• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.674-680
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• 2015

A solvent-soluble polyimide (PI) polymeric binder was synthesized by a two-step reaction for silicon (Si) anodes for lithium-ion batteries. Polyamic acid was first prepared through ring opening between two monomers, bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA) and 4,4-oxydianiline (ODA), followed by condensation reaction. Using the synthesized PI polymeric binder (molecular weight = ~10,945), the coating slurry was then prepared and Si anode was fabricated. For the control system, Si anode based on polyvinylidene fluoride (PVDF, molecular weight = ~350,000) having the same constituent ratio was prepared. During precycling, PI polymeric binder revealed much improved discharge capacity ($2,167mAh\;g^{-1}$) compared to that of using PVDF polymeric binder ($1,740mAh\;g^{-1}$), while the Coulombic efficiency of two systems were similar. PI polymeric binder improved the cycle retention ability during cycles compared to that of using PVDF, which is attributed to an improved adhesion property inside Si anode diminishing the dimensional stress during Si volume changes. The adhesion property of each polymeric binder in Si anode was confirmed by surface and interfacial cutting analysis system (SAICAS) (Si anode based on PI polymeric binder = $0.217kN\;m^{-1}$ and Si anode based on PVDF polymeric binder = $0.185kN\;m^{-1}$).

• Journal of Korean Tunnelling and Underground Space Association
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• v.22 no.4
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• pp.435-450
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• 2020

The divergence section of a double-deck tunnel can be divided into a 'widening pre-divergence section', a large cross-section with a cap shape and a 'post-divergence section' where the separation between the main and the branch tunnel is made. Since the cross-section of the widening pre-divergence section is considerably larger than that of the post-divergence section, the influence of excavation due to the different sizes and shapes in the cross-section should be considered in the examination of the tunnel stability. In this study, the effect of the preceding excavation, that is the excavation of the widening pre-divergence section, on excavation stability of the post-divergence section was examined by varying the excavation methods and bench lengths through 3D finite element analysis. The results showed that although the effects of the excavation methods and the bench lengths are not significant on the variation of principal stresses, the preceding excavation causes a relatively large variation on the stresses which may have an impact on the stability of the post-divergence section from the comparison of Stress-Strength Ratio (SSR) between the cases with and without the consideration of the preceding excavation effect by 2D finite element analysis.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.17 no.3
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• pp.319-332
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• 2004

Due to their high strength to weight ratios and excellent durability, fiber reinforced polymer(FRP) is widely used in construction industries. In this paper, a shape optimum design of FRP bridge decks haying pultruded cellular cross-section is presented. In the problem formulation, an objective function is selected to minimize the volumes. The cross-sectional dimensions and material properties of the deck of FRP bridges are used as the design variables. On the other hand, deflection limits in the design code, material failure criteria, buckling load, minimum height, and stress are selected as the design constraints to enhance the structural performance of FRP decks. In order to efficiently treat the optimization process, the cross-sectional shape of bridge decks is assumed to be a tube shape. The optimization process utilizes an improved Genetic Algorithms incorporating indexing technique. For the structural analysis using a three-dimensional finite element, a commercial package(ABAQUS) is used. Using a computer program coded for this study, an example problem is solved and the results are presented with sensitivity analysis. The bridge consists of a deck width of 12.14m and is supported by five 40m long steel girders spaced at 2.5m. The bridge is designed to carry a standard DB-24 truck loading according to the Standard Specifications for Highway Bridges in Korea. Based on the optimum design, viable cross-sectional dimensions for FRP decks, suitable for pultrusion process are proposed.

• Tunnel and Underground Space
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• v.11 no.2
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• pp.109-119
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• 2001

Up to now single large cavern was excavated for each undergroud hydraulic powerhouse in Korea. But the Yangyang underground hydraulic powerhouse consists of two large caverns; a powerhouse cavern and main transformer cavern. In this carte, the structural stability of the caverns, especially the rock pillar formed between two large caverns, should be guaranteed to be sound to make the caverns permanently sustainable. In this research, the Distinct Element Method(DEM) was used to analyze the structural stability of two caverns and the rock pillar. The Barton-Bandis joint model was used as a constitutive model. The moot significant parameters such as in-site stress, JRC of in-situ natural joints, and spatial distribution characteristics of discontinuities were acquired through field investigation. In addition, two different cases; 1) with no support system and 2) with a support system, were analysed to optimize a support system and to investigate reinforcing effects of a support system. The results of analysis horizontal displacement and joint shear displacement proved to be reduced with the support system. The relaxed zone in the rock pilar also proved to be reduced in conjunction with the support system. Having a support system in place provided the fact that the non zero minimum principal stresses were still acting in the rock pillar so that the pillar was not under uniaxial compressive condition but under triaxial compressive condition. The structural stability f an approximately 36 m wide rock pillar between two large caverns was assured with the appropriate support system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.9
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• pp.626-633
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• 2020

