• Title/Summary/Keyword: Stripping efficiency

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Numerical analysis of the electromagnetic force for design optimization of a rectangular direct current electromagnetic pump

  • Lee, Geun Hyeong;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.869-876
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    • 2018
  • The force of a direct current (DC) electromagnetic pump used to transport liquid lithium was analyzed to optimize its geometrical and electrical parameters by numerical simulation. In a heavy-ion accelerator, which is being developed in Korea, a liquid lithium film is utilized for its high charge-stripping efficiency for heavy ions of uranium. A DC electromagnetic pump with a flow rate of $6cm^3/s$ and a developed pressure of 1.5 MPa at a temperature of $200^{\circ}C$ was required to circulate the liquid lithium to form liquid lithium films. The current and magnetic flux densities in the flow gap, where a $Sm_2Co_{17}$ permanent magnet was used to generate a magnetic field, were analyzed for the electromagnetic force distribution generated in the pump. The pressure developed by the Lorentz force on the electromagnetic force was calculated by considering the electromotive force and hydraulic pressure drop in the narrow flow channel. The opposite force at the end part due to the magnetic flux density in the opposite direction depended on the pump geometrical parameters such as the pump duct length and width that defines the rectangular channels in the nonhomogeneous distributions of the current and magnetic fields.

Separation of Gold and Silver from Diverse Solutions by Solvent Extraction (다양한 용액으로부터 용매추출에 의한 금과 은의 분리)

  • Xing, Weidong;Lee, Manseung
    • Resources Recycling
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    • v.26 no.5
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    • pp.3-11
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    • 2017
  • Solvent extraction is an important process to recover pure gold and silver from various leaching solutions. The present work reviews the aqueous chemistry and solvent extraction separation of gold (I, III) and silver (I) from several leaching systems such as cyanide, thiocyanate, thiosulfate, thiourea and chloride medium. The extraction and separation behavior of gold (I, III) and silver (I) by various single and mixtures was compared on the basis of extraction reaction and the selectivity from these mediums. The chloride medium is recommended for the separation of gold and silver by solvent extraction in terms of extraction and stripping efficiency.

Surfactant Aided Air-sparging for Groundwater Remediation (계면촬성제 첨가에 따른 지하수 폭기법의 폭기효율 변화 연구)

  • 소효은;최경민;이승재;김헌기
    • Economic and Environmental Geology
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    • v.35 no.5
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    • pp.421-428
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    • 2002
  • Lab-scale experiments were conducted to evaluate the effect of surface tension reduction on the extension of the influence zone and the VOC removal efficiency of ground water sparging. A glass column packed with coarse sand was used for VOC removal test at two different surface tensions. A glass column without porous media was also used fer control purpose prior to sand-packed column test. A quasi-two-dimensional glass box model, packed with a sand, was used fer sparging zone tests at different water surface tensions. Surface tension of the aquoues solution used in this study was controlled using sodium dodecyl sulfate (SDS). For the glass, sand column experiments, total amount of air filled in the media increased as surface tension decreased. Toluene (used as VOC in this study) removal rate increased slightly with decreased surface tension f3r both free water column and sand-packed column. Air sparging zone extended up to 500% as the surface tension decreased. Combining the results from two different experiments, VOC removal efficiency is expected to increase significantly with surface tension reduction.

Initial Electrochemical Insertion/Desertion of Lithium into Hard Carbon

  • Doh, Chil-Hoon;Moon, Seong-In;Yun, Mun-Soo;Jin, Chang-Soo;Jin, Bong-Soo;Eom, Seung-Wook
    • Carbon letters
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    • v.1 no.1
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    • pp.36-40
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    • 2000
  • The initial irreversible capacity (IIC) of a hard carbon during the charge/discharge reaction is strongly affected by both the initial irreversible capacity on the carbon surface $(IIC_S)$ and the initial irreversible lithium insertion into carbon $(IIC_B)$. The initial coulombic efficiency of the insertion and the desertion of lithium (IIE) can be used as a performance to classify $IIC_B$ of the carbon. The $IIC_B$ was proportional to the specific discharge capacity with a slope, $IIE^{-1}$ - 1. The IIE of hard carbon had four regions. $IIE_A$ for the region of 0~95 mAh/g of $Q_{D1}$ was 60.2%. $IIE_B$ and $IIE_C$ for the regions of 95~172 mAh/g and 172~308 mAh/g had 84.9% and 91.5%, respectively. $IIE_D$ was appeared above 308 mAh/g. But, the $IIE_D$ was reduced to 82.1% compared with $IIE_C$. These IIE might be corresponding to lithium desertion from carbon at the region of 0~172 mAh/g range, lithium desertion from the micropore of carbon at the region of 172~308 mAh/g range, and to the lithium stripping of the plated lithium for the region above 308 mAh/g, respectively.

