• Title/Summary/Keyword: Sterols

Search Result 241, Processing Time 0.023 seconds

The Origin of Molluscs Sterol (1) The Sterol Compositon of Bivalves and Snails (연체동물의 스테롤의 기원에 관하여 (1) 2매패와 권패의 스테롤 조성의 차이)

  • JOH Yong Goe;KIM Yong Keun
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.9 no.3
    • /
    • pp.185-193
    • /
    • 1976
  • The sterol compositions of the Pelecypoda, M. sultataria, S. sachalinensis, and the Gastropoda, H. discus hannai Inc, T. cornutus were investigated. The results areas follows: 1. The contents of the unsaponifiables and sterols of the Pelecypoda, M. sulcataria, S. sathalinensis, and the Gastropoda, H. discus hannai Ino, T. cornutus, are $12.0\%,\;11.8\%,\;and\;16.2\%,\;15.3\%$, respectively. 2. The complex sterols from the Pelecypoda and Gastropoda are well separated on Silica Gel HF 254 TLC impregnated with $15\%$ silver nitrate. 3. The prominent sterols of the Pelecypoda, M. sulcateria and S. sachalinensis, are 22-trans-24-norcholesta-5, $22-dien-3\beta-ol$ $3.0\%\;3.9\%$ 22-dehydrocholesterol $6.7\%,\;10.2\%$, cholesterol $39.0\%,\;48.6\%$ brassicasterol $14.1\%,\;13.8\%$ 24-methylenecholesterol $19.4\%,\;11.5\%$, stigmasterol $2.4\%,\;0\%$ $\beta-sitosterol\;10.5\%,\;11.9\%$, and fucosterol $4.3\%,\;0\%$. 4. Abalone, H. discus hannai Ino, and T. cornutus contain cholesterol $98.0\%,=97.5\% as main component with small amounts of 22-dehydrocholesterol, brassicasterol and desmosterol. In H. discus hannai rno, 24-methylenecholesterot and fucosterol are also found.

  • PDF

Chlorosmaridione; A Novel Chlorinated Diterpene Quinone Methide from Rosemarinus officinalis L.

  • El-Lakany, Abdalla M.
    • Natural Product Sciences
    • /
    • v.10 no.2
    • /
    • pp.59-62
    • /
    • 2004
  • A novel chlorinated diterpene quinone methide; chlorosmaridione (7-chloro-11-hydroxy-abeita-7,9(11),13-triene-6,12-diode) was isolated from petroleum ether extract of the stems of Rosemarinus officinalis L. growing in Egypt. In addition, ${\beta}-sitosterol$, stigmasterol, lupeol acetate, ${\alpha}-amyrin,\;{\beta}-amyrin$, lupeol, acetyloleanolic acid, acetylursolic acid taxodione, horminone, and cryptotanshinone were also identified. Chemical structures of the isolated compounds have been elucidated on the bases of physical, chemical, and spectral data including IR, UV, MS, 1D-and 2D-NMR spectra.

Sterols and Steryl glycosides from the Root of Codonopsis pilosula (만삼의 Sterol 및 Steryl glycoside에 관한연구)

  • Lee, Ihn-Rhan;Kim, Young-Hee;Park, Sung-Bae
    • Korean Journal of Pharmacognosy
    • /
    • v.13 no.3
    • /
    • pp.129-131
    • /
    • 1982
  • From the roots of Codonopsis pilosula (Franch.) Nannfeldt (Campanulaceae), ${\alpha}$-spinasterol, mp $165{\sim}7^{\circ}$ and alpha-spinasteryl D-glucoside, mp $283{\sim}5^{\circ}$, were isolated and identified on the basis of chemical and spectral data. Spectral data showed that $\Delta^7-stigmasterol$ and its glucoside were contained as minor components.

  • PDF

Studies on the Constituents of the Roots of Rubus parvifolius (I) -Isolation of (-)-Epicatechin- (멍석딸기뿌리의 성분(成分)에 관한 연구(硏究)( I ) -(-)-Epicatechin의 분리(分離)-)

  • Do, Jae-Chul;Son, Kun-Ho;Kang, Sam-Sik
    • Korean Journal of Pharmacognosy
    • /
    • v.19 no.3
    • /
    • pp.170-173
    • /
    • 1988
  • (-)-Epicatechin, $mp\;234{\sim}6^{\circ}$, was isolated from the fresh roots of Rubus parvifolius together with a sterol mixture, which was found to be a mixture of ${\beta}-sitosterol\;(major)$, stigmasterol and campesterol.

