• Title/Summary/Keyword: Stress intensity

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Thermal Stability and Mechanical Interfacial Properties of DGEBA/PMR-15 Blend System Initiated by Cationic Latent Thermal Catalyst (잠재성 양이온 개시제를 이용한 DGEBA/PMR-15 블렌드계의 열안정성 및 기계적 계면 특성에 관한 연구)

  • Park, Soo-Jin;Lee, Hwa-Young;Han, Mijeong;Hong, Sung-Kwon
    • Journal of Adhesion and Interface
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    • v.5 no.1
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    • pp.3-11
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    • 2004
  • In this work, the cure behaviors of the DGEBA/PMR-15 blends initiated by N-benzylpyrazinium hexafluoroantimonate (BPH) as a cationic latent catalyst were performed in DSC and DMA analyses. And, the thermal stabilities were carried out by TGA analysis and their mechanical interfacial properties of blends were measured in the context of critical stress intensity factor ($K_{IC}$). As a result, the curing activation energy ($E_a$) determined from Ozawa's equation in DSC and the relaxation activation energy ($E_r$) from DMA were increased with increasing PMA-15 content. Also, the thermal stabilities obtained from the integral procedural decomposition temperature (IPDT) and the glass transition temperature ($T_g$) were highly improved with increasing the PMR-15 content, which were probably due to the high heat resistance. And, the $K_{IC}$ showed a similar behavior with $E_a$, which was attributed to the improving of the interfacial adhesion or hydrogen bondings between intermolecular chains.

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Cure Behaviors and Fracture Toughness of PEl/Difunctional Epoxy Blends (PEI/DGEBA 블랜드계의 열적특성 및 파괴인성)

  • Park, Soo-Jin;Jin, Sung-Yeol;Kaang, Shinyoung
    • Journal of Adhesion and Interface
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    • v.4 no.3
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    • pp.33-40
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    • 2003
  • In this work, diglycidyl ether of bisphenol A (DGEBA)/polyetherimide (PEI) blends were cured using 4,4-diaminodiphenyl methane (DDM). And the effects of addition of different PEI contents to neat DGEBA were investigated in the thermal properties and fracture toughness of the blends. The contents of contents of containing PEI were varied in 0, 2.5, 5, 7.5, and 10 phr. The cure activation energies ($E_a$) of the cured specimens were determined by Kissinger equation and the mechanical interfacial properties of the specimens were performed by critical stress intensity factor ($K_{IC}$). Also their surfaces were examined by using a scanning electron microscope (SEM) and the surface energetics of blends was determined by contact angles. As a result, $E_a$ and $K_{IC}$ showed maximum values in the 7.5 phr PEI. This result was interpreted in the increment of the network structure of DGEBA/PEI blends. Also, the surface energetics of the DGEBA/PEI blends showed a similar behavior with the results of $K_{IC}$. This was probably due to the improving of specific or polor component of the surface free energy of DGEBA/PEI blends, resulting in increasing the hydrogen bonding of the hydroxyl and imide groups of the blends.

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Experimental Study on Fatigue Characteristics of the Single Spot Welded Joint (점용접재(点熔接材)의 피로(疲勞) 특성(特性)에 관한 실험적(實驗的) 연구(硏究))

  • Chang-Min Suh;Sung-Soo Kang;Nam-Seong Hwang;Yong-Ich Cho
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.4
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    • pp.214-226
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    • 1992
  • In this paper, the characteristics of fatigue crack growth in the spot welded joint of the same kinds of specimens($HS{\times}HS,\;GA{\times}GAB$) and different kinds of specimens($HS{\times}GA,\;HS{\times}GAB$) which consist of dual phase high strength steel(HS) and monogalvanized steel(GA) were examined with static tension tests and axial tension fatigue tests. Some of the important results are as follows : 1. The divergence of tensile strengths among the same and different kinds of spot welds under the same conditions is comparatively low regardless of the difference of stiffness. 2. At the low load bevel and long life legion, the fatigue crack is initiated near the nugget. However, in the high load level and short life region, it occurs a tittle far from the nugget. 3. It has shown a linear relation between maximum stress Intensity factor, Kmax and fatigue life, $N_f$ among each of the spot welds and has gathered in a narrow band on the log-log graph paper. $Kmax=H{\cdot}{N_f}^{P}$ where H and P are a material constant.

