• Journal of the Korean Chemical Society
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• v.48 no.4
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• pp.339-350
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• 2004

The simplified cumulant method was applied to diffraction data of $CClF_3$ to study the equilibrium molecular parameters over a range of temperatures. The molecular parameters of $CClF_3$ by the simplified cumulant method were compared with those from the traditional method. Also the instrumentation of picosecond time resolved electron diffraction (TRED) and the experimental details are described. The total experimental temporal resolution was discussed in terms of the electron pulse width. The TRED system was applied to study the molecular structures for $CClF_3$ at room temperature. The molecular structural parameters $CClF_3$ from TRED are compared with those from GED/RT. The molecular parameters ($r_e$)of bonded C-F and C-Cl for $CClF_3$ by simplified CA are 132.00(2) pm and 175.20(3) pm, respectively, by using GED/RT. From the results of TRED experiments $r_a$ for bonded C-F and C-Cl are 132.23(13) pm and 177.23(19) pm.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.8
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• pp.792-799
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• 2008

Motion estimation is crucial in a remote control for its convenience or accuracy. Time delays, however, can occur in the problem because data communication is required through a network. In this paper, state estimation problem with uncertain time delayed measurements is addressed. In dynamic system with noise, after taking measurements, it often requires some time until that is available in the filter algorithm. Standard filters not considering this time delays cannot be used since the current measurement is related with a past state. These delayed measurements are solved with augmented extended Kalman filter, and the uncertainty of delayed time is also resolved based on an explicit formulation. The proposed method is analyzed and verified by simulations.

• Korean Chemical Engineering Research
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• v.58 no.2
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• pp.319-324
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• 2020

Electroconvective instability is a non-linear transport phenomenon which can be found in ion-selective transport system such as electrodialysis, Galvanic cell and electrolytic cell. The instability is triggered by the fluctuation of space charge layer in adjacent of ion-selective surface, leading to increase of mass transport rate. Thus, in the aspect of mass transport, the instability has an important meaning. Although recent experimental techniques have opened up an avenue to direct visualize the instability, fundamental investigations have been conducted in limited area due to several experimental limitations. In this work, the electroconvective instability under potentiostatic mode was solved by numerical method in order to demonstrate correlation between current-time curve and the instability behavior. By rigorous time-resolved analysis, the transition behaviors can be divided into three stages; formation of space charge layer - growth of electroconvective instability - steady state. Furthermore, scaling laws of transition time were numerically obtained according to applied voltage as well.

• Architectural research
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• v.25 no.2
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• pp.29-40
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• 2023

The purpose of this study is to analyze the conflicts caused by the spatial expansion in two types of urban heritage in Seoul. To explain the national and professional orientation found in each spatial transformation, the study brought the concept of 'historic state' and 'epitome,' thereby examining the operating system of the conflicts. Field observations and stakeholder interviews were performed based on literature and historical research. The study results are as follows. ①In the case of Gwanghwamun and Donuimun, the spatial expansion is to find the historic state of the sites. Gwanghwamun with high national status and substance, conflicts show a pattern that spreads to memory conflicts. Donuimun is relatively unknown and has no substance so that a flexible method of digital restoration was applied. ② In the case of Ikseon-dong and Bukchon hanok, they show heterogeneous spatial expansion. The conflicts in relation to this is caused by the epitome of hanok. In Ikseon-dong, illegal installation of structures(non-epitome) is prevalent, while in Bukchon, there was a process of transferring the new basement(non-epitome) as part of the hanok. ③Conflicts in Gwanghwamun can be coordinated by referring to the digital restoration of Donuimun, and conflicts in Ikseon-dong can be resolved by taking Bukchon as a precedent.

• Journal of Korea Foundry Society
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• v.40 no.3
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• pp.85-96
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• 2020

The effect of an aluminum scrap addition ratio on the tensile and solidification cracking properties of the AC4A aluminum alloy in the as-cast state and heat-treated state were investigated in this study. Generally, the expected problem of using scrap in aluminum casting is an increase of hydrogen and Fe element inside the aluminum melt. Another issue is an oxide film which has a weak interface with the molten aluminum and acts as potent nucleation sites for internal porosity and crack initiation. Solidification cracking is one of the critical defects that must be resolved to produce high quality castings. A conventional evaluation method for solidification cracking is a relative and qualitative analysis method which does not provide quantitative data on the thermal stress in the solidification process. Therefore, a newly designed solidification cracking test apparatus was used in this study, and the device can provide quantitative data. As a result, after conducting experiments with different scrap addition ratios (0%, 20%, 35%, 50%), the tensile strengths and elongations in the as-cast state were 214, 187.7, 182.1 and 170.4MPa and 4.6%, 3.4%, 3.1% and 2.3%, respectively. In the case of the T6 heat-treated state, the tensile strengths and elongations were 314.9, 294.6, 293.1 and 271.1MPa and 5.4%, 4.6%, 3.8% and 3.1%, respectively. The strength of the solidification cracking was 3.1, 2.4, 2.2and 1.6MPa as the scrap addition ratio increases.

