• Title/Summary/Keyword: State Dependence

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Trapping centers due to native defects in the $CdIn_2S_4$ films grown by hot wall epitaxy

  • Hong, Myung-Seuk;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.167-168
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    • 2007
  • $CdIn_2S_4$ (110) films were grown on semi-insulating GaAs (100) by a hot wall epitaxy method. Using photocurrent (PC) measurement, the PC spectra in the temperature range of 30 and 10 K appeared as three peaks in the short wavelength region. It was found that three peaks, A-, B-, and C-excitons, correspond to the intrinsic transition from the valence band states of ${\Gamma}_4(z),\;{\Gamma}_5(x),\;and\;{\Gamma}_5(y)$ to the exciton below the conduction band state of ${\Gamma}_1(s)$, respectively. The 0.122 eV crystal field splitting and the 0.017 eV spin orbit splitting were obtained. Thus, the temperature dependence of the optical band gap obtained from the PC measurement was well described by $E_g$(T)=2.7116eV - $(7.65{\times}10^{-4}\;eV/K)T^2$/(425+T). But, the behavior of the PC was different from that generally observed in other semiconductors. The PC intensities decreased with decreasing temperature. This phenomenon had ever been reported at a PC experiment on the bulk crystals grown by the Bridgman method. From the relation of log $J_{ph}$ vs 1/T, where $J_{ph}$ is the PC density, two dominant levels were observed, one at high temperatures and the other at low temperatures. Consequently, the trapping centers due to native defects in the $CdIn_2S_4$ film were suggested to be the causes of the decrease in the PC signal with decreasing temperature.

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High Temperature Compressive Deformation Behavior of Ti-6Al-2Sn-4Zr-6Mo Alloy (Ti-6Al-2Sn-4Zr-6Mo 합금의 고온압축 변형거동)

  • Hyun, Yong-Taek;Lee, Yong-Tai;Lee, Chan-Gyu
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.82-87
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    • 2001
  • The hot deformation behavior of Ti-6Al-2Sn-4Zr-6Mo(Ti6246) alloy was investigated in both the $\alpha$+$\beta$ and $\beta$-phase fields by conducting compression tests over a strain rate range of $10^{-3}s^{-1}$ to $10^0s^{-1}$. The flow stress was increased with increasing strain rate and decreasing test temperature. The flow curves obtained at temperatures below 90$0^{\circ}C$ exhibited a flow softening. However, in the $\beta$-phase field, above 95$0^{\circ}C$, the flow stress increased monotonically with plastic strain approaching steady state values. Constitutive equations for the dependence of flow stress on strain, strain rate, and temperature were developed through the analysis of the flow curves.

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Dielectric Properties and Phase Transformation of Poled <001>-Oriented Pb(Mg1/3Nb2/3)O3-PbTiO3 Single Crystals (분극된 <001> 방위 Pb(Mg1/3Nb2/3)O3-PbTiO3 단결정의 유전 특성 및 상전이)

  • Lee, Eun-Gu;Lee, Jae-Gab
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.342-345
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    • 2012
  • The dielectric properties and phase transformation of poled <001>-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$(PMN-x%PT) single crystals with compositions of x = 20, 30, and 35 mole% are investigated for orientations both parallel and perpendicular to the [001] poling direction. An electric-field-induced monoclinic phase was observed for the initial poled PMN-30PT and PMN-35PT samples by means of high-resolution synchrotron x-ray diffraction. The monoclinic phase appears from $-25^{\circ}C$ to $100^{\circ}C$ and from $-25^{\circ}C$ to $80^{\circ}C$ for the PMN-30PT and PMN-35PT samples, respectively. The dielectric constant (${\varepsilon}$)-temperature (T) characteristics above the Curie temperature were found to be described by the equation$(1/{\varepsilon}-1/{\varepsilon}_m)^{1/n}=(T-T_m)/C$, where ${\varepsilon}_m$ is the maximum dielectric constant and $T_m$ is the temperature giving ${\varepsilon}_m$, and n and C are constants that change with the composition. The value of n was found to be 1.82 and 1.38 for 20PT and 35PT, respectively. The results of mesh scans and the temperature-dependence of the dielectric constant demonstrate that the initial monoclinic phase changes to a single domain tetragonal phase and a to paraelectric cubic phase. In the ferroelectric tetragonal phase with a single domain state, the dielectric constant measured perpendicular to the poling direction was dramatically higher than that measured in the parallel direction. A large dielectric constant implies easier polarization rotation away from the polar axis. This enhancement is believed to be related to dielectric softening close to the morphotropic phase boundary.

