• Title/Summary/Keyword: Stationary phase

검색결과 773건 처리시간 0.02초

정상 액체크로마토그래피에서의 선형 용매화에너지 비교법 연구 Ⅰ (Linear Solvation Energy Comparison Study in Normal Phase Liquid Chromatography Ⅰ)

  • 최장덕;정원조
    • 대한화학회지
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    • 제38권3호
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    • pp.221-223
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    • 1994
  • 정상 액체크로마토그래피에서의 선형 용매화에너지 비교법 연구를 시도하였다. 용매를 고정시키고 여러 용질의 lnk'과 용질의 극성도 지수간의 상관관계를 조사한 회귀분석의 결과를 보면, 상관계수는 정상 액체크로마토그래피의 용질 머무름 메카니즘상의 복잡성으로 인하여 역상 액체크로마토그래피의 경우보다 낮은 결과를 보였고, 회귀계수의 용매조성 부피비(${\phi}$)에 따른 경향을 조사하여 정지상의 모든 극성도가 이동상의 그것보다 크며 그 극성도 차이는 극성이 더 큰 용매의 ${\phi}$가 증가함에 따라 감소하는 경향을 관찰하였다. 주어진 컬럼과 한 용질에 대해서 여러 다른 조성의 용매를 고려하여 수행한 lnk'과 용매 극성도 지수간의 다중 회귀분석은 용매 극성도 지수간의 직선상관성으로 인하여 의미있는 결과를 얻을 수 없었고, 대신 lnk'대 ${\pi}^*$간의 회귀분석은 용질 머무름 예측의 응용성이 있는 직선상관을 주었으며 이것은 lnk'대 ${\phi}$간의 직선상관성보다 우수하였다.

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아미노산 Phenylthiohydantoin 유도체를 키랄 고정상으로 한 GC에 의한 아미노산 광학 이성질체의 상호분리 (Separation of Amino Acid Enantiomers by Gas Chromatogaphy on Phenylthiohydantoin Derivatives as Chiral Stationary Phases)

  • 박만기;양정선;고창범;이미영
    • 약학회지
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    • 제32권3호
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    • pp.170-176
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    • 1988
  • The resolution of five amino acids derivatives by gas chromatography on phenylthiohydantoin derivatives as chiral stastionary phase was investigated. (S)-5-isopropyl, isobutyl, (sec)-butyl and benzoyl derivatives of $N^3-phenyl-2-thiohydantoin$ were synthesized from L-valine, L-leucine, L-isoleucine and L-phenylalanine, respectively. The phases were employed at several column temperatures ($140^{\circ}C{\sim}210^{\circ}C$). The separation factors were compared with each stationary phase with varying R groups. The possible mechanism of chiral recognition was investigated by NMR technique.

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Turbulent properties in a mixed statistically stationary flow

  • Baek, Tae-Sil;Doh, Deog-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권7호
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    • pp.729-736
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    • 2013
  • The turbulent properties in a mixed statistically stationary flow were investigated experimentally by a pseudo stereoscopic PIV. In order to validate the experimental results, the profiles of the turbulent kinetic energy were evaluated with the flow features. A mechanical agitator having 6 blades was installed at the bottom of the mixing tank (D=60cm, H=60cm). The agitator was rotated with 80rpm clockwise and counter-clockwise. For the measurements, three cameras were used and all were synchronized. The images captured by one of the three cameras was used for the measurement of rotational speed, and the images captured by the other two cameras were used to measure three dimensional components of velocity vectors. All vectors captured at the same rotational angle were phase averaged to construct three-dimensional vector fields to reconstruct the spatial distribution of the flow properties. It was seen that the jet scrolling along the tank was the main source of mixing.

