• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.377-380
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• 2008

Ground state structures and ring flipping transition states of eight- and seven-membered silicon containing heterocyclic compounds such as dithienodisilacyclooctatriene and oxadithienodisilacycloheptadiene derivatives, respectively have theoretically been investigated. Although the bithienylene moiety of the derivatives does not change the ground state structures, they significantly increase the ring flipping barrier by 13-17 kcal/mol in the case of the eight-membered rings (2, 3, and 4) in comparison with that of silicon containing heterocyclic compound 6, chosen as a model. The same moiety increases the flipping barrier of seven-membered ring (5) is only slightly (3.3 kcal/mol) in comparison with that of model compound 7. Hence, it has been concluded that not only the existing ring strain of eight-membered ring but also the bithienylene moiety collectively increases the ring flipping barrier so as to prevent such conformational changes explaining anomalous NMR behaviour of dithienodisilacyclooctatriene derivatives (2-4). In contrast, the effect of substituents R1 and R2 at the olefinic carbons of the eight-membered ring on the flipping barrier turned out to be mild.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.2
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• pp.120-124
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• 2016

In this study, we fabricate transparent and bendable a-IGZO (amorphous indium gallium zinc oxide) TFTs (thin-film transistors) with a-IZO (amorphous indium zinc oxide) transparent electrodes on plastic substrates and investigate their electrical characteristics under bending states. Our a-IGZO TFTs show a high transmittance of 82% at a wavelength of 550 nm. And these TFTs have an $I_{on}/I_{off}$ ratio of $1.8{\times}10^8$, a field effect mobility of $15.4cm^2/V{\cdot}s$, and a subthreshold swing of 186 mV/dec. The good electrical characteristics are retained even after bending with a curvature radius of 18 mm corresponding to a strain of 0.5% owing to mechanical durability of the transparent electrodes used in this study.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.3
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• pp.101-110
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• 1996

The aim of the work described in this paper is to develope a constitutive model for the prediction of an unsaturated clayey soil and to confirm the application of the model. To this end a series of suction controlled isotropic and triaxial compression tests are conducted on clayey soils. Matric suction is controlled by the axis translation technique using high air entry ceramic disk. Total volume change, air and water volume changes are measured by the device made for the experiment. The specimens are compacted by dynamic compaction using a half of Proctor compaction energy with the water contents of 5% drier than the optimum moisture contents. From test results, volume changes and deviator stresses are analyzed at each state and their relationships are formulated. And the application of the model to clayey soils is confirmed by the comparison between test and predicted results. During drying-wetting and loading-unloading processes for isotropic states, the agreement between predicted and test results are satisfactory. And predicted deviator stresses are well agreed with the test results in shearing process, but volumetric strain is not well agreed with the test results in high suctions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.6 no.2
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• pp.183-194
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• 2002

A general procedure to evaluate the sensitivity of design variables to stresses and strains in PSC flexural members is proposed. To accomplish the purpose of this study, long-term losses including creep, shrinkage, and PS steel relaxation are formulated based on the equilibrium states of the deformed sectional geometry. Thereby, the formulation follows the basic steps which consider the fundamental formulas adopted by CEB-FIP, ACI, and KCI rather than the age adjusted effective modulus concept. Twenty-one design variable including the material and geometrical properties of concrete, nonprestressing steel and prestressing steel, and the geometry of the cross section are considered in the sensitivity analysis. The gradients of the stresses and strains needed for the sensitivity assessment are calculated in a closed format. The derived formulation is applied to the T-type section PSC beam with prestressing and nonprestressing steels for the sensitivity analysis. The analytically calculated sensitivity results are compared with those numerically calculated to ensure the validity of the proposed procedure.

• Journal of the Korean Chemical Society
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• v.10 no.1
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• pp.18-24
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• 1966

In formulating the Transient State Theory of Significant Liquid Structure it is assumed that there exist holes of molecular size in liquids and that the liquid state is partitioned in three states, namely, solid-like state, representing the molecules apart from holes; gas-like state, representing the molecules jumping into the holes; and the transient state, representing the molecules in a possible state of jumping into the holes by aquiring the strain energy due to the holes. It is found that the partition function derived according to the proposed theory can be applied to the liquids of argon, nitrogen, benzene, chloroform, and carbon disulfide with good accuracy.

• Journal of the Society of Naval Architects of Korea
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• v.52 no.2
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• pp.143-152
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• 2015

In the present study, the fiber and matrix failure of composite laminates under arbitrary biaxial stresses were evaluated based on separate mode criteria such as Hasnin and Puck theories. There is a limitation to predict the fiber-dominant and/or matrix-dominant failures under arbitrary stress states using limit criteria (maximum stress and maximum strain theories) and interactive criteria (Tsai-Hill and Tsai-Wu theories). There is little literature for failure analysis of ships and offshore composite structures considering advanced failure theories such as Hashin and Puck theories. Furthermore, there is not enough practical commercial finite element analysis (FEA) code which is basically adopted the separate mode criteria. Hence, in the present study, the user-defined subroutine of commercial FEA code ABAQUS for evaluation of fiber and matrix failures of composite structures was developed based on Hashin and Puck failure criteria. And then, the proposed subroutine was validated by comparing with a series of experimental results of carbon- and glass-implemented composite laminates to guarantee the reliability and usefulness of the developed method.