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Extraction Characteristics of $Cr^{6+}$ from Aqueous Solutions with PC-88A, Alamine 336 and Aliquat 336 (PC-88A, Alamine 336 및 Aliquat 336에 의한 수용액중$Cr^{6+}$의 추출특성)

  • Kim Sung Gyu;Lee Hwa Young;Oh Jong Kee
    • Resources Recycling
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    • v.11 no.6
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    • pp.18-23
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    • 2002
  • A study on the solvent extraction of hexavalent chromium from aqueous solutions has been investigated. The results showed that the extraction efficiency of chromium increased in proportion to extractant concentration. Aliquat 336 of quarternary amine effectively extracted hexavalent chromium and was superior to Alamine 336. And the stabilizers like polyhydric alcohols of octanol, decanol and dodecanol showed the similar effect fur prevention of third phase and a little promotion of extraction efficiency in comparison with non-use of polyhydric alcohols. On the other hand, in solvent extraction of hexavalent chromium from aqueous solutions, the hexavalent chromium was completely extracted at pH range lower than 7 with 1% Aliquat 336 as extractant and 5% decanol as stabilizer and the hexavalent chromium in extractant was completely stripped with 1M sodium hydroxide solution in the stripping step.

Evaluation on Efficiency of VOC Removal in Groundwater Using Diffused Aeration System (Diffused Aeration System을 이용한 지하수 내 VOC 제거 효율성 평가)

  • Seo, Minwoo;Suk, Heejun;Choi, Doohyoung;Kim, Jinhoon
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.2
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    • pp.31-37
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    • 2008
  • Diffused Aeration System (DAS) is one of the remediation methods used for removing contaminants in groundwater and this method brings air bubbles in contact with contaminated water, afterwards transferring contaminants in liquid phase into air phase. In this study, three applicability tests using DAS were conducted in two highly contaminated sites. For these tests, diffused air bubbles are generated with a in-flow rate of 17.1, 44.8 and 76.5 (1/min), respectively. The concentrations of TCE in grounwater and air phase were measured during the tests. The measured results showed that TCE concentration hit the highest value after 6~8 min and afterwards decreased gradually. Also, it was observed that the TCE concentration in air phase changed depending on the rate of diffused aeration. In addition, $K_La$ values from liquid to air phase were calculated based on the test results and those of three tests (test 1, 2 3) were 0.444, 1.158 and 1.836(1/hr), respectively. From the comparison of $K_La$ values, the faster air in-flow rate is, the higher the efficiency of the DAS is.

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A Tunable Transmitter - Tunable Receiver Algorithm for Accessing the Multichannel Slotted-Ring WDM Metropolitan Network under Self-Similar Traffic

  • Sombatsakulkit, Ekanun;Sa-Ngiamsak, Wisitsak;Sittichevapak, Suvepol
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.777-781
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    • 2004
  • This paper presents an algorithm for multichannel slotted-ring topology medium access protocol (MAC) using in wavelength division multiplexing (WDM) networks. In multichannel ring, there are two main previously proposed architectures: Tunable Transmitter - Fixed Receiver (TTFR) and Fixed Transmitter - Tunable Receivers (FTTR). With TTFR, nodes can only receive packets on a fixed wavelength and can send packets on any wavelengths related to destination of packets. Disadvantage of this architecture is required as many wavelengths as there are nodes in the network. This is clearly a scalability limitation. In contrast, FTTR architecture has advantage that the number of nodes can be much larger than the number of wavelength. Source nodes send packet on a fixed channel (or wavelength) and destination nodes can received packets on any wavelength. If there are fewer wavelengths than there are nodes in the network, the nodes will also have to share all the wavelengths available for transmission. However the fixed wavelength approach of TTFR and FTTR bring low network utilization. Because source node with waiting data have to wait for an incoming empty slot on corresponding wavelength. Therefore this paper presents Tunable Transmitter - Tunable Receiver (TTTR) approach, in which the transmitting node can send a packet over any wavelengths and the receiving node can receive a packet from any wavelengths. Moreover, the self-similar distributed input traffic is used for evaluation of the performance of the proposed algorithm. The self-similar traffic performs better performance over long duration than short duration of the Poison distribution. In order to increase bandwidth efficiency, the Destination Stripping approach is used to mark the slot which has already reached the desired destination as an empty slot immediately at the destination node, so the slot does not need to go back to the source node to be marked as an empty slot as in the Source Stripping approach. MATLAB simulator is used to evaluate performance of FTTR, TTFR, and TTTR over 4 and 16 nodes ring network. From the simulation result, it is clear that the proposed algorithm overcomes higher network utilization and average throughput per node, and reduces the average queuing delay. With future works, mathematical analysis of those algorithms will be the main research topic.