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Effect of Methoxy PEG-45 Thioctate (LA-PEG) against Oxidative Protein Damage and Anti-glycation (Methoxy PEG-45 Thioctate (LA-PEG)의 항노화 효과에 대한 연구)

  • Kim, Jin Hwa;Oh, Jung Young;Bae, Jun Tae;Lee, Geun Soo;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.3
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    • pp.239-245
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    • 2017
  • Aging is a physiological and irreversible, progressive process involving changes in the ability to maintain cellular functionality. It affects tissues, organs and the whole organism and thus finally cause to death. Oxidative stress has been postulated to contribute significantly to the accelerated accumulation of advanced glycation endproducts (AGEs) in collagen, which is implicated in the process of skin aging. In the present study, glycation inhibitory activity of methoxy PEG-45 thioctate (LA-PEG), and its inhibitory effect of cellular oxidation and senescence was investigated. Treatment of LA-PEG significantly showed lower fluorescent intensity induced by AGEs. In addition, LA-PEG was significantly reduced the formation of ROS induced by AGEs. High antioxidant and anti-glycation activities of LA-PEG in glycated collagen model indicated its contribution to anti-aging process. Cellular senescence leads to an increase in senescence-associated ${\beta}$-galactosidase ($SA-{\beta}-gal$) activity, which can be used as a biomarker to identify senescent cells. Treatment with LA-PEG showed a dose-dependent, statistically significant decreased in $SA-{\beta}-gal$ indicating reduced senescence. These results suggest that LA-PEG may have potent anti-aging effects and can be used as new functional materials against cellular accumulation of AGEs.

The Current Methods of Landslide Monitoring Using Observation Sensors for Geologic Property (지질특성 관측용 센서를 이용한 산사태 모니터링 기법 현황)

  • Chae, Byung-Gon;Song, Young-Suk;Choi, Junghae;Kim, Kyeong-Su
    • Journal of Sensor Science and Technology
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    • v.24 no.5
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    • pp.291-298
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    • 2015
  • There are many landslides occurred by typhoons and intense rainfall during the summer seasons in Korea. To predict a landslide triggering it is important to understand mechanisms and potential areas of landslides by the geological approaches. However, recent climate changes make difficult to predict landslide based on only conventional prediction methods. Therefore, the importance of a real-time monitoring of landslide using various sensors is emphasized in recent. Many researchers have studied monitoring techniques of landslides and suggested several monitoring systems which can be applicable to the natural terrain. Most sensors of landslide monitoring measure slope displacement, hydrogeologic properties of soils and rocks, changes of stress in soil and rock fractures, and rainfall amount and intensity. The measured values of each sensor are transmitted to a monitoring server in real-time. The ultimate goal of landslide monitoring is to warn landslide occurrence in advance and to reduce damages induced by landslides. This study introduces the current situation of landslide monitoring techniques in each country.

A Study on Surface Properties of Mechanical Interfacial Behavior of DGEBA/PMR-15 Blends (DGEBA/PMR-15 블렌드계의 표면특성 변화가 기계적 계면특성에 미지는 영향)