• Journal of Microbiology and Biotechnology
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• v.33 no.4
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• pp.419-429
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• 2023

Ultraviolet C (UV-C, 200-280 nm) light has germicidal properties that inactivate a wide range of pathogenic and spoilage microorganisms. UV-C has been extensively studied as an alternative to thermal decontamination of fruit juices. Recent studies suggest that the efficacy of UV-C irradiation in reducing microorganisms in fruit juices is greatly dependent on the characteristics of the target microorganisms, juice matrices, and parameters of the UV-C treatment procedure, such as equipment and processing. Based on evidence from recent studies, this review describes how the characteristics of target microorganisms (e.g., type of microorganism/strain, acid adaptation, physiological states, single/composite inoculum, spore, etc.) and fruit juice matrices (e.g., UV absorbance, UV transmittance, turbidity, soluble solid content, pH, color, etc.) affect the efficacy of UV-C. We also discuss the influences on UV-C treatment efficacy of parameters, including UV-C light source, reactor conditions (e.g., continuous/batch, size, thickness, volume, diameter, outer case, configuration/arrangement), pumping/flow system conditions (e.g., sample flow rate and pattern, sample residence time, number of cycles), homogenization conditions (e.g., continuous flow/recirculation, stirring, mixing), and cleaning capability of the reactor. The collective facts indicate the immense potential of UV-C irradiation in the fruit juice industry. Existing drawbacks need to be addressed in future studies before the technique is applicable at the industrial scale.

• Advances in nano research
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• v.14 no.6
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• pp.575-590
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• 2023

Many of small-scale devices should be designed to tolerate high temperature changes. In the present study, the states of buckling and stability of nano-scale cylindrical shell structure integrated with piezoelectric layer under various thermal and electrical external loadings are scrutinized. In this regard, a multi-layer composite shell reinforced with graphene nano-platelets (GNP) having different patterns of layer configurations is modeled. An outer layer of piezoelectric material receiving external voltage is also attached to the cylindrical shell for the aim of observing the effects of voltage on the thermal buckling condition. The cylindrical shell is mathematically modeled with first-order shear deformation theory (FSDT). Linear elasticity relationship with constant thermal expansion coefficient is used to extract the relationship between stress and strain components. Moreover, minimum virtual work, including the work of the piezoelectric layer, is engaged to derive equations of motion. The derived equations are solved using numerical method to find out the effects of temperature and external voltage on the buckling stability of the shell structure. It is revealed that the boundary condition, external voltage and geometrical parameter of the shell structure have notable effects on the temperature rise required for initiating instability in the cylindrical shell structure.

• Structural Engineering and Mechanics
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• v.84 no.2
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• pp.285-293
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• 2022

Lumped damage mechanics (LDM) is a recent nonlinear theory with several applications to civil engineering structures, such as reinforced concrete and steel buildings. LDM apply key concepts of classic fracture and damage mechanics on plastic hinges. Therefore, the lumped damage models are quite successful in reproduce actual structural behaviour using concepts well-known by engineers in practice, such as ultimate moment and first cracking moment of reinforced concrete elements. So far, lumped damage models are based in the strain energy equivalence hypothesis, which is one of the fictitious states where the intact material behaviour depends on a damage variable. However, there are other possibilities, such as the energy equivalence hypothesis. Such possibilities should be explored, in order to pursue unique advantages as well as extend the LDM framework. Therewith, a lumped damage model based on the energy equivalence hypothesis is proposed in this paper. The proposed model was idealised for reinforced concrete structures, where a damage variable accounts for concrete cracking and the plastic rotation represents reinforcement yielding. The obtained results show that the proposed model is quite accurate compared to experimental responses.

• Journal of the Earthquake Engineering Society of Korea
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• v.28 no.4
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• pp.223-231
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• 2024

For the OPR1000, a standard power plant in Korea, an analytical model of the containment building considering voids and deterioration was built with multilayer shell elements. Voids were placed in the vulnerable parts of the analysis model, and the deterioration effects of concrete and rebar were reflected in the material model. To check the impact of voids and deterioration on the seismic performance of the containment building, iterative push-over analysis was performed on four cases of the analytical model with and without voids and deterioration. It was found that the effect of voids with a volume ratio of 0.6% on the seismic performance of the containment building was insignificant. The effect of strength reduction and cross-sectional area loss of reinforcement due to deterioration and the impact of strength increase of concrete due to long-term hardening offset each other, resulting in a slight increase in the lateral resistance of the containment building. To determine the limit state that adequately represents the seismic performance of the containment building considering voids and deterioration, the Ogaki shear strength equation, ASCE 43-05 low shear wall allowable lateral displacement ratio, and JEAC 4601 shear strain limit were compared and examined with the analytically derived failure point (ultimate point) in this study.