원통면 음향 홀로그래피를 이용한 수중음향 곡면배열센서의 빔 해석 (Beam Analysis of Underwater Conformal Array by Using Cylindrical Acoustic Holography)

  • 권휴상;박성철;서희선;신구균;조치영
    • 한국소음진동공학회논문집
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    • 제19권10호
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    • pp.987-995
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    • 2009
  • As an experimental technique to analyze the far-field characteristics of underwater cylindrical array sensors, cylindrical acoustic holography is studied. Inside an laboratory water tank, far-field directivity patterns as well as near-field source images are reconstructed from the measured hologram by hydrophone array. Approximate equation for far-field directivity estimation is derived based on stationary phase method. The simulation and experiment show well usefulness of the proposed method in application of underwater array sensors.

Molecular Weight Distribution of Pullulan and Degrading Enzyme Activity of Aureobasidium pullulans

  • 이지현;김미령;김정화;이진우;김성구
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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    • pp.325-328
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    • 2000
  • The effects of DO and pH on the mass production of pullulan with high-molecular weight from A. pullulans ATCC 42023 were evaluated. The maximum pullulan production yield (51%) was obtained at pH non control (initial pH 6.5) and DO control (above 50%) condition. The pullulan degrading enzyme was activated when the pH of broth reached lower than 5.0 and portion of low molecular weight pullulan was increased. The formation of a black pigment was observed at the initial stationary phase, 40hr of fermentation. Therefore, the fermentation should be carried out in pH non control and DO control condition and harvested before reaching stationary phase around 40h for the production of high molecular weight pullulan.

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원통면 음향 홀로그래피를 이용한 수중음향 곡면배열센서의 빔 해석 (Beam analysis of underwater conformal array by using cylindrical acoustic holography)

  • 권휴상;박성철;서희선;신구균;조치영
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2009년도 춘계학술대회 논문집
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    • pp.111-116
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    • 2009
  • As an experimental technique to analyze the far-field characteristics of underwater cylindrical array sensors, cylindrical acoustic holography is studied. Inside an laboratory water tank, far-field directivity patterns as well as near-field source images are reconstructed from the measured hologram by hydrophone array. Approximate equation for far-field directivity estimation is derived based on stationary phase method. The simulation and experiment show well usefulness of the proposed method in application of underwater array sensors.

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정지좌표계를 이용한 3상 UPS용 PWM-VSI 제어 (PWM-VSI controller of Three-phase UPS Using Stationary Reference Frame)

  • 김민규;김재식;방상석;최재호
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2003년도 춘계전력전자학술대회 논문집(2)
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    • pp.965-968
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    • 2003
  • This paper describes the PWM-VSI controller of three-phase UPS system using stationary reference frame. This controller meets the specification the UPS inverter output voltage even under the unbalanced or nonlinear load. This controller is also constructed with duble control loop of the outer voltage control loop and the inner current control loop. For the fast response of the output voltage control, yhr inner current control loop of the capacitor current os used. To get the good property against overshoot, the If controller us used. The outer voltage controller is designed with P controller and the high gain transfer function is used for the zero steady state error. All control gains of both controller is designed base on the CDM method.

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Numerical Study on Frequency Up-conversion in USPR using MATLAB

  • Roh, Young-Su
    • Journal of Electrical Engineering and Technology
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    • 제5권3호
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    • pp.497-502
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    • 2010
  • In this paper, the O-mode ultrashort-pulse reflectometry (USPR) millimeter-wave signals that propagate into the plasma and cover a frequency bandwidth of 33-158 GHz are examined numerically using MATLAB. Two important processes are involved in the computation: the propagation of the USPR impulse signal through a waveguide and the frequency up-conversion using millimeter-wave mixers. These mixers are limited to intermediate frequency signals that are less than 500 mV; thus, it is necessary to disperse the impulse signal into a chirped waveform using the waveguide. The stationary phase method is utilized to derive a closed-form formula for a chirped waveform under the assumption that the USPR impulse is Gaussian. In the process of frequency up-conversion, the chirped waveform is mixed with the mixer LO signal, and the lower frequency components of the RF signal are removed using high pass filters.