  • Park, Soo-Jin;Lee, Hwa-Young;Han, Mijeong;Hong, Sung-Kwon
    • Journal of Adhesion and Interface
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    • v.4 no.1
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    • pp.1-8
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    • 2003
  • In this work, the effect of PMR-15 content on the variation of surface free energy of the DGEBA/PMR-15 blend system was investigated in terms of contact angles and mechanical interfacial tests. Based on FT-IR result of the blend system. C=O (1,772, $1,778cm^{-1}$) and C-N ($1,372cm^{-1}$) peaks appeared with imidization of PMR-15 and -OH ($3,500cm^{-1}$) peak showed broadly at 10 phr of PMR-15 by ring-opening of epoxy. Contact angle measurements were performed by using deionized water and diiodomethane as testing liquids. As a result, the surface free energy of the blends gave a maximum value at 10 phr of PMR-15, due to the significant increasing of specific component. The mechanical interfacial properties measured from the critical stress intensity factor ($K_{IC}$) and the critical strain energy release rate ($G_{IC}$) showed a similar behavior with the results of surface energetics. This behavior was probably attributed to The improving of the interfacial adhesion between intermolecules, resulting from increasing the hydrogen bondings of the blends.

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A study of applying soil moisture for improving false alarm rates in monitoring landslides (산사태 모니터링 오탐지율 개선을 위한 토양수분자료 활용에 관한 연구)

  • Oh, Seungcheol;Jeong, Jaehwan;Choi, Minha;Yoon, Hongsik
    • Journal of Korea Water Resources Association
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    • v.54 no.12
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    • pp.1205-1214
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    • 2021
  • Precipitation is one of a major causes of landslides by rising of pore water pressure, which leads to fluctuations of soil strength and stress. For this reason, precipitation is the most frequently used to determine the landslide thresholds. However, using only precipitation has limitations in predicting and estimating slope stability quantitatively for reducing false alarm events. On the other hand, Soil Moisture (SM) has been used for calculating slope stability in many studies since it is directly related to pore water pressure than precipitation. Therefore, this study attempted to evaluate the appropriateness of applying soil moisture in determining the landslide threshold. First, the reactivity of soil saturation level to precipitation was identified through time-series analysis. The precipitation threshold was calculated using daily precipitation (Pdaily) and the Antecedent Precipitation Index (API), and the hydrological threshold was calculated using daily precipitation and soil saturation level. Using a contingency table, these two thresholds were assessed qualitatively. In results, compared to Pdaily only threshold, Goesan showed an improvement of 75% (Pdaily + API) and 42% (Pdaily + SM) and Changsu showed an improvement of 33% (Pdaily + API) and 44% (Pdaily + SM), respectively. Both API and SM effectively enhanced the Critical Success Index (CSI) and reduced the False Alarm Rate (FAR). In the future, studies such as calculating rainfall intensity required to cause/trigger landslides through soil saturation level or estimating rainfall resistance according to the soil saturation level are expected to contribute to improving landslide prediction accuracy.

Study on Bearing Capacity of Ultra High Strengh End Extended PHC Pile by Loading Test (재하시험을 통한 초고강도 선단확장 PHC말뚝의 적용성 연구)

  • Hwang, Ui-Seong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.269-275
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    • 2019
  • As the national industry is developing gradually due to the expansion of the economic scale, the construction of large and super high-rise structures for building social infrastructure has been increasing, and studies have been conducted actively to transmit the large loads at the upper portion to the lower bedrock. In this study, the PHC was extended to an ultra-high strength PHC, which increased the concrete compressive strength of the PHC from the conventional 80 MPa to 110 MPa, and the PHC, which extended the tip of the pile. After construction with the driving method and injected pile method, the tendency of the bearing capacity was tested through a load test. Measurements of the bearing capacity of the extended PHC using the pile driving method revealed the main surface friction force to be smaller than that of the general PHC, and the stet-up effect was also insignificant. On the other hand, the effect of the friction force on the ground surface when the injected pile method was applied is expected to increase the bearing capacity when the gap between the main surface and the ground is wide and the cement paste is filled tightly. In addition, the ultrahigh strength PHC showed higher bearing capacity than the conventional PHC, and the permissible pile stress was less than 60%. Therefore, it is possible to reduce the number of piles and reduce the construction cost and effect of shortening the length of the pile by designing the tip of the pile on the ground with the intensity of soft rock as a method for utilizing the increased strength of the ultra-high strength PHC.

