• Elastomers and Composites
• /
• 제36권1호
• /
• pp.30-36
• /
• 2001

이 연구의 목적은 카본블랙이 충전된 천연고무에서 비 등방성 발생에 영향을 주는 인자를 조사하기 위함이다. 고분자 사슬의 방향성은 인장특성에 영향을 준다. Pre-strained 방향의 parallel 시편은 등방성 혹은 perpendicular 시편에 비하여 낮은 인장영역에서 낮은 강도를 보이지만 높은 신장영역에서 높은 강도를 보인다. 고 인장 영역에서 parallel한 천연고무 시편은 비결정성인 SBR에 비하여 높은 강도를 보여주고 있다. 이것은 parallel 시편의 방향성에 영향을 받는 것으로, 시편의 방향성은 2차 인장시 결정화를 위한 핵으로 작용하여 결정화도를 증가시키는 것으로 보인다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 춘계학술대회
• /
• pp.342-347
• /
• 2004

The deformation behavior of a $Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass under tensile loading at different range of strain rates and temperatures between 680 K and 740 K were investigated. The variation in the deformation behavior of $Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass which resulted from the crystallization induced during testing was reported. The$Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass has showed either homogeneous or inhomogeneous deformation depending on test condition. It exhibited a maximum elongation of about 560 % at the condition of $407^{\circ}C{\times}\;10^{-4}/s$. The flow behavior exhibited three different types and the flow stress became lower at higher temperatures and lower strain rates. The increase of the time elapsed during heating resulted in the partial crystallization of bulk metallic glass phase and eventually strain hardening and brittle fracture.

• Macromolecular Research
• /
• 제10권6호
• /
• pp.365-368
• /
• 2002

Thermoplastic polyurethanes (TPUs) with different hard segment length has been prepared from a fixed molar ratio of poly(tetramethylene ether glycol), 4,4'-diphenylmethane diisocyanate, and 1,4-butanediol by different polymerization procedures. Results reveal that the on-set temperature of endotherms ( $T_{cc}$ ) due to the crystallization of hard segments by cooling the TPUs from melt and the peak temperature of endotherms due to the melting of hard segments ( $T_{mh}$ ) by heating the TPUs increased and levelled off with increasing the hard segment length of TPUs. It has also been observed that soft segment glass transition temperature ( $T_{gs}$ ) of TPU decreased slightly with increasing the hard segment length, which explains less mixing of soft segments and hard segments. In tensile measurement of TPUs, strain hardening is observed with increasing the hard segment length, which is attributed to the strain induced crystallization of soft segments.

• Elastomers and Composites
• /
• 제36권4호
• /
• pp.255-261
• /
• 2001

Precut을 가지고 있는 고무 시편에서 서로 다른 온도에서 인장 강도의 영향을 조사하였다. 온도 조건에 따라 precut이 있는 시편과 precut이 없는 시편의 인장 강도는 서로 다른 거동을 보였다. $80^{\circ}C$에서는 임계 Precut 크기보다 더 큰 precut를 가지는 시편은 상온에서 시편보다 높은 인장 강도를 보였다. 상온에서 측정한 시편에 비하며 $80^{\circ}C$에서 측정한 시편은 잘 발달된 2차 균열들을 가지고 있는 반면, $110^{\circ}C$에서 측정한 시편의 경우 2차 균열들이 명확하게 발달하지 못하였다. 서로 다른 온도에서 인장강도의 차이는 인장시 발달된 결정화도와 균열 끝 부분에서 형성된 미세 균열 형상과 관계가 있는 것으로 보인다.

• 대한기계학회논문집A
• /
• 제35권9호
• /
• pp.999-1005
• /
• 2011

고무복합재료에 대해 변형에 의한 결정화(SIC)가 기계적 특성에 미치는 영향을 연신율(${\lambda}$) 및 다중벽 탄소나노튜브(CNT)와 카본블랙(CB)의 함유량을 함수로 하여 연구하였다. 시차 주사 열량(DSC) 분석을 통해 CB 및 CNT의 함유량에 따라 결정화 정도가 증가함을 확인 하였다. 또한 연신율이 증가함에 따라 복합재료의 유리전이온도(Tg)는 증가하였고, 결정화 잠열 값(LHc)은 ${\lambda}$=1.5에서 최대값을 보였다. CNT의 함유량 증가에 따라 기계적 특성과 LHc는 비례관계임을 확인하였다. 열 중량 분석(TGA)을 통해 기지의 소실율은 94.3%였고, 복합재료의 소실율은 보강재의 함유량 증가에 따라 감소하였다. 인장탄성율 비는 고무 내의 CNT 배향으로 인장강도 비보다 높게 나타났다.