Reaction Mechanism of Acetylcholinesterase Catalyzed Hydrolysis of Thiocholine Esters (아세틸콜린에스터라제 촉매에 의한 티오에스테르의 가수분해 반응 메카니즘 연구)

  • 정대일;최순규;이용균;박유미;곽문정;신영주;최병욱;이봉호;한정태
    • Journal of Life Science
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    • v.12 no.1
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    • pp.32-42
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    • 2002
  • It was researched to react horse serum-BChE with hefanoylthiocholine chosen among choline esters. According as number of carbon of acyl group in choline esters was increased, reactivity was decreased but strength of ES complex was increased (Km=0,140mM). The pH-V/K profile for BChE-catalyzed hydrolysis of hexanoylthiocholine yields a p $K_{a}$ =4.974$\pm$0.028. This value is equal to recent literature that shows systematic shift from dependence of activity on the basic form fo a residue that huts a p $K_{a}$ =6.2~6.4 to catalysis by a residue or residues that has a p $K_{a}$ =4.7~5.0. The resulting kinetic solvent isotope effect of hexanoylthiocholine is $^{D/V}$K=1.18. The magnitude of the isotope effect suggests that proton transfer is not an element of transition-state stabilization.n.

An analysis of Nontraditional Activities at Banks: a cross-country analysis (은행의 비이자 수익에 대한 Multi-Country 연구)

  • Choi, Sung-Ho
    • International Area Studies Review
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    • v.12 no.2
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    • pp.27-53
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    • 2008
  • This paper investigates factors determining the level of nontraditional activities at banks around the world. Specifically, the paper examines what kinds of firm-specific and country-specific characteristics determine the level of noninterest income using a comprehensive multi-country database. This paper focuses beyond the traditional U.S. based analyses and provides detailed asset-liability management practices of banks around the world.The findings suggest that banks' size and loan loss provision, explicit deposit insurance, banking restriction, banking freedom ranking of respective countries, the extent of state and foreign ownership, governance, and transparency of the country have positive effects on the level of nontraditional activities. Greater dependence on traditional lending and financing, market based economy, and multiple bank supervisory bodies in the country have negative associations with noninterest income. The economic development of country however affects the extent of the relationship.

The Magnetism and Electronic Structures of Ru Monolayer with Square Lattice (사각형구조를 갖는 Ru 단층의 자성과 전자구조)

  • 조이현;김인기;이재일;장영록;박인호;최성을;권명회
    • Journal of the Korean Magnetics Society
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    • v.9 no.3
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    • pp.127-130
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    • 1999
  • The magnetism and electronic structure of Ru monolayer with square lattice is investigated using the FLAPW band method. The dependence of total energies on the lattice constant was calculated for three magnetic states, i.e.,para-,ferro-, and antiferromagnetic ones. It was found that there is no energy difference between para-and antiferromagnetic states for all the lattice constant. The possibility of antiferromagnetism in square Ru monolayer is thus excluded. The ferromagnetic state is most stable for the lattice constants greater than 7.30 a.u. The energy minimum is found at the lattice constant of 6.53 a.u. Where it is paramagenetic. It is calculated that the magenetic moment is 2.49 ${\MU}_B$ at 7.72 a.u., which is close to the lattice constant of Ag. The magnetic moment is almost saturated to be ${\MU}_B$ at the lattice constant of 7.86 a.u.

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Luminescence properties of asymmetric double quantum well composed of $Al_xGa_{l-x}As/AlAs/GaAs$ system ($Al_xGa_{l-x}As/AlAs/GaAs$계로 이루어진 비대칭 이중 양자우물 구조에서의 광 luminescsnce 특성 연구)

  • 정태형;강태종;이종태;한선규;유병수;이해권;이정희;이민영;김동호
    • Korean Journal of Optics and Photonics
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    • v.3 no.3
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    • pp.183-190
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    • 1992
  • Luminescence properties of asymmetric double quantum well structure composed of $Al_x/Ga_{1-x}$ /As AIAs/GaAs have been studied by steady state and time-resolved photoluminescence and phtoluminescence excitation spectroscopy at low temperature. Two quantum well samples with different barrier thickness (15$\AA$ and 150$\AA$) were prepared to investigate the dependence of tunneling characteristics on barrier thickness. The abscence of excitonic recombination peak from $Al_x/Ga_{1-x}$As well for the 15$\AA$ barrier sample indicates a very fast electron tunneling to GaAs well. Meanwhile, T-X transition between well and barrier is supposed to be a major route for the fast decay of luminescence from $Al_x/Ga_{1-x}$As well in the 150$\AA$ barrier sample. Time-resolved photduminescence from GaAs well of 15$\AA$ sample shows the exsitence of the rise with 100 ps which is attributed to the hole tunneling.

