• Resources Recycling
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• v.18 no.2
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• pp.51-55
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• 2009

Sawdust and sewage sludge and PE gasification by high temperature steam of Brown gas have been performed in this study. Steam/carbon ratio has been changed from 1 to 5 and the effect of steam/carbon ratio on the produced gas concentrations, gasification rate and tar generation has been determined. Also, the temperature distribution in the gasification reactor has been studied. Highest combustible content in the produced gas is around 70vol% and $H_2$ shows highest content among the combustible compounds. However, the heating value of the produced gas and tar content have been reduced with increasing steam/carbon ratio.

• Resources Recycling
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• v.30 no.6
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• pp.12-18
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• 2021

The water-gas shift reaction is the subsequent step using steam for hydrogen enrichment and H₂/CO ratio-controlled syngas from gasification. In this study, a water-gas shift reaction was performed using syngas from an RPF gasification system. The water-gas shift using a catalyst was performed in a laboratory-scale tube reactor with a high temperature shift (HTS) and a low temperature shift (LTS). The effects of the reaction temperature, steam/carbon ratio, and flow rate on H₂ production and CO conversion were investigated. The operating temperature was 250-400℃ for the HTS system and 190-220℃ for the LTS system. Steam/carbon ratios were between 1.5 and 3.5, and the composition of reactant was CO : 40 vol%, H₂ : 25 vol%, and CO₂ : 25 vol%. The CO conversion and H₂ production increased as the reaction temperature and steam/carbon ratio increased. The CO conversion and H₂ production decreased as the flow rate increased due to reduced retention time in the catalyst bed.

• Applied Chemistry for Engineering
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• v.20 no.2
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• pp.186-190
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• 2009

This study is purposed to analyze thermodynamic properties on the hydrogen production by dimethyl ether steam reforming. Various reaction conditions of temperatures (300~1500 K), feed compositions (steam/carbon = 1~7), and pressures (1, 5, 10 atm) were applied to investigate the effects of the reaction conditions on the thermodynamic properties of dimethyl ether steam reforming. An endothermic steam reforming competed with an exothermic water gas shift reaction and an exothermic methanation within the applied reaction condition. Hydrogen production was initiated at the temperature of 400 K and the production rate was promoted at temperatures exceeding 550 K. An increase of steam to carbon ratio (S/C) in feed mixture over 1.5 resulted in the increase of the water gas shift reaction, which lowered the formation of carbon monoxide. The maximum hydrogen yield with minimizing loss of thermodynamic conversion efficiency was achieved at the reaction conditions of a temperature of 900 K and a steam to carbon ratio of 3.0.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.29-31
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• 2012

The effects of combustion parameters on the characteristics of a steam-methane reformer. The reformer system was numerically simulated using a simplified two-dimensional axisymmetric model domain with an appropriate user-defined function. The fuel ratio, defined as the ratio of methane flow rate in the combustor to that in the reactor, was varied from 20 to 80%. The equivalence ratio was changed from 0.5 to 1.0. The results indicated that as the fuel ratio increased, the production rates of hydrogen and carbon monoxide increased, although their rates of increase diminished. In fact, at the highest heat supply rates, hydrogen production was actually slightly decreased. Simulations showed that equivalence ratio of 0.7 yielded the highest steam-methane mixture temperature despite a 43% higher air flow rate than the stoichiometric flow rate. This means that the production of hydrogen and carbon monoxide can be increased by adjusting the equivalence ratio, especially when the heat supply is insufficient.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.1
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• pp.19-24
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• 2018

Fuel cells are used to generate electricity with a reformer. In particular, methanol has various advantages among the fuels for reformer. Methanol steam reformer devices can efficiently supply hydrogen to PEM fuel cell. This study investigated the optimal operation conditions of a methanol steam reforming process. For this purpose, aspen HYSYS was used for the optimization of reforming process. The optimal operating condition could be designed by setting independent variables such as temperature, pressure and steam to carbon ratio (SCR). The optimal temperature and steam to carbon ratio were $250-270^{\circ}C$ and 1.3-1.5, respectively. It is advantageous to operate at a pressure of 15-20 barg, considering the performance of the hydrogen purifier. In addition, a heat exchange network was designed to supply heat constantly to reformer through the latent heat of steam.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.700-704
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• 2009