This study examined the behavior of the ground by comparing the methods using the results of the Terzaghi formula and the ground investigation data and method considering the dilatancy effect for a circular tunnel using the finite element method. In the case of the Terzaghi formula, the tunnel load can be overestimated and cause overdesign. The method using the results of the ground investigation data cannot be applied when a reasonable coefficient of earth pressure is not determined. This is because it behaves completely differently from the actual behavior, and unexpected problems can occur. In the case of the method considering the dilatancy effect, however, both the strength enhancement effect can be considered through the dilatancy angle and relative density. Therefore, the tunnel load was calculated most reasonably using the method considering dilatancy. Finite element analysis using the geotechnical survey results showed that the tensile stress acts at the top of the tunnel when the upper soil of the tunnel is shallow. On the other hand, additional verification is necessary, such as a comparison with the field measurement results. Through additional research, if normalized, the tunnel load can be calculated reasonably at the time of tunnel design, and safe and economical design is possible.

• Journal of Radiation Protection and Research
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• v.31 no.1
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• pp.37-46
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• 2006

For the first step to develop a reference disposal container of spent fuel to be used in a deep geological repository, this paper examined safe dimensions of the disposal container on the points of nuclear criticality and radiation safety and mechanical structural safety and provided basic information for dimensioning the container and configuration of the container components, and establishing the favorable and safe disposal conditions. When the safety factor for stress due to the external loads (hydrostatic and swelling pressure) is taken as 2.0, the safe diameter of the filler material to provide enough container strength under the assumed external loads is found to be 112cm with 13cm spacing between inner baskets in PWR container. Also the thickness of the thinner section between the fuel basket and the surface of the cast insert is determined to be 150 mm. Regarding these dimensions of the container, the PWR fuel container is sketched to accommodate 4 square assemblies or 297 CANDU fuel 297 bundles (33 circle tubes x 9 stacks). However the top and bottom parts need to be checked again through the detail radiation shielding analysis with respects to the emplacement position and handling processes of the disposal container.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.936-944
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• 2019

Submarines, which have been called an invisible force, are strategic underwater weapon systems that perform missions such as anti-surface warfare, anti-submarine warfare, and high payoff target strikes with the advantage of underwater covertness. A submarine should be able to withstand the hydrostatic pressure of the deep sea. In this respect, the submarine pressure hull, as the main structural system to resist the external pressure corresponding to the submerged depth, should ensure the survivability from hazards and threats such as leakage, fires, shock, explosion, etc. To do this, the initial scantling of the submarine pressure hull must be calculated appropriately in the concept design phase. The shape of the aft transition ring varies according to its connection with the submarine aft end conical structure, pressure hull cylindrical part, and non-pressure hull of the submarine; the design of the aft transition ring should not only take into account stress flow and connectivity but also the cost increase due to the increased man-hours of its complex geometry. Therefore, trade-off studies based on the four different shapes of the aft transition ring are carried out considering both the review of the structural strength through nonlinear finite element analysis (FEA) and economic feasibility by reviewing the estimations of the manufacturing working days and material costs. Finally, the most rational structural aft transition ring shape for a submarine amongst four reviewed types was proposed.

