• 신재생에너지
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• 제20권1호
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• pp.126-134
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• 2024

Biogas, composed mainly of methane (CH₄) and carbon dioxide (CO₂), is a renewable gas that can serve as an alternative energy source. In this study, we developed a new microwave reformer and analyzed its reforming characteristics. We observed that higher temperatures of the microwave receptor led to increased reforming efficiency. By supplying appropriate amounts of methane and steam, we could prevent carbon generated from the thermal decomposition reaction of carbon dioxide from depositing on the catalytic active layer, thus avoiding the inhibition of catalytic activity. Hydrogen generation was enhanced when maintaining the biogas ratio and steam supply at adequate levels. Increasing the SiC ratio in the receptor improved the uniformity of temperature distribution and growth rate, resulting in higher conversion rates of the reforming process.

• 한국수소및신에너지학회논문집
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• 제24권1호
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• pp.12-19
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• 2013

A gasification process with pre-combustion $CO_2$ capture process, which converts coal into environment-friendly synthetic gas, might be promising option for sustainable energy conversion. In the coal gasification for power generation, coal is converted into $H_2$, CO and $CO_2$. To reduce the cost of $CO_2$ capture and to maximize hydrogen production, the removal of CO and the additional production of hydrogen might be needed. In this study, a 2l/min water gas shift system for a coal gasifier has been studied. To control the concentration of major components such as $H_2$, CO, and $CO_2$, MFCs were used in experimental apparatus. The gas concentration in these experiments was equal with syngas concentration from dry coal gasifiers ($H_2$: 25-35, CO: 60-65, $CO_2$: 5-15 vol%). The operation conditions of the WGS system were $200-400^{\circ}C$, 1-10bar. Steam/Carbon ratios were between 2.0 and 5.0. The commercial catalysts were used in the high temperature shift reactor and the low temperature shift reactor. As steam/carbon ratio increased, the conversion (1-$CO_{out}/CO_{in}$) increased from 93% to 97% at the condition of CO: 65, $H_2$: 30, $CO_2$: 5%. However the conversion decreased with increasing of gas flow and temperature. The gas concentration from LTS was $H_2$: 54.7-60.0, $CO_2$: 38.8-44.9, CO: 0.3-1%.

• Nuclear Engineering and Technology
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• 제25권2호
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• pp.215-221
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• 1993

중대 사고에 이어 형성 될 수 있는 용융 핵연료와 냉각수의 혼합체는 그 후에 일어날 수 있는 증기 폭발의 초기 조건을 이루게 되며, 또한 이러한 혼합의 정도는 증기 폭발의 강도를 결정하는 주요 요인이 된다. 본 연구는 간단한 일차원 과도 상태 모형을 이용하여 용융 핵연료와 냉각수의 혼합의 한계를 결정하였으며, 용융 핵연료의 분쇄 과정을 모사 하기 위하여 동적 분쇄모형과 순간 파열 모형을 각각 적용하여 그 결과를 비교하였다. 계산 결과에서는 용융 핵연료의 온도. 압력. 수조의 깊이, 혼합 상태에서의 분쇄물 직경 그리고 용융 핵연료 입사 직경등이 혼합량에 영향을 미치는 주요한 인자들로 나타났다.

• 에너지공학
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• 제7권2호
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• pp.202-208
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• 1998

원자력 발전소의 증기방출계통에는 상당수의 산업공정에서 보여지는 바와 같이 배관을 통해 응축성 기체를 침수 분사시켜 응축시키는 과정이 포함된다. 본 연구에서는 증기방출계통 파이프와 지지문의 설계에 사용되는 동적 하중을 계산하기 위하여 증기방출 과도현상에 대한 해석을 특성기법을 사용하여 수행하였다. 해석모델은 마찰이 존재하는 균일한 배관을 통해 증기가 수조로 방출되는 경우에 대하여, 증기유량 및 배관 내에 원래 존재하고 있는 공기와 물의 방출유량 등을 고려하였고 압력 및 열원, 밸브, 분지관 등을 포함하였다. 배관의 유동 특성과 동적 하중을 계통 압력, 배관 길이 및 침수 깊이의 변화에 따라 계산하였다. 계산 결과 공기와 물의 경계에서의 배관의 동적 하중, 배관 내의 물 제거 시간 및 물 이동 속도 등은 계통 압력뿐만 아니라 배관 길이 및 침수 깊이의 영향을 받는 것으로 확인되었다.

• Korean Chemical Engineering Research
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• 제50권1호
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• pp.76-82
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• 2012

볏짚 톱밥과 같은 바이오매스는 석탄과 함께 사용할 수 있는 잠재력이 큰 에너지원으로 이들을 가스화공정에 적용하면 수송용 연료같은 bio-oil을 생산할 수 있다. 본 연구에서는 상압의 열천칭 반응기(thermobalance)에서 톱밥, 볏짚, 갈탄, 역청탄, 무연탄의 수증기 가스화 반응특성을 수행하였으며, 가스화 온도 $600{\sim}850^{\circ}C$, 수증기 분압 30~90 kPa의 범위에서 조업변수들이 가스화반응속도에 미치는 영향을 조사하였다. 세 가지의 기체-고체 화학반응모델이 가스화반응의 거동을 예측하는 능력을 비교하였으며, modified volumetric reaction model을 사용하여 공정설계에 필수적인 kinetic 정보를 도출하였다. 두 가지 바이오매스와 세 가지 석탄 촤의 가스화반응성을 비교하였다. Arrhenius plot으로부터 얻어진 바이오매스와 석탄의 활성화에너지는 모두 문헌상의 범위에 속하였다. 각 연료에 대하여 수증기분압에 대한 반응차수를 결정하였으며, 가스화공정 설계의 기초데이타로서 겉보기 반응속도식을 제시하였다.

