\circ}C$. This indicated that the inhibitory effect was temperature dependent. In the chicken model system, the practical death rate of C. jejuni in the FBP-media with 1% acetic temperatures ($4{\circ}$C$, $25{\circ}$C, and $42{\circ}$). Therefore, precaution has to be taken in the use of organic acids as a disinfectant in the chicken slaughterhouse.

  • PDF

Mechanism and regulation of body malodor generation (1) -Effect of iron in axillary malodor and using an antioxidant as a deodorant-

  • Ichinose, N.;lida, S.;Gomi, T.;Someya, K.;Hirano, K.;Ogura, M.;Yamazaki, S.;Sakurai, K.
    • 대한화장품학회:학술대회논문집
    • /
    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
    • /
    • pp.139-144
    • /
    • 2003
  • Using GC/MS and GC/Olfactmetry analysis, we identified two vinyl ketones such as 1-Octen-3-one (OEO) and cis-1, 5-Octadien-3-one (ODO) as key materials in axillary odor. OEO and ODO showed a strong metallic odor and low odor threshold. These two materials were occurred from the reaction of unsaturated long fatty acids in lipids and the iron ion in our body's metabolism. Then, it was recognized that Morus alba (Japanese name, Kuwa) extract, one of the plant extract, showed a very good effect to control the generation of these vinyl ketones due to its remarkable anti-oxidization effects.

  • PDF

강산성 유해화학물질의 법적관리 수준 및 GHS 분류정보 제공 실태분석 연구 (Analysis on the Legal Control Levels and GHS Classification Information Status for Strongly Acidic Hazardous Materials)

  • 이권섭;조지훈;박진우;송세욱
    • 한국산업보건학회지
    • /
    • 제23권4호
    • /
    • pp.384-392
    • /
    • 2013
  • Objective: This study inspected incident cases, legal control levels, and GHS(Globally Harmonized System of Classification and Labeling of Chemicals) classification results of strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid, which have been responsible for many recent chemical accidents. As a result, it is deemed necessary for legal control levels of these strong acids to be revised and GHS classification be managed nation-wide. Methods: This study inspected incident cases and legal control levels for strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid. The study analyzed and compared chemical information status and GHS classification results. Results: There were 76 domestic incidents involving strongly acidic hazardous materials over the five years between 2007 and 2011. They include 37 leakage incidents(46.7%) within a workplace, 30 leakage incidents(39.5%) during transportation, and nine leakage incidents(13.8%) following an explosion. The strongly acidic materials in question are defined and controlled as toxic chemicals according to the classes of Substances Requiring Preparation for Accidents, Managed Hazardous Substance, Hazardous Chemical(corrosive) as set forth under the Enforcement Decree of the Toxic Chemicals Control Act and Rules on Occupational Safety and Health Standards of Occupational Safety and Health Act. Among them, nitric acid is solely controlled as a class 6 hazardous material, oxidizing liquid, under the Hazardous Chemicals Control Act. The classification results of the EU ECHA(European Chemicals Agency) CLP(Commission Regulation(EC) No. 790/2009 of 10 August 2009, for the purposes of its adaptation to technical and scientific progress, Regulation(EC) No 1272/2008 of the European Parliament and of the Council on classification, labeling and packaging of substances and mixtures) and NIER (National Institute of Environmental Research) are almost identical for the three chemicals, with the exception of sulfuric acid. Much of the classification information of NITE (National Institute of Technology and Evaluation) and KOSHA(Korea Occupational Safety and Health Agency, KOSHA) is the same. NIER provides 12(41.4%) out of 29 classifications, as does KOSHA.

