• Title/Summary/Keyword: State Dependence

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Size and Crystal Structure Dependence of Photochromism of Nanocrystalline WO3 and MoO3 Prepared by Acid-Precipitation Method

  • Jun Young, Kwak;Young Hee, Jung;Yeong Il, Kim
    • Journal of the Korean Chemical Society
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    • v.67 no.1
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    • pp.33-41
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    • 2023
  • Nanocrystallne WO3 and MoO3 with several different sizes and crystal structures were prepared by simple acid precipitation and subsequent heat treatment. The photochromic (PC) properties of these samples were comparatively investigated in powder state by monitoring diffuse reflectance spectral changes after bandgap irradiation. The PC effect of hexagonal WO3 and monoclinic WO3 strongly depended upon crystallite size rather than crystal structure. The smaller the crystallite size, the better the PC effect. However, orthorhombic WO·H2O and MoO3 having hexagonal and orthorhombic structures did not follow this trend. One consistent result for all WO3 and MoO3 samples is that the heat treatment in air, which changes crystallinity, whether it changes the crystal structure or only the crystallite size, reduces the PC effect. Since the thermal treatment reduces the surface oxygen defect sites, we believe that the PC effect of WO3 and MoO3 depends critically on the surface oxygen defect sites that serve as deep trap sites for photogenerated electrons and oxygen radical holes. We also found that the proton insertion claimed by double charge injection model is not critical for the PC effect.

Effects of rosiglitazone, an antidiabetic drug, on Kv3.1 channels

  • Hyang Mi Lee;Seong Han Yoon;Min-Gul Kim;Sang June Hahn;Bok Hee Choi
    • The Korean Journal of Physiology and Pharmacology
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    • v.27 no.1
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    • pp.95-103
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    • 2023
  • Rosiglitazone is a thiazolidinedione-class antidiabetic drug that reduces blood glucose and glycated hemoglobin levels. We here investigated the interaction of rosiglitazone with Kv3.1 expressed in Chinese hamster ovary cells using the wholecell patch-clamp technique. Rosiglitazone rapidly and reversibly inhibited Kv3.1 currents in a concentration-dependent manner (IC50 = 29.8 µM) and accelerated the decay of Kv3.1 currents without modifying the activation kinetics. The rosiglitazonemediated inhibition of Kv3.1 channels increased steeply in a sigmoidal pattern over the voltage range of -20 to +30 mV, whereas it was voltage-independent in the voltage range above +30 mV, where the channels were fully activated. The deactivation of Kv3.1 current, measured along with tail currents, was also slowed by the drug. In addition, the steady-state inactivation curve of Kv3.1 by rosiglitazone shifts to a negative potential without significant change in the slope value. All the results with the use dependence of the rosiglitazone-mediated blockade suggest that rosiglitazone acts on Kv3.1 channels as an open channel blocker.

Generation of Super-Resolution Benchmark Dataset for Compact Advanced Satellite 500 Imagery and Proof of Concept Results

  • Yonghyun Kim;Jisang Park;Daesub Yoon
    • Korean Journal of Remote Sensing
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    • v.39 no.4
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    • pp.459-466
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    • 2023
  • In the last decade, artificial intelligence's dramatic advancement with the development of various deep learning techniques has significantly contributed to remote sensing fields and satellite image applications. Among many prominent areas, super-resolution research has seen substantial growth with the release of several benchmark datasets and the rise of generative adversarial network-based studies. However, most previously published remote sensing benchmark datasets represent spatial resolution within approximately 10 meters, imposing limitations when directly applying for super-resolution of small objects with cm unit spatial resolution. Furthermore, if the dataset lacks a global spatial distribution and is specialized in particular land covers, the consequent lack of feature diversity can directly impact the quantitative performance and prevent the formation of robust foundation models. To overcome these issues, this paper proposes a method to generate benchmark datasets by simulating the modulation transfer functions of the sensor. The proposed approach leverages the simulation method with a solid theoretical foundation, notably recognized in image fusion. Additionally, the generated benchmark dataset is applied to state-of-the-art super-resolution base models for quantitative and visual analysis and discusses the shortcomings of the existing datasets. Through these efforts, we anticipate that the proposed benchmark dataset will facilitate various super-resolution research shortly in Korea.