• Journal of KIISE:Computing Practices and Letters
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• v.7 no.5
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• pp.467-474
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• 2001

When user wants to animate more than one character, some unexpected motion animation like a collision between characters may occur. Therefore, this problem must be resolved using a proper control mechanism. Therefore, this problem must be resolved using a proper control mechanism. This paper proposes an agent-based system that controls the motion animation of the character for representing animation scenario reflecting user\`s intention. This system provides a method that coordinates a type of motion and avoids collision between characters according to the moving path of a character in three-dimensional space. Agent communicates with others for motion synchronization. Agent is extended into several intelligent agents that coordinate character\`s motion. Agent system enables not only an intended motion animation, but also the scheduling of motion to an entire character animation. It designs automata model using Petri-net analysis tool for the agent\`s interaction as a method that passes the agent\`s information and infers the current state of agents. We implement this agent system to control the motion of character using agent technology and show an example of controlling the motion of human character model to prove the possiblity of motion control.

• Journal of the Korean Ceramic Society
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• v.29 no.9
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• pp.739-749
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• 1992

The sols prepared by dialyzing solutions, in which the hydrolyzed precipitates of TEOT or directly Ti(OC3H7)4 were resolved, were the nanoparticulate sol with the average particle size less than 7 nm and the anatase crystal phase. In the pH range of 1.5 to 2.9, the particle size of the nanoparticulate TiO2 sols (0.09 mol/ι) increased gradually upto 15 nm~26nm with the increase of pH in the initial aging state but the sols were transparent all the time, and stable without growin any more after 30 days. When the slipcasted porous alumina tubes were coated by the sol-gel dipping method, the minimum particle size and the aging time for forming the coated gel layer at the given pH were optimized. For obtaining the very thin crack-free and reproducible membrane coating, the use of a nanoparticulate TiO2 sol (0.09 mol/ι) aged for about 30 dyas at pH=2.0 was found to be the best.

• Journal of Communications and Networks
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• v.13 no.4
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• pp.385-392
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• 2011

A loop can take place in the process of managing tree topology for mobility management of mobile nodes in infrastructure-based mobile ad hoc networks. The formation of a loop degrades an effective bandwidth of the wireless network by passing an identical message repeatedly within the same loop. Therefore, the loop should be resolved to revert the system back to the normal state. In this paper, we propose a simple and novel mechanism that detects and resolves a loop quickly by tracking the depth of trees. The mobility management approach that employs the loop resolution method is evaluated comparatively with the original tree-based one and the hybrid one. It is shown that the proposed approach far outperforms the other approaches, and it is robust against the rapid changes in network topology.

• Journal of Communications and Networks
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• v.13 no.4
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• pp.377-384
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• 2011

Cooperative beamforming has previously been proven to be an efficient way to improve the cooperative diversity. This method generally requires all relay nodes to participate in beamforming, which can be seen as "all participate" cooperative beamforming. However, not all relay nodes have constructive impacts on the end-to-end bit error rate (BER) performance. Based on this observation, we propose a new cooperative scheme which only selects those "appropriate" relay nodes to perform cooperative beamforming. Such relay nodes can be simply determined with mean channel gains. Therefore, the selection complexity is significantly reduced as global instantaneous channel state information is not required. This scheme guarantees that energy is only allocated to the "appropriate" relay nodes, and hence provides superior diversity. We also prove that power allocation among source and selected relay nodes is a convex problem, and can be resolved with lower computational complexity. Simulation results demonstrate that our scheme achieves an essential improvement in terms of BER performance for both optimal and limited feedback scenarios, as well as high energy-efficiency for the energy-constrained networks.

• Journal of Photoscience
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• v.11 no.32
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• pp.77-81
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• 2004

Deoxygadusol (DO) and structurally related mycosporine-like amino acids, i.e. mycosporine glycine (MO) and mycosporine taurine (MT), were isolated from phytoplankton Prorocentrum micans and studied for the reactivity toward singlet oxygen. These water-soluble compounds with a cyclohexenone chromophore were all shown to be highly effective in quenching singlet oxygen ($^1$ $O_2$), with the efficiencies being significantly larger compared with histidine, a well-known $^1$ $O_2$ quencher. The $^1$ $O_2$ reaction rate constant ( $k_{Q}$) of DG was determined to be 5.4 ${\times}$ 10$^{7}$ $M^{-1}$ $s^{-1}$ by a steady state method based on competitive inhibition of rubrene oxidation. The feasibility of this method was confirmed by estimating the $k_{Q}$ values for MG and two other quenchers, furfuryl alcohol and 1,4-diazabicyclo [2,2,2]octane, and comparing with those values determined by the time-resolved $^1$ $O_2$ decay method in the previous work.ork.