• Smart Structures and Systems
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• v.14 no.2
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• pp.209-224
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• 2014

With more and more built long-term structural health monitoring (SHM) systems, it has been considered to apply monitored data to learn the reliability of bridges. In this paper, based on a long-term SHM system, especially in which the sensors were embedded from the beginning of the construction of the bridge, a method to calculate the localized reliability around an embedded sensor is recommended and implemented. In the reliability analysis, the probability distribution of loading can be the statistics of stress transferred from the monitored strain which covered the effects of both the live and dead loads directly, and it means that the mean value and deviation of loads are fully derived from the monitored data. The probability distribution of resistance may be the statistics of strength of the material of the bridge accordingly. With five years' monitored strains, the localized reliabilities around the monitoring sensors of a bridge were computed by the method. Further, the monitored stresses are classified into two time segments in one year period to count the loading probability distribution according to the local climate conditions, which helps us to learn the reliability in different time segments and their evolvement trends. The results show that reliabilities and their evolvement trends in different parts of the bridge are different though they are all reliable yet. The method recommended in this paper is feasible to learn the localized reliabilities revealed from monitored data of a long-term SHM system of bridges, which would help bridge engineers and managers to decide a bridge inspection or maintenance strategy.

• Restorative Dentistry and Endodontics
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• v.31 no.4
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• pp.290-299
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• 2006

Objectives: The purpose of this study is to evaluate the effect of ethylene glycol analogs on modulus of elasticity and ultimate tensile strength of moist, demineralized dentin matrix. Methods: Dentin disks 0.5 mrn thick were prepared from mid-coronal dentin of extracted. unerupted, human third molars. 'I' beam and hour-glass shaped specimens were prepared from the disks, the ends protected with nail varnish and the central regions completely demineralized in 0.5M EDTA for 5 days. Ultimate tensile stress (UTS) and low strain modulus of elasticity (E) were determined with specimens immersed for 60 min in distilled water $(H_{2}O)$, ethylene glycol $(HO-CH_{2}-CH_{2}-OH)$, 2-methoxyethanol $(H_{3}CO-CH_{2}-CH_{2}-OH)$, and 1,2-dimethoxyethane $(H_{3}CO-CH_{2}-CH_{3}-OCH_{3})$ prior to testing in those same media. Modulus of elasticity was measured on the same specimens in a repeated measures experimental design. The results were analyzed with a one-way ANOVA on ranks, followed by Dunn's test at ${\alpha}\;=\;0.05$. Regression analysis examined the relationship between UTS or E and hoy's solubility parameter for hydrogen bonding $({\delta}_{h})$ of each solvent. Results: The UTS of demineralized dentin in water, ethylene glycol, 2-methoxyethanol, and 1,2-dimethoxyethane was 24 (3), 30 (5), 37 (6), and 45 (6) MPa, ${\times}$ (SD) N = 10. Low strain E for the same media were 16 (13), 23 (14), 52 (24), and 62 (22) MPa. Regression analysis of UTS vs ${\delta}_{h}$ revealed a significant $(p\;<\;0.0001,\;r\;=\;-0.99,\;R^{2}\;=\;0.98)$ inverse, exponential relationship. A similar inverse relationship was obtained between low strain E vs ${\delta}_{h}\;(p\;<\;0.0005,\;r\;=\;-0.93,\;R^{2}\;=\;0.86)$. Significance: The tensile properties of demineralized dentin are dependent upon the hydrogen bonding ability of polar solvents $({\delta}_{h})$. Solvents with low ${\delta}_{h}$ values may permit new interpeptide H-bonding in collagen that increases its tensile properties. Solvents with high ${\delta}_{h}$ values prevent the development of these new interpeptide H-bonds.

• Tunnel and Underground Space
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• v.18 no.2
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• pp.98-106
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• 2008

When a tunnel is excavated in a rock mass of poor condition, the adjacent zone of excavation surface may be reinforced by adopting the appropriate methods such as grouting and rock bolting. The reinforced effect can be evaluated by use of various numerical approaches, where the reinforcing elements may be expressed as distinct discretizations or smeared into the equivalent material properties. In this study, a simple numerical method, which can be classified as the latter approach, was developed for the elasto-plastic analysis of a circular tunnel. If a circular tunnel in a Mohr-Coulomb rock mass is reinforced to a finite thickness, the reinforced annulus may have different material properties from the in-situ rock mass. In the proposed elasto-plastic method for assessing the reinforcing effect, Lee & Pietruszczak (2007)'s method is applied to both the reinforced annulus and the outer insitu rock mass of the fictitious tunnel, and then two results are combined by enforcing the compatibility condition. The method were verified through comparing the results with the proposed method and the commercial finite difference code FLAC. When taking the variation of deformation modulus and strength parameters in the reinforced zone into account, the distributions of stress and radial displacement were much different from those obtained with the assumption of homogeneous rock mass.