  • PDF

The Conversion of Lithocholic Acid into 5$\beta$-Androstan-3, 17-dione in the Cell-free System of Mycobacterium sp. NRRL B-3805

  • Lee, Kang-Man;Park, Hye-Kyung
    • Archives of Pharmacal Research
    • /
    • v.14 no.3
    • /
    • pp.261-265
    • /
    • 1991
  • In a microbial cell-free extract system, side chain cleavage on various sterols and steroids was tested. The cell-free extracts of Mycobacterium sp. NRRL B-3805 showed the side chain cleavage activity on lithocholic acid to form 5$\beta$-androstan-3.17-dione. The properties of the activity were examined.

  • PDF

Studies on the Lipid Classes of Nicotiana tabacum L. Seed Oil

  • Waheed, Amran;Mahmud, Shahid;Javed, Muhammad Akhtar;Saleem, Muhammad
    • Natural Product Sciences
    • /
    • v.7 no.4
    • /
    • pp.110-113
    • /
    • 2001
  • The lipid classes constituents; hydrocarbons, wax esters, sterol esters, triacylglycerols, free fatty acids, 1,3-diacylglycerols, 1,2-diacylglycerols, free sterols, 2-monoacylglycerols, 1-monoacylglycerols, phosphatidylethanolamines, phosphatidylcholines, lysophosphatidylethanolamines and phosphatidylinositols of Nicotiana tabacum L. seeds oil were investigated by thin layer and gas chromatography. Palmitic, oleic and linoleic acids were the major components in all lipid classes studied.

  • PDF

Conversion of Plant Sterols to Androsta-4-ene-3,17-dione by a mutant of Mycobacterium sp. NRRL B-3805 (Mycobacterium종 (NRRL B-3805)의 변이종에 의한 식물스테롤의 androsta-4-ene-3,17-dione(AD)으로의 전환)

  • 이강업
    • Korean Journal of Microbiology
    • /
    • v.28 no.4
    • /
    • pp.351-363
    • /
    • 1990
  • A mutant was selected by NTG treatment of Mycobacterium sp. NRRL B-3805, which was capable of degrading plant sterol to androsta-4-ene-3, 17-dione and yields was higher than NRRL B-3805. Also this mutant produced androst-4-ene-3, 17-dione faster than NRRL B-3805. It described the mode of sitosteroidal degradation, and the interrelation between cell membrane and its attachment to substrate during the sterol degradation process by this mutant and it was compared with Mvcobacterium sp. NRRL B-3805.

  • PDF

Nature of the Hydrogen Chloride Induced Isomers of $\alpha$-Spinasterol

  • Woo, Won-Sick;Kang, Sam-Sik
    • YAKHAK HOEJI
    • /
    • v.18 no.3
    • /
    • pp.217-227
    • /
    • 1974
  • It was established that .alpha.-spinasterol (I) was isomerized by hydrogen chloride to a mixture of two isomers. These isomers were separated into each of components and identified as .DLETA.$^{8(14),22}$ -stigmastadienol (III) and ${\delta}$$^{14,22}$ -stigmastadienol (IV), respectively. The mass spectra of these compounds were found to be particularly suitable to idetify the position of nuclear double bond of sterols possessing 22 : 23 -double bond in side chain.

  • PDF

Terpenoids from the Aerial Parts of Aster glehni (섬쑥부쟁이의 테르페노이드 성분)

  • 민용득;권학철;최상진;이강노
    • YAKHAK HOEJI
    • /
    • v.48 no.1
    • /
    • pp.65-69
    • /
    • 2004
  • The chromatographic separation of MeOH extract of the aerial parts of Aster glehni (Compositae) led to the isolation of three sesquiterpenes, two sterols and four terpenes. Their structures were determined to be $\beta$-amyrin acetate (1), phytol (2), alismol (3), $\alpha$-tocopheryl quinone (4), $\alpha$-spinasterol (5), 10-O-methyl alismoxide (6), alismoxide (7), and 3-O-(6'-O-palmitoyl-$\beta$-D-glucosyl)-spinasta 7,22-diene (8) by physicochemical and spectroscopic methods . These compounds (1-8) were first isolated from the Aster glehni.