• Journal of Hydrogen and New Energy
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• v.22 no.3
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• pp.386-401
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• 2011

Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.3
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• pp.403-407
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• 2016

In general, drum-type boilers are designed for base load duty and applied under constant pressure operation mode. Recently, however conditions often occur that even drum-type boilers have to operate at partial load conditions. A feasibility study on adopting the sliding pressure operation for drum-type boiler was conducted, and corresponding performance changes and effects on the equipment were analyzed by utilizing a process simulation model. As a result, the conclusion was reached that drum type boilers are able to adopt the sliding pressure operation and can improve of net efficiency at part load operation in spite of the Rankine cycle efficiency reduction due to the decreases in main steam pressure. Because of thank to improvement of high pressure turbine stage-1 internal efficiency and power savings of boiler feed water pump. The sliding pressure operation is advantageous in terms of stress level relief for boiler tube as well as maintaining the rating steam temperature at part load condition. However, cautions are required because the drum boilers have poor dynamic response characteristics which may get worse during the sliding pressure operation.

• Journal of Hydrogen and New Energy
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• v.18 no.4
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• pp.382-390
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• 2007

To check the feasibility of SMART(Steam Methane Advanced Reforming Technology) system, an experimental investigation was performed. A fluidized bed reactor of diameter 0.052m was operated cyclically up to 10th cycle, alternating between reforming and regeneration conditions. FCR-4 catalyst was used as the reforming catalyst and calcined limestone(domestic, from Danyang) was used as the $CO_2$ absorbent. Hydrogen concentration of 98.2% on a dry basis was reached at $650^{\circ}C$ for the first cycle. This value is much higher than $H_2$ concentration of 73.6% in the reformer of conventional SMR (steam methane reforming) condition. The hydrogen concentration decreased because the $CO_2$ capture capacity decreased as the number of cycles increased. However, the average hydrogen concentration at 10th cycle was 82.5% and this value is also higher than that of SMR. Based on these results, we could conclude that the SMART system can replace SMR system to generate pure hydrogen without HTS (high tempeature shift), LTS (low temperature shift) and $CO_2$ separation process.

• Journal of the Korean Chemical Society
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• v.15 no.2
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• pp.55-63
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• 1971

In this study, several nickel catalysts for the steam-hydrocarbon reforming process were prepared from various nickel salt, magnesium oxide, alumina and kaolinite. The activity and strength of the catalysts were investigated. 1. The proper composition of the calcined catalysts are: NiO (5-15%)-MgO(10-20%)-$Al_2O_3$(10-40%)-Kaolinite(50-80%). 2. The admixed or cosedimented ingredients of the catalysts was pelletized and calcinated at 1000 or $1150^{\circ}C$. Calcination at $1150^{\circ}C$ for an hour was optimum. 3. The water to oil ratio (W/O) for reforming of hexane should be above 7 mole/mole. As the W/O increases, more carbon dioxide and hydrogen, but less carbon monoxide was produced. Also carbon deposition become lessen at higher W/O. 4. Maximum conversion had attained at about $850^{\circ}C$. As the reaction temperature increases, more carbon monoxide and hydrogen, but less carbon dioxide and lower hydrocarbon was produced. 5. The percent conversion at $850^{\circ}C$ was about 80%, using a catalyst which the nickel oxide content are 5%.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2221-2226
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• 2008

The objective of this paper is to describe the experimental and numerical investigation of the analysis of the heat transfer in a solar chemical reactor. These are compared about methane steam reforming process in the solar chemical reactor which was a volumetric absorber consisting of honeycomb and a multilayered catalyst supports. With this high operating temperature, convective heat loss, thermal fracture are important features for designing SCR. In order to estimate the system performance and to design the actual solar reactor with various conditions, CFD analysis was used in this study. The nickel oxide porous metal is inserted inside the solar chemical reactor to increase the conversion rate of the reforming reaction. Simulation has been carried out based on the experimental data. According to the simulation results, the optimum methane-steam mole ratio and thickness and numbers of catalyst supports were obtained.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.225-229
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• 2005

We have designed micro-fuel processor system, which consists of a steam reforming area and a PROX(preferential oxidation) area. Micro-fuel processor system generates $H_2$ rich gas from a methanol. In our experiment, we have integrated micro-fuel processor system using low temperature cofired ceramics (LTCC) process because LTCC is superior to other materials principally due to their high thermal and chemical stability, simpler fabrication processes, and lower materials cost. Therefore, we have studied and integrated micro-fuel processor system containing embedded heaters, cavities, and 3D structures of micro-channel with LTCC. Also we have optimized the LTCC process.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2004.04a
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• pp.127-139
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• 2004

The process of papermaking involves water removal on the paper machine wire, in the press section and in the dryer section. In the dryer section, liquid water in the wet web is removed mainly by evaporation. In conventional machine this is achieved by passing the web over a number of steam heated dryer rolls. A drying process of paper on a heated cylinder roll calculated based on a 1-dimensional model which concerns unsteady heat and mass transfer in the direction of paper thickness. In this study, Prediction of moisture contents average paper sheet temperature and volume fraction along a series of cylinder. Independently, developed models is compared using the same reference data. The model is implemented in CFD code, FLUENT, using user-define-function(UDFs).

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.41-46
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• 2003

Until now, the quantity to recycle wasted concrete as the great supplementary value was very little. But considering a insufficiency of the present state of aggregates, the recycling of wasted aggregates is indispensable. This study will offer the basic application data of the recycled aggregates to make by the new attempt and offer the basic data of the great supplementary value of recycled aggregate to make good use of precast process. The result of compressive strength, tensile strength, flexural strength and drying shrinkage test of concrete by recycled aggregates were similar to the property of normal aggregate concrete, and the contrary effect of recycled aggregate by high temperature steam curing do not have been found out. Therefore the great supplementary value of recycled aggregate to make good use of precast process is possible way to be helpful to a insufficiency of the present state of aggregates.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.4
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• pp.57-67
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• 2003

The purpose of the present study is to identify the drying cylinder model in paper plants and to analyze characteristics of process responses for changes in input variables. The model developed in this work is based on actual plant operation data and the steam pressure applied to the cylinder behaves as one the main variables. It is found that heat transfer coefficients from the condensate to the canvas could be represented as empirical relations based on heat conductivities and operation date. The effectiveness of the cylinder model is demonstrated by the measured moisture contents and web temperature. Using transfer functions derived from the cylinder model stability of the drying process is analyzed.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.62-66
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• 2009

Utilization and interest of unconventional fuel and process residue such as oil sand and its residue, oil sand coke, have been increased because of the continuous rise of fuel price and conventional fuel availability. In this study, the gasification of oil sand coke produced from coking process of oil sand was performed to utilize as an energy resource using lab-scale fixed bed gasification system. The combustion characteristics of oil sand bitumen and oil sand coke were investigated by using TGA and lab-scale gasification system was applied to reveal the characteristics of produced syngas composition with oxygen/fuel ratio, temperature and steam injection rate. Oil sand coke shows a high carbon content, heating value and sulfur content and low ash content and reactivity. In case of oil sand coke gasification, generally with increasing temperature, the amount of steam introduced and decreasing oxygen injection rate, $H_2$ content in product gas increased while the $CO_2$ content decreased. The calorific value of syngas shows about $2100kcal/Nm^3$ and this result indicates that the oil sand coke can be used as a resource of hydrogen and fuel.