A cDNA Clone for the 5' Exon of Chloroplast ATP Synthase Subunit I Gene (atpF) from Broccoli (Brassica oleracea L. var. Italica) and Its Expression Pattern

  • Choo Bong Hong
    • Journal of Plant Biology
    • /
    • 제38권2호
    • /
    • pp.137-141
    • /
    • 1995
  • We isolated a cDNA clone, BLSC1, encoding 5' exon of ATP synthase CF0 subunit I from broccoli. BLSC1 is 285 nucleotides long which consists of a 5' noncoding region of 34 nucleotides, a 5' exon of 145 nucleotides and an intron of 106 nucleotides. The 5' exon codes for 48 amino acids which reveals mostly hydrophobic. The amino acid sequence deduced from BLSC1 shares 83%, 83% and 91% identities with the genes coding for atpF from wheat, rice and spinach, respectively. Genomic Southern blot analysis for BLSC1 showed a typically strong signal for a gene located in the chloroplast genome. Northern blot analysis identified three major classes of transcripts showing strong positive signals in the leaves, but only trace amounts of the transcripts were identified in the other organs like stems, flowr buds and roots.

  • PDF

대칭적 Triazine 유도체들에 대한 젤라틴 유제층의 경막 시험에 관한 연구 (Studies on the Hardening Test of Gelatin Emulsion Layers by Derivatives of Symmetrical Triazine)

  • 김영찬
    • 정보학연구
    • /
    • 제9권1호
    • /
    • pp.1-7
    • /
    • 2006
  • In this paper, we describe a study on the relationship between photographic emulsion manufacture and hardening test of films. The hardeners were prepared by condensation of equimolar amounts of trichlorotriazine with benzene- or naphthalene-based amino or oxy acids at 0 to 5$^{\circ}C$ and at pH 7, and used as hardening agents for gelatin. The hardening test of photographic emulsion was studied at pH 5.5. For example I(R=ONa) had strong hardening properties, I substituted with an aminobenzosulfonate moiety (R=$NHC_6H_4-p-SO_3Me$ where Me = K, Na) was a much weaker gelatin hardener, and when substituted with amino- or oxynaphthalene derivative (II, III) did not harden gelatin at all. Compound with 2 dichlorotriazine groups as IV exhibited strong hardening properties. The hardener can be used in photographic emulsion of film and showed very good hardening effect.

  • PDF

The $CO_{2}$ Hydrogenation toward the Mixture of Methanol and Dimethyl Ether: Investigation of Hybrid Catalysts

  • 준기원;K.S. Rama Rao;정미희;이규완
    • Bulletin of the Korean Chemical Society
    • /
    • 제19권4호
    • /
    • pp.466-470
    • /
    • 1998
  • Catalytic hydrogenation of carbon dioxide for the simultaneous synthesis of methanol and dimethyl ether (together called oxygenates) over a combination of methanol synthesis and methanol dehydration catalysts has been studied. Various methanol synthesis and methanol dehydration catalysts were examined for this reaction. The addition of promotors like $Ga_2O_3\; and\; Cr_2O_3$ to Cu/ZnO catalyst gave much more enhanced yield on the formation of oxygenates. From the results, the promotional effect of $Cr_2O_3$ has been explained in terms of increase in the intrinsic activity of Cu while that of $Ga_2O_3$ being increase in the dispersion of Cu. Among the methanol dehydration catalysts examined, the solid acids bearing high population of intermediate-strength acid sites were found to be very effective for the production of oxygenates. HY zeolite which contains strong acid sites produce small amount of hydrocarbons as by-products. However, CuNaY zeolite in which the presence of strong acid sites are minimum gives very high oxygenates yield without the formation of hydrocarbons.

Emulsifying Property of Carboxymethylchitin

  • Byun, Hee-Guk;Park, Pyo-Jam;Kim, Se-Kwon
    • 한국어업기술학회:학술대회논문집
    • /
    • 한국어업기술학회 2001년도 추계 수산관련학회 공동학술대회발표요지집
    • /
    • pp.237-238
    • /
    • 2001
  • Chitin is the second most abundant natural polymer after cellulose. It is mainly extracted from crustaceous shells and cell walls of fungi, insects and yeast. Chitin is known to be insoluble in most common solvents except for strong acids or N,N-dimethylacetamid because of its rigid crystalline structure through intra- and intermolecular hydrogen bonds. Therefore, different derivatives have been prepared based on chemical and enzymic modification of chitin. (omitted)

  • PDF