• Applied Microscopy
• /
• 제45권2호
• /
• pp.44-51
• /
• 2015

At room temperature, metallic glasses deform inhomogeneously by strain localization into narrow bands as a result of yielding due to an external force. When shear bands are generated during deformation, often nanocrystals form at the shear bands. Experimental results on the deformation of bulk metallic glass in the current study suggest that the occurrence of nanocrystallization at a shear band implies the loading condition that induces deformation is more triaxial in nature than uniaxial. Under a compressive stress state, the geometrical constraint strain imposed by the stress triaxiality plays a crucial role in the deformation-induced nanocrystallization at the shear bands.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2012년도 춘계학술대회 논문집
• /
• pp.585-586
• /
• 2012

• 한국주조공학회지
• /
• 제28권1호
• /
• pp.31-36
• /
• 2008

Ti-Ni-Cu alloys are very attractive shape memory alloys for applications as actuators because of a large transformation elongation and a small transformation hysteresis. Rapidly solidified Ti-Ni alloy ribbons have been known to have the shape memory effect and superelasticity superior to the alloy ingots fabricated by conventional casting. In this study, solidification structures and shape memory characteristics of $Ti-Ni_{30}-Cu_{20}$ alloy ribbons prepared by melt spinning were investigated by means of DSC and XRD. Operating parameters to fabricate the amorphous ribbons were the wheel velocity of 55 m/s and the melt spinning temperature of $1500^{\circ}C$. The crystallization temperature was measured to be $440^{\circ}C$. The crystallized ribbons exhibited very fine microstructure after annealing at $440^{\circ}C$ for 10 minutes and $460^{\circ}C$ for 5 minutes and was deformed up to about 6.8% and 6.23% in ductile manner, respectively. Stress-strain curve of the ribbon exhibited a flat stress-plateau at 64 MPa and this is associated with the stress-induced a B2-B19 martensitic transformation. During cycle deformation with the applied stress of 220 MPa, transformation hysteresis and elongation associated with the B2-B19 transformation were observed to be $4.3^{\circ}C$ and 3.6%.

• 소성∙가공
• /
• 제32권5호
• /
• pp.239-246
• /
• 2023

To reduce the forming load due to the temperature drop, during the hot forging process, a reheating hot forging process design is required that to repeat heating and forging. However, if the critical strain required for recrystallization is not induced during forging and grain growth becomes dominant due to the reduction in dislocation density due to repeated heating, the mechanical properties may deteriorate. Therefore, in this study, Inconel 706 alloy was applied, and the grain refinement behavior was comparatively analyzed according to the number of reheating times and effective strain during reheating hot forging process. Reheating was carried out with a total compression rate of 40% up to 4 times. The Inconel 706 compression test specimens heated once showed finer grains as the effective strain increased due to the dynamic recrystallization phenomenon. However, as the number of heating increases, grain refinement was observed even in a low effective strain distribution of 0.43 due to static recrystallization during reheating. Moreover, grain growth occurs at a relatively low effective strain of 0.43 when the number of reheating is four or more. Therefore, it was effective to apply an effective strain of 0.43 or more during hot forging to Inconel 706 in order to induce crystallization through grain refinement and improve the properties of forged products. In addition, we could notice that up to three reheating times condition was appropriate to prevent grain growth and maintain fine grain size.

• Tribology and Lubricants
• /
• 제11권1호
• /
• pp.37-43
• /
• 1995

Sputtering parameters such as N$_{2}$ flow percentage and bias voltage in reactive TiN film deposition by RF magnetron sputtering system were selected to investigate the effects of sputtering deposition conditions on tribological characteristics of TiN films. Wear scar of the steel ball damaged by TiN films was measured by SEM to understand wear behavior of deposited TiN films. Crystallization and induced strain of TiN were detected by XRD. Wear mode changed from plastic to brittle with increasing N$_{2}$ ratio. Wear scar by sliding with TiN film deposited at around 27% N$_{2}$ ratio was maximum. The results indicate that bias voltage affects tribological behavior by formation of high density film and internal stress.