• Title/Summary/Keyword: Stationary phase

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Linear Solvation Energy Comparison Study in Normal Phase Liquid Chromatography Ⅰ (정상 액체크로마토그래피에서의 선형 용매화에너지 비교법 연구 Ⅰ)

  • Choe, Jang Deok;Jeong, Won Jo
    • Journal of the Korean Chemical Society
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    • v.38 no.3
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    • pp.221-223
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    • 1994
  • We tried to apply the linear solvation energy comparison method to solute retention in normal phase liquid chromatography. Correlation coefficients of regression of lnk' collected in a fixed eluent against solute polarity indices have proven to be lower than those obtained from reversed phase liquid chromatography data. This event can be attributed to complexity of solute retention process in normal phase liquid chromatography. We concluded from the regression results that each specific polarity of the stationary phase is greater than that of the mobile phase and that the difference in each polarity between the stationary phase and the mobile phase decreases as the volume fraction(${\phi}$) of the more polar solvent in the mobile phase increases. Correlations of lnk' of a single solute against solvent polarity indices have proven to be meaningless owing to covariance among the solvent polarity indices. Instead, a good linear relationship between lnk' and solvent ${\pi}^*$ was observed, and its linearity is better than that between lnk' and ${\phi}$.

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Separation of Amino Acid Enantiomers by Gas Chromatogaphy on Phenylthiohydantoin Derivatives as Chiral Stationary Phases (아미노산 Phenylthiohydantoin 유도체를 키랄 고정상으로 한 GC에 의한 아미노산 광학 이성질체의 상호분리)

  • Park, Man-Ki;Yang, Jeong-Seen;Ko, Chang-Bum;Lee, Mi-Yung
    • YAKHAK HOEJI
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    • v.32 no.3
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    • pp.170-176
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    • 1988
  • The resolution of five amino acids derivatives by gas chromatography on phenylthiohydantoin derivatives as chiral stastionary phase was investigated. (S)-5-isopropyl, isobutyl, (sec)-butyl and benzoyl derivatives of $N^3-phenyl-2-thiohydantoin$ were synthesized from L-valine, L-leucine, L-isoleucine and L-phenylalanine, respectively. The phases were employed at several column temperatures ($140^{\circ}C{\sim}210^{\circ}C$). The separation factors were compared with each stationary phase with varying R groups. The possible mechanism of chiral recognition was investigated by NMR technique.

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Turbulent properties in a mixed statistically stationary flow

  • Baek, Tae-Sil;Doh, Deog-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.7
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    • pp.729-736
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    • 2013
  • The turbulent properties in a mixed statistically stationary flow were investigated experimentally by a pseudo stereoscopic PIV. In order to validate the experimental results, the profiles of the turbulent kinetic energy were evaluated with the flow features. A mechanical agitator having 6 blades was installed at the bottom of the mixing tank (D=60cm, H=60cm). The agitator was rotated with 80rpm clockwise and counter-clockwise. For the measurements, three cameras were used and all were synchronized. The images captured by one of the three cameras was used for the measurement of rotational speed, and the images captured by the other two cameras were used to measure three dimensional components of velocity vectors. All vectors captured at the same rotational angle were phase averaged to construct three-dimensional vector fields to reconstruct the spatial distribution of the flow properties. It was seen that the jet scrolling along the tank was the main source of mixing.

Beam Analysis of Underwater Conformal Array by Using Cylindrical Acoustic Holography (원통면 음향 홀로그래피를 이용한 수중음향 곡면배열센서의 빔 해석)

  • Kwon, Hyu-Sang;Park, Seong-Chol;Seo, Hee-Seon;Shin, Gu-Kyun;Joh, Ghee-Young
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.10
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    • pp.987-995
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    • 2009
  • As an experimental technique to analyze the far-field characteristics of underwater cylindrical array sensors, cylindrical acoustic holography is studied. Inside an laboratory water tank, far-field directivity patterns as well as near-field source images are reconstructed from the measured hologram by hydrophone array. Approximate equation for far-field directivity estimation is derived based on stationary phase method. The simulation and experiment show well usefulness of the proposed method in application of underwater array sensors.

Molecular Weight Distribution of Pullulan and Degrading Enzyme Activity of Aureobasidium pullulans

  • Lee, Ji-Hyeon;Kim, Mi-Ryeong;Kim, Jeong-Hwa;Lee, Jin-U;Kim, Seong-Gu
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.325-328
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    • 2000
  • The effects of DO and pH on the mass production of pullulan with high-molecular weight from A. pullulans ATCC 42023 were evaluated. The maximum pullulan production yield (51%) was obtained at pH non control (initial pH 6.5) and DO control (above 50%) condition. The pullulan degrading enzyme was activated when the pH of broth reached lower than 5.0 and portion of low molecular weight pullulan was increased. The formation of a black pigment was observed at the initial stationary phase, 40hr of fermentation. Therefore, the fermentation should be carried out in pH non control and DO control condition and harvested before reaching stationary phase around 40h for the production of high molecular weight pullulan.

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Beam analysis of underwater conformal array by using cylindrical acoustic holography (원통면 음향 홀로그래피를 이용한 수중음향 곡면배열센서의 빔 해석)

  • Kwon, Hyu-Sang;Park, Seong-Chol;Seo, Hee-Seon;Shin, Gu-Kyun;Joh, Ghee-Young
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2009.04a
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    • pp.111-116
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    • 2009
  • As an experimental technique to analyze the far-field characteristics of underwater cylindrical array sensors, cylindrical acoustic holography is studied. Inside an laboratory water tank, far-field directivity patterns as well as near-field source images are reconstructed from the measured hologram by hydrophone array. Approximate equation for far-field directivity estimation is derived based on stationary phase method. The simulation and experiment show well usefulness of the proposed method in application of underwater array sensors.

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PWM-VSI controller of Three-phase UPS Using Stationary Reference Frame (정지좌표계를 이용한 3상 UPS용 PWM-VSI 제어)

  • Kim M.K.;Kim J.S.;Bang S.S.;Choi J.H.
    • Proceedings of the KIPE Conference
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    • 2003.07b
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    • pp.965-968
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    • 2003
  • This paper describes the PWM-VSI controller of three-phase UPS system using stationary reference frame. This controller meets the specification the UPS inverter output voltage even under the unbalanced or nonlinear load. This controller is also constructed with duble control loop of the outer voltage control loop and the inner current control loop. For the fast response of the output voltage control, yhr inner current control loop of the capacitor current os used. To get the good property against overshoot, the If controller us used. The outer voltage controller is designed with P controller and the high gain transfer function is used for the zero steady state error. All control gains of both controller is designed base on the CDM method.

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Numerical Study on Frequency Up-conversion in USPR using MATLAB

  • Roh, Young-Su
    • Journal of Electrical Engineering and Technology
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    • v.5 no.3
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    • pp.497-502
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    • 2010
  • In this paper, the O-mode ultrashort-pulse reflectometry (USPR) millimeter-wave signals that propagate into the plasma and cover a frequency bandwidth of 33-158 GHz are examined numerically using MATLAB. Two important processes are involved in the computation: the propagation of the USPR impulse signal through a waveguide and the frequency up-conversion using millimeter-wave mixers. These mixers are limited to intermediate frequency signals that are less than 500 mV; thus, it is necessary to disperse the impulse signal into a chirped waveform using the waveguide. The stationary phase method is utilized to derive a closed-form formula for a chirped waveform under the assumption that the USPR impulse is Gaussian. In the process of frequency up-conversion, the chirped waveform is mixed with the mixer LO signal, and the lower frequency components of the RF signal are removed using high pass filters.