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Performance Evaluation of the Probability based MAC Protocol for Fair Transmission in WDM Metro Ring (WDM 메트로 링에서 공정한 전송을 위한 확률기반 MAC 프로토콜에 대한 성능 평가)

  • So Won-Ho;Kim Young-Chon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.4B
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    • pp.323-332
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    • 2006
  • In this paper, we consider a WDM based metro ring connecting broadband access networks by using FT-TR (Fixed Transmitter-Tunable Receiver) type access nodes and a new MAC protocol for fair transmission is proposed. The basic channel access scheme is CSMA/CA(Carrier Sense Multiple Access with Collision Avoidance) and the transferred optical slot is changed to be empty slot by SS(Source-Stripping) which drops a packet from ring-rotated slot. This empty slot can be either used to send head-of-line packet in buffer or transmitted to next access node. In former cases, there is the improvement of network throughput, but latter case leads unfairness problem of transmission. Thus the proposed MAC protocol exploits the advantages form tow cases. It gives downstream access nodes chance to use empty slots and limits the unconditional usage of empty slots at upstream access nodes with probability as called p-Persistent MAC protocol. We use a numerical analysis to evaluate bandwidth efficiency and maximum node throughput and compares simulation results in terms of node throughput, fairness factor, transfer delay depending on probability. Under two different FT-TR type architectures for metro ring network the proposed MAC protocol is evaluated and compared.

Synthesis of Trimetallic (PtRu-Sn/VC, PtRu-Ni/VC) Catalysts by Radiation Induced Reduction for Direct Methanol Fuel Cell (DMFC) (방사선환원법을 이용한 직접메탄올연료전지용(DMFC) 삼성분계촉매(PtRu-Sn/VC, PtRu-Ni/VC)의 합성)

  • Kim, Sang Kyum;Park, Ji Yun;Hwang, Sun Choel;Lee, Do Kyun;Lee, Sang Heon;Rhee, Young Woo;Han, Moon Hee
    • Clean Technology
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    • v.19 no.3
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    • pp.320-326
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    • 2013
  • Nano-sized PtRu-Ni/VC and PtRu-Sn/VC electrocatalysts were synthesized by a one-step radiation-induced reduction (RIR) (30 kGy) process using distilled water as the solvent and Vulcan XC-72 as the supporting material. The obtained electrocatalysts were characterized by transmission electron microscopy (TEM), scanning electron microscope energy dispersive spectroscopic (SEM-EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. The catalytic efficiency of electrocatalysts was examined for oxygen reduction, MeOH oxidation and CO stripping decreased in the following order, Hydrogen stripping : PtRu-Sn/VC > PtRu-Ni/VC > PtRu/VC$^{(R)}$ (E-TEK). MeOH oxidation : PtRu-Sn/VC > PtRu-Ni/VC > PtRu/ VC$^{(R)}$ (E-TEK). Unit cell performance : PtRu-Sn/VC > PtRu-Ni/VC > PtRu/VC$^{(R)}$ (E-TEK) catalysts.

Recovery of Cobalt from Synthetic Leaching Solution of Manganese Nodule Matte by Solvent Extraction-electrowinning (용매추출-전해채취법에 의한 망간단괴 매트상 모의 침출용액으로부터 코발트 회수)

  • Kim, Hyun-Ho;Nam, Chul-Woo;Park, Kyung-Ho;Yoon, Ho-Sung;Kim, Min-Seuk;Kim, Chul-Joo;Park, Sang-Woon
    • Resources Recycling
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    • v.25 no.2
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    • pp.33-41
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    • 2016
  • A scale up tests (380 kg/day) using a continuous solvent extraction and electro-winning system was carried out to separate and recover cobalt from a solution containing 1.91 g/L Co and 14.65 g/L Ni. The solution was obtained during a process including solvent extraction and precipitation stages for removal of Cu and Fe from a synthetic sulfuric acid solution of manganese nodule matte. The optimal condition for solvent extraction was : solvent concentration of 0.22M Na-Cyanex 272 (45% saponified with NaOH) and O:A phase ratios of 1:1.5, 10:1 and 1.5:1 used in extraction, scrubbing and stripping stages, respectively. The extraction and stripping efficiencies were found to be 99.8% and 99.88%, respectively. The stripped solution contained 40.27 g/L Co with 4 ppm Ni. Cobalt metal of 99.963% purity was yielded with current efficiency of 67% and current density of $0.563A/dm^2$ during the electro-winning process.