Effects of Organizational Citizenship Behavior on Turnover Intentions in Marine Officers as Mediated by Organizational Commitment (해기사의 조직시민행동이 조직몰입을 매개로 이직의도에 미치는 영향)

  • LEE, Chang-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.7
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    • pp.787-797
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    • 2020
  • The marine officer plays a pivotal role in the shipping organization as a professional who performs a complex and diverse function. On the sea, unlike land duty, the possibility of turnover increases due to characteristics such as living in isolated spaces, continuous shift work during a set sailing period, high intensity work tension, stress, and social isolation. In this study, the impact of the organization's civic actions on the intention of turnover as a mediator of organizational immersion was divided into three groups of large companies, small and medium-sized enterprises, and public enterprises to check the differences between each category in a structural manner. Analysis showed that there were statistically significant differences between the groups in loyalty and turnover intention when the sub-factors of organizational commitment and organizational citizen behavior of the marine officer, and the size of turnover intention were included. Organization citizen behavior did not directly affect turnover intention, but when indirect effects were included, there was an effect through loyalty, and relationship-oriented organizational citizen behavior negatively affected turnover intention through loyalty. Excluding public enterprises, the non-standardization path coefficients were -0.229±0.117 and -0.319±0.068, respectively, showing a statistically significant effect in large companies and SMEs. These results indicate that in order to lower the employee turnover intention in large corporations and small and medium-sized shipping companies, it is necessary to consider not only organizational citizen behavior but also measures to increase organizational commitment.

Major environmental factors and traits of invasive alien plants determining their spatial distribution

  • Oh, Minwoo;Heo, Yoonjeong;Lee, Eun Ju;Lee, Hyohyemi
    • Journal of Ecology and Environment
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    • v.45 no.4
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    • pp.277-286
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    • 2021
  • Background: As trade increases, the influx of various alien species and their spread to new regions are prevalent and no longer a special problem. Anthropogenic activities and climate changes have made the distribution of alien species out of their native range common. As a result, alien species can be easily found anywhere, and they have nothing but only a few differences in intensity. The prevalent distribution of alien species adversely affects the ecosystem, and a strategic management plan must be established to control them effectively. To this end, hot spots and cold spots were analyzed according to the degree of distribution of invasive alien plants, and major environmental factors related to hot spots were found. We analyzed the 10,287 distribution points of 126 species of alien plants collected through the national survey of alien species by the hierarchical model of species communities (HMSC) framework. Results: The explanatory and fourfold cross-validation predictive power of the model were 0.91 and 0.75 as AUC values, respectively. The hot spots of invasive plants were found in the Seoul metropolitan area, Daegu metropolitan city, Chungcheongbuk-do Province, southwest shore, and Jeju island. Generally, the hot spots were found where the higher maximum temperature of summer, precipitation of winter, and road density are observed, but temperature seasonality, annual temperature range, precipitation of the summer, and distance to river and sea were negatively related to the hot spots. According to the model, the functional traits accounted for 55% of the variance explained by the environmental factors. The species with higher specific leaf areas were more found where temperature seasonality was low. Taller species preferred the bigger annual temperature range. The heavier seed mass was only preferred when the max temperature of summer exceeded 29 ℃. Conclusions: In this study, hot spots were places where 2.1 times more alien plants were distributed on average than non-hot spots (33.5 vs 15.7 species). The hot spots of invasive plants were expected to appear in less stressful climate conditions, such as low fluctuation of temperature and precipitation. Also, the disturbance by anthropogenic factors or water flow had positive influences on the hot spots. These results were consistent with the previous reports about the ruderal or competitive strategies of invasive plants instead of the stress-tolerant strategy. The functional traits are closely related to the ecological strategies of plants by shaping the response of species to various environmental filters, and our result confirmed this. Therefore, in order to effectively control alien plants, it is judged that the occurrence of disturbed sites in which alien plants can grow in large quantities is minimized, and the river management of waterfronts is required.