• Title/Summary/Keyword: Stripping analysis

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Novel Method for Stripping of Molybdenum(VI) after Its Extraction with Cyanex 301

  • Saberyan, Kamal;Maragheh, Mohammad Ghannadi;Ganjali, Mohammad Reza
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.460-465
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    • 2004
  • Hydrofluoric acid has been used as a novel stripping agent for molybdenum(VI) after its extraction with Cyanex 301. In the extraction step, the effects of parameters such as type and initial concentration of acid, type of diluent, extractant concentration, metal concentration and temperature have been studied. In the stripping step, the effects of various stripping agents on stripping efficiency have been investigated. Hydrofluoric acid has been chosen as an effective stripping agent, and the effects of concentration of hydrofluoric acid, stripping time, volume of hydrofluoric acid and the number of stages of stripping have been studied. Molybdenum(VI) has been effectively separated from a large number of elements in binary mixtures, with a very high tolerance limit. Finally, the optimized method has been extended for the analysis of Mo(VI) in spent molybdenum catalysts.

An Oxidative Chloride Stripping Solution for 14K Gold Alloys

  • Kim, Kwangbae;Kim, Ikgyu;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.393-398
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    • 2020
  • We propose a novel stripping solution containing acids (HCl and HNO3), an oxidant [(NH4)2S2O8], and complexing agents (NaCl and citric acid) to remove surface passivation layers from 14K gold alloys fabricated using an investment casting process. The optimized solution employing only HCl acid is determined by varying molar fractions of HCl and HNO3 on 14K yellow gold samples. Stripping properties are also identified for red and white gold alloy samples under the optimized stripping conditions. The removal of passivation layers, weight loss, and microstructure evolution are characterized using Raman spectroscopy, a precision scale, and optical microscopy. The proposed stripping solution effectively removes passivation layers more rapidly than conventional cyanide stripping. Weight loss increases linearly for up to 5 min for all 14K gold alloys. Red gold exhibits the greatest weight loss, followed by yellow gold and white gold. The results of microstructural analysis reveal that the conformal stripping occurs according to time. These results imply that the proposed oxidative chloride stripping might replace conventional cyanide stripping.

Evaluation of Moisture Susceptibility of Asphalt Mixtures Using Boiling Water Test (보일링 시험을 통한 아스팔트 혼합물의 수분민감성 평가)

  • Kim, Jun;Park, Dae-Wook;Vo, Viet Hai;Kim, Hyeok-Jung;Park, Jun-Sang
    • International Journal of Highway Engineering
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    • v.17 no.1
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    • pp.77-82
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    • 2015
  • PURPOSES : The purpose of this paper is to evaluate the moisture susceptibility of asphalt mixtures containing developed liquid anti-stripping agents using the boiling water test as a screening test. METHODS : The boiling water test was used to evaluate the moisture susceptibility of asphalt mixtures containing different anti-stripping agents. The tensile strength ratio was calculated to compare the moisture susceptibility of the asphalt mixtures after indirect strength tests were performed. Additionally, image analysis techniques were used to calculate and analyze the quantity of stripped area in the asphalt mixtures. RESULTS : In general, the asphalt mixtures containing anti-stripping agents showed a higher resistance of anti-stripping based on the boiling water test and tensile strength ratio. CONCLUSIONS : The boiling water test can be used to differentiate the resistance of moisture susceptibility of asphalt mixtures, except for asphalt mixtures containing hydrated lime. The boiling water test can be used as a screening test for asphalt mixtures before conducting time consuming and expensive indirect tensile strength tests.

Determination of Ultra Trace Levels of Copper in Whole Blood by Adsorptive Stripping Voltammetry

  • Attar, Tarik;Harek, Yahia;Larabi, Lahcen
    • Journal of the Korean Chemical Society
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    • v.57 no.5
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    • pp.568-573
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    • 2013
  • A selective and sensitive method for simultaneous determination of copper in blood by adsorptive differential pulse cathodic stripping voltammetry is presented. The procedure involves an adsorptive accumulation of Cu(II)-ETSC (4- ethyl-3-thiosemicarbazide) on a hanging mercury drop electrode, followed by a stripping voltammetry measurement of reduction current of adsorbed complex at about -715 mV. The optimum conditions for the analysis of copper (II) ion are : pH 10.3, concentration of 4-ethyl-3-thiosemicarbazide $3.25{\times}10^{-6}$ M and an accumulation potential of -100 mV. The peak current is proportional to the concentration of copper over the range 0.003-125 ng/mL with a detection limit of 0.001 ng/mL and an accumulation time of 60 s. Moreover, with the use of the proposed method, there is a considerable improvement in the detection limit, the linear dynamic range and the deposition time, compared with the methods of adsorptive stripping voltammetry for the determination of copper. The developed method was validated by analysis of whole blood certified reference materials.

A Study on Applicability of Turbulence Models for Unsteady Turbulent Flow with Temperature Variation (온도변화를 수반한 비정상 난류유동장에 대한 난류모델의 적용성에 관한 연구)

  • 유근종;전원대
    • Journal of the Korean Society of Propulsion Engineers
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    • v.6 no.1
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    • pp.1-11
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    • 2002
  • The suitable turbulence model is found to be required in the course of establishing a proper analysis methodology for thermal stripping phenomena which are shown in strong temperature variation area such as reactors and propulsion devices. Three different turbulence models of $\kappa$-$\varepsilon$ model, modified $\kappa$-$\varepsilon$ model, and full Reynolds stress(FRS) model, are applied to analyze unsteady turbulent flows with temperature variation. Three test cases are selected for verification. These are vertical jet flows with water and sodium, and parallel jet flow with sodium. Analysis yields the conclusion that 3-D computation with FRS betters others. However, modified modeling is required to improve its heat transfer characteristic analysis. Further analysis is performed to find momentum variation effects on temperature distribution. It is found that the momentum increase results increase of fluid mixing and magnitude of temperature variation.