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A first-principles theoretical investigation of the structural, electronic and magnetic properties of cubic thorium carbonitrides ThCxN(1-x)

  • Siddique, Muhammad;Rahman, Amin Ur;Iqbal, Azmat;Azam, Sikander
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1373-1380
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    • 2019
  • Besides promising implications as fertile nuclear materials, thorium carbonitrides are of great interest owing to their peculiar physical and chemical properties, such as high density, high melting point, good thermal conductivity. This paper reports first-principles simulation results on the structural, electronic and magnetic properties of cubic thorium carbonitrides $ThC_xN_{(1-x)}$ (X = 0.03125, 0.0625, 0.09375, 0.125, 0.15625) employing formalism of density-functional-theory. For the simulation of physical properties, we incorporated full-potential linearized augmented plane-wave (FPLAPW) method while the exchange-correlation potential terms in Kohn-Sham Equation (KSE) are treated within Generalized-Gradient-Approximation (GGA) in conjunction with Perdew-Bruke-Ernzerhof (PBE) correction. The structural parameters were calculated by fitting total energy into the Murnaghan's equation of state. The lattice constants, bulk moduli, total energy, electronic band structure and spin magnetic moments of the compounds show dependence on the C/N concentration ratio. The electronic and magnetic properties have revealed non-magnetic but metallic character of the compounds. The main contribution to density of states at the Fermi level stems from the comparable spectral intensity of Th (6d+5f) and (C+N) 2p states. In comparison with spin magnetic moments of ThSb and ThBi calculated earlier with LDA+U approach, we observed an enhancement in the spin magnetic moments after carbon-doping into ThN monopnictide.

Dielectric and Electrical Characteristics of Lead-Free Complex Electronic Material: Ba0.8Ca0.2(Ti0.8Zr0.1Ce0.1)O3

  • Sahu, Manisha;Hajra, Sugato;Choudhary, Ram Naresh Prasad
    • Korean Journal of Materials Research
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    • v.29 no.8
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    • pp.469-476
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    • 2019
  • A lead-free bulk ceramic having a chemical formula $Ba_{0.8}Ca_{0.2}(Ti_{0.8}Zr_{0.1}Ce_{0.1})O_3$ (further termed as BCTZCO) is synthesized using mixed oxide route. The structural, dielectric, impedance, and conductivity properties, as well as the modulus of the synthesized sample are discussed in the present work. Analysis of X-ray diffraction data obtained at room temperature reveals the existence of some impurity phases. The natural surface morphology shows close packing of grains with few voids. Attempts have been made to study the (a) effect of microstructures containing grains, grain boundaries, and electrodes on impedance and capacitive characteristics, (b) relationship between properties and crystal structure, and (c) nature of the relaxation mechanism of the prepared samples. The relationship between the structure and physical properties is established. The frequency and temperature dependence of the dielectric properties reveal that this complex system has a high dielectric constant and low tangent loss. An analysis of impedance and related parameters illuminates the contributions of grains. The activation energy is determined for only the high temperature region in the temperature dependent AC conductivity graph. Deviation from the Debye behavior is seen in the Nyquist plot at different temperatures. The relaxation mechanism and the electrical transport properties in the sample are investigated with the help of various spectroscopic (i.e., dielectric, modulus, and impedance) techniques. This lead free sample will serve as a base for device engineering.

Alcock-Paczynski Test with the Evolution of Redshift-Space Galaxy Clustering Anisotropy: Understanding the Systematics

  • Park, Hyunbae;Park, Changbom;Tonegawa, Motonari;Zheng, Yi;Sabiu, Cristiano G.;Li, Xiao-dong;Hong, Sungwook E.;Kim, Juhan
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.78.2-78.2
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    • 2019
  • We develop an Alcock-Paczynski (AP) test method that uses the evolution of redshift-space two-point correlation function (2pCF) of galaxies. The method improves the AP test proposed by Li et al. (2015) in that it uses the full two-dimensional shape of the correlation function. Similarly to the original method, the new one uses the 2pCF in redshift space with its amplitude normalized. Cosmological constraints can be obtained by examining the redshift dependence of the normalized 2pCF. This is because the 2pCF should not change apart from the expected small non-linear evolution if galaxy clustering is not distorted by incorrect choice of cosmology used to convert redshift to comoving distance. Our new method decomposes the redshift difference of the 2-dimensional correlation function into the Legendre polynomials whose amplitudes are modelled by radial fitting functions. The shape of the normalized 2pCF suffers from small intrinsic time evolution due to non-linear gravitational evolution and change of type of galaxies between different redshifts. It can be accurately measured by using state of the art cosmological simulations. We use a set of our Multiverse simulations to find that the systematic effects on the shape of the normalized 2pCF are quite insensitive to change of cosmology over \Omega_m=0.21 - 0.31 and w=-0.5 - -1.5. Thanks to this finding, we can now apply our method for the AP test using the non-linear systematics measured from a single simulation of the fiducial cosmological model.

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