• Journal of Welding and Joining
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• 제34권3호
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• pp.52-60
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• 2016

Recently nickel based superalloys are extensively being regarded as the materials for the steam turbine parts for hyper super critical (HSC) power plants working at the temperature over $700^{\circ}C$, since the materials have excellent strength and corrosion resistance in high temperature. In this paper, alloy 617 of solution strengthened material and alloy 263 of ${\gamma}^{\prime}$-precipitation strengthened material were prepared as the testing materials for HSC plants each other. Post weld heat treatment (PWHT) was conducted with the gas tungsten arc (GTA) welded specimens. The microstructure of the base metals and weld metals were investigated with Electron Probe Micro-Analysis (EPMA) and Scanning Transmission Electron Microscope (STEM). The experimental results revealed that Ti-Mo carbides were formed in both of the base metals and segregation of Co and Mo in both of the weld metals before PWHT and PWHT leaded to precipitation of various carbides such as Mo carbides in the specimens. Furthermore, fine ${\gamma}^{\prime}$ particles, that were not precipitated in the specimens before PWHT, were observed in base metal as well as in the weld metal of alloy 263 after PWHT.

• 공업화학
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• 제10권2호
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• pp.190-195
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• 1999

테트라 플로오르에틸렌의 제조를 위한 클로로디플루오르메탄 (R22) 열분해 반응에 대해 저자들이 고안한 관형 반응기에서 반응온도 ($600{\sim}850^{\circ}C$), 체류시간 (0.005~0.6초) 및 희석비 (수증기/R22, 3~30)를 변수로 하여 전환율, 테트라플로오로에틸렌의 수율 및 선택도에 대한 영향을 고찰하였다. 이상의 결과로부터 이 반응기의 최적조업 및 설계를 위한 지침을 제시하였다. 반응온도는 $700{\sim}750^{\circ}C$, 체류시간은 0.07~0.1초일 때 최적 조업 조건이었다. 희석제인 과열 수증기의 사용은 반응 전환율 뿐만 아니라, TFE의 선택도도 증진시키는 것으로 나타났다. 속도론적 분석을 통하여 R22열분해 반응의 주반응이 $CF_2$ 라디칼 생성반응인 것인 것을 보였으며, 1차 속도식으로 잘 표현되었다. 이 주반응의 활성화 에너지는 44.7~48 kcal/mol이었다.

• 대한기계학회논문집B
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• 제26권11호
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• pp.1578-1584
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• 2002

Combustion stability is one of the most important factors that must be considered in burning of heavy fuel oil, especially low-grade oil. This paper describes the combustion characteristics of petrochemical process by- product in the combustion furnace of heavy fuel oil. Main experimental parameters were combustion load, excess 02, fuel preheating temperature and air/fuel ratio. The capacity of CRF(combustion research facility) used in this study was 1.0 ton/hr and the burner is steam jet type suitable far heavy oil combustion and manufactured by UNIGAS in Italy. The fuel used in this experiment were 0.5 B-C, petrochemical process by-product and 3 kinds of 0.5 B-C/process by-product mixtures. The combustion stability was monitored and exhaust gases such as CO, NOx, SOx and particulates were measured with the excess $O_2$ and combustion load. The main purpose of this study is to clarify whether process by-product can be used as a boiler fuel or not in consideration of flame stability and emission properties.

• 한국수소및신에너지학회논문집
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• 제20권5호
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• pp.416-423
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• 2009

High-temperature steam electrolysis (HTSE) using solid oxide cell is a challenging method for highly efficient large-scale hydrogen production as a reversible process of solid oxide fuel cell (SOFC). The overall efficiency of the HTSE hydrogen and synthesis gas production system was analyzed thermo-electrochemically. A thermo-electrochemical model for the hydrogen and synthesis gas production system with solid oxide electrolysis cell (SOEC) and very high temperature gas-cooled reactor (VHTR) was established. Sensitivity analyses with regard to the system were performed to investigate the quantitative effects of key parameters on the overall efficiency of the production system. The overall efficiency with SOEC and VHTR was expected to reach a maximum of 58% for the hydrogen production system and to 62% for synthesis gas production system by improving electrical efficiency, steam utilization rate, waste heat recovery rate, electrolysis efficiency, and thermal efficiency. Therefore, overall efficiency of the synthesis production system has higher efficiency than that of the hydrogen production system.

• Nuclear Engineering and Technology
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• 제54권5호
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• pp.1570-1578
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• 2022

During a severe accident, steam generator (SG) tubes undergo rapid changes in the pressure and temperature. Therefore, an appropriate creep model to predict a short term creep damage is essential. In this paper, a novel creep model for Alloy 690 SG tube material was proposed. It is based on the theta (θ) projection method that can represent all three stages of the creep process. The original θ projection method poses a limitation owing to its inability to represent experimental creep curves for SG tube materials for a large strain rate in the tertiary creep region. Therefore, a new modified θ projection method is proposed; subsequently, a master curve for Alloy 690 SG material is also proposed to optimize the creep model parameters, θ_i (i = 1-5). To adapt the implicit creep scheme to the finite element code, a partial derivative of incremental creep with respect to the stress is necessary. Accordingly, creep model parameters with a strictly linear relationship with the stress and temperature were proposed. The effectiveness of the model was validated using a commercial finite element analysis software. The creep model can be applied to evaluate the creep rupture behavior of SG tubes in nuclear power plants.