VP-ellipsis, Stripping, and the Functions of the Delimiter -to in Korean

  • Kim, So-Jee;Cho, Sae-Youn
    • Language and Information
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    • v.20 no.1
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    • pp.93-110
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    • 2016
  • VP-ellipsis constructions in English can be schematized as S + [NP finite-AUX __ ] where the underlined part is understood to be a VP. Similarly, the pattern S + NP[-to] can be observed in Korean colloquial contexts. Though the English VP-ellipsis sentence pattern and the Korean pattern superficially seem to be similar, the Korean pattern exhibits peculiar properties: Syntactically, the NP of the pattern should have the delimiter -to. Semantically, it may convey ambiguous readings: VP-ellipsis-like and/or Stripping-like interpretation. To account for the pattern at issue, we propose a base-generated analysis driven by the delimiter -to within a construction grammar. We claim that the mother of the NP[-to] in this pattern is an S whose meaning is ambiguous between a VP-ellipsis-like and a Stripping-like reading. Consequently, the code of the VP-ellipsis in English is finite auxiliary verbs while that of the pattern S + NP[-to] in Korean is the delimiter -to.

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Characteristics of the Oxygen Plasma and Its Application to Photoresist Stripping (산소 플라즈마의 특성과 포토레지스트 제거에의 응용)

  • Whang, Ki Woong;Lee, Jong Duk;Kim, Joung Ho
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.24 no.1
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    • pp.73-78
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    • 1987
  • The physical mechanism of a RF discharge used in photoresist stripping and etching process are not well understood and, plasma reactor design and the determination of optimum operating coditions are done largely on empirical basis. We analyzed the discharge process through the measurement of plasma characteristics and applied out results tothe analysis of the photoresist stripping. We investigated the effects of plasma electron density, neutral oxygen gas pressure and electrode temperature on the stripping rates and related their effects with the characteristics of plasma.

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Analysis of Arsenic(III) by the Cathodic Stripping Voltammetry (음극 벗김 전류법을 이용한 비소(III) 분석에 관한 연구)

  • Yun, Young Ja;Lee, Hyung Sook;Ko, Weon Bae;Kim, Chung Hee
    • Analytical Science and Technology
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    • v.5 no.4
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    • pp.417-423
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    • 1992
  • The effects of metal ions on the arsenic(III) stripping peak were examined by the cathodic stripping voltammetry. The reduction stripping peak potential and current of arsenic(III) value were -0.79V(vs. Ag/AgCl). $0.86{\mu}A$ by using 0.1N-hydrochloric acid solution. When 10 times of Cu(II) was added to the solution, the reduction stripping peak potential of arsenic(III) was the value of -0.84V(vs. Ag/Cl), which showed a good agreement with theoretical value -0.84V(vs. Ag/Cl) by using 0.1N hydrochloric acid solution. Lead(II) and copper(II) increased the stripping peak heigh of arsenic(III), Among them, the copper(II) extremely enhanced it.

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Resolving the Ambiguities of Negative Stripping Construction in English : A Direct Interpretation Approach (영어 부정 스트리핑 구문의 중의성 해소에 관한 연구: 직접 해석 접근법을 중심으로)

  • Kim, So-jee;Cho, Sae-youn
    • Cross-Cultural Studies
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    • v.52
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    • pp.393-416
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    • 2018
  • Negative Stripping Construction in English involves the disjunction but, the adverb not, and a constituent NP. This construction is an incomplete sentence although it delivers a complete sentential meaning. Interpretation of this construction may be ambiguous in that the constituent NP can either be construed as the subject, or as the complements including the object. To generate such sentences and resolve the issue of ambiguity, we propose a construction-based analysis under direct interpretation approach, rejecting previous analyses based on deletion approaches. In so doing, we suggest a negative stripping construction rule that can account for ambiguous meaning. This rule further can enable us to explain syntactic structures and readings of Negative Stripping Construction.

Performance Evaluation of the MAC Protocols for WDM Metro Ring with Wavelength-Shared Nodes Connecting Broadband Access Networks (대역 액세스 망을 연결하는 파장 공유 노드 기반 WDM 메트로 링의 MAC 프로토콜 성능 평가)

  • So Won-Ho
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.1 s.343
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    • pp.111-120
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    • 2006
  • In this paper, a node architecture of WDM metro network for connecting broadband access networks to converge wire/wireless networks. In consideration of the proposed node architecture and network requirements we proposed and evaluated medium access control protocols. We review WDM related technologies of sub-carrier multiplexing and optical components in order to resolve the bottleneck between optical backbone networks md access networks, and a access node architecture sharing common wavelength is introduced. Source-stripping (SS) MAC protocol Is evaluated under the proposed functional node architecture. DS+IS (Destination-Stripping and Source-Stripping) and DS+IS (Destination-Stripping and Intermediate-Stripping) MAC protocols are described to increase the slot-reuse factor which is low on SS MAC protocol. The key function of new MAC protocols regards the optical switch module of proposed node architecture and helps intermediate or source access nodes for dropping slots to destinations of different wavelength group. Thus, slot-reuse factor increases as the MAC protocols reduce the unnecessary ring-rotation of transferred slots. We use a numerical analysis to expect bandwidth efficiency and maximum throughput by slot-reuse factor Throughput network simulation, the verification of throughput, queuing delay, and transmission fairness are compared among MAC protocols.