A simulation study on SCR(steam carbon dioxide reforming) in gas-to-liquid(natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for SCR experiment. Optimum operating conditions for SCR process were determined by changing reaction variables such as temperature and $CH_4/steam/CO_2$ feed ratio. Simulation was carried out by Aspen Plus. During the simulation, overall process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS(Redlich-Kwong-Soave) equation. Optimum simulation variables such as temperature and feed ratio were determined by considering $H_2/CO$ ratio for FTS(Fischer-Tropsch synthesis), $CH_4$ conversion, and $CO_2$ conversion. Simulation results showed that optimum reaction temperature and $CH_4/steam/CO_2$ feed ratio in SCR process were $850^{\circ}C$ and 1.0/1.6/0.7, respectively. Under optimum temperature of $850^{\circ}C$, $CH_4$ conversion and $CO_2$ conversion were found to be 99% and 49%, respectively.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.243-247
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• 2009

This study is purposed to analyze thermodynamic properties on the hydrogen production by ethylene glycol steam reforming. Various reaction conditions of temperatures(300~1,600 K), feed compositions(steam/carbon= 0.5~4.5), and pressures(1~30 atm) were applied to investigate the effects of the reaction conditions on the thermodynamic properties of dimethyl ether steam reforming. An endothermic steam reforming competed with an exothermic water gas shift reaction and an exothermic methanation within the applied reaction condition. Hydrogen production was initiated at the temperature of 400 K and the production rate was promoted at temperatures exceeding 500 K. An increase of steam to carbon ratio(S/C) in feed mixture over 1.0 resulted in the increase of the water gas shift reaction, which lowered the formation of carbon monoxide. The maximum hydrogen yield with minimizing loss of thermodynamic conversion efficiency was achieved at the reaction conditions of a temperature of 900 K and a steam to carbon ratio of 3.0.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2015-2020
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• 2007

Diesel is an excellent candidate fuel for fuel cell applications due to its high hydrogen density and well-established infrastructure. But, it is hard to guarantee desirable performance of diesel reformer because diesel reforming has several problems such as sulfur poisoning of catalyst and carbon deposition. We have been focusing on diesel autothermal reforming(ATR) for substantial period. It is reported that ATR of diesel has several technical advantages such as relatively high efficiency and fuel conversion compared to steam reforming(SR) and partial oxidation(POX). In this paper, we investigate characteristics of diesel reforming under various ratios of reactants(oxygen to carbon ratio, steam to carbon ratio) for improvement of reforming performances(high reforming efficiency, high fuel conversion, low carbon deposition). We also exhibit calculated heat balance of autothermal reformer at each condition to help thermal management of SOFC system.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.91.1-91.1
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• 2010

The Reforming system is an effective method to generate hydrogen which uses for fuel cell system. The purpose of this study is to present characteristics of an autothermal reformer at various operating conditions and to investigate ideal conditions for reforming efficiency. Dominant chemical reactions are Full Combustion, Steam Reforming reaction, Water-Gas Shift reaction and Direct Steam Reforming reaction. Operating parameters of the autothermal reformer are inlet temperature, Oxygen to Carbon Ratio, Steam to Carbon Ratio and Gas Hourly Space Velocity. Autothermal reformer is filled with catalysis of a packbed-bed type. Using numerical approach, we have investigated on various reaction conditions.

• Resources Recycling
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• v.16 no.6
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• pp.28-33
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• 2007

Coal is the most abundant energy source and deposited in every area of world. Combustion process with lower efficiency has been mainly used. Therefore, implementation of more efficient technologies, involving gasification, combined cycles and fuel cells, would be a key issue in the plans for more efficient power generation. In these technologies, gasification has been studied for decades. However, coal gasification to high value combustible gas such as hydrogen and carbon monoxide is focused again due to high oil price. The gaseous product, called syngas, can be effectively utilized in a variety of ways ranging from electricity production to chemical industry (as feedstock). In this study, coal gasification with ultra high temperature steam has been performed. The effect of steam/carbon ratio on the produced gas concentrations, gasification rate and additional products like tar, ammonia and cyan compounds has been determined.