Handling dependencies among performance shaping factors in SPARH through DEMATEL method

  • Zhihui Xu;Shuwen Shang;Xiaoyan Su;Hong Qian;Xiaolei Pan
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.2897-2904
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    • 2023
  • The Standardized Plant Analysis Risk-Human Reliability Analysis (SPAR-H) method is a widely used method in human reliability analysis (HRA). Performance shaping factors (PSFs) refer to the factors that may influence human performance and are used to adjust nominal human error probabilities (HEPs) in SPAR-H. However, the PSFs are assumed to be independent, which is unrealistic and can lead to unreasonable estimation of HEPs. In this paper, a new method is proposed to handle the dependencies among PSFs in SPAR-H to obtain more reasonable results. Firstly, the dependencies among PSFs are analyzed by using decision-making trial and evaluation laboratory (DEMATEL) method. Then, PSFs are assigned different weights according to their dependent relationships. Finally, multipliers of PSFs are modified based on the relative weights of PSFs. A case study is illustrated that the proposed method is effective in handling the dependent PSFs in SPAR-H, where the duplicate calculations of the dependent part can be reduced. The proposed method can deal with a more general situation that PSFs are dependent, and can provide more reasonable results.

Electron Transport and Magneto-optical Properties of Magnetic Shape-memory $Ni_2NnGa$ Alloy

  • Lee, Y.P.;Lee, S.J.;Kim, C.O.;Jin, X.S.;Zhou, Y.;Kudryavtsev, Y.V.;Rhee, J.Y.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.1
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    • pp.12-15
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    • 2002
  • The physical properties, including magneto-optical and transport ones, of Ni$_2$MnG$_2$ alloy in the martensitic and austenitic states were investigated. The dependence of the temperature coefficient of resistivity on temperature shows kinks at the structural and ferro-para magnetic transitions. Electron-magnon and electron-phonon scattering are analyzed to be the dominant scattering mechanisms of the Ni$_2$MnG$_2$ alloy in the martensitic and austenitic states, respectively. The experimental real parts of the off-diagonal components of the dielectric function present two sharp peaks, one at 1.9 eV and the other at 3.2 eV, and a broad shoulder at 3.5 eV, all are identified by the band-structure calculations. These peak positions are coincident with those in the corresponding optical-conductivity spectrum, which is thought to originate from the single-spin state in Ni$_2$MnG$_2$ alloy.

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Online Multi-Task Learning and Wearable Biosensor-based Detection of Multiple Seniors' Stress in Daily Interaction with the Urban Environment

  • Lee, Gaang;Jebelli, Houtan;Lee, SangHyun
    • International conference on construction engineering and project management
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    • 2020.12a
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    • pp.387-396
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    • 2020
  • Wearable biosensors have the potential to non-invasively and continuously monitor seniors' stress in their daily interaction with the urban environment, thereby enabling to address the stress and ultimately advance their outdoor mobility. However, current wearable biosensor-based stress detection methods have several drawbacks in field application due to their dependence on batch-learning algorithms. First, these methods train a single classifier, which might not account for multiple subjects' different physiological reactivity to stress. Second, they require a great deal of computational power to store and reuse all previous data for updating the signle classifier. To address this issue, we tested the feasibility of online multi-task learning (OMTL) algorithms to identify multiple seniors' stress from electrodermal activity (EDA) collected by a wristband-type biosensor in a daily trip setting. As a result, OMTL algorithms showed the higher test accuracy (75.7%, 76.2%, and 71.2%) than a batch-learning algorithm (64.8%). This finding demonstrates that the OMTL algorithms can strengthen the field applicability of the wearable biosensor-based stress detection, thereby contributing to better understanding the seniors' stress in the urban environment and ultimately advancing their mobility.

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How Content Affects Clicks: A Dynamic Model of Online Content Consumption

  • Inyoung Chae;Da Young Kim
    • Asia pacific journal of information systems
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    • v.31 no.4
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    • pp.606-632
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    • 2021
  • With many consumers being exposed to news via social media platforms, news organizations are challenged to attract visitors and generate revenue during visits to their websites. They therefore need detailed information on how to write articles and headlines to increase visitors' engagement with the content to drive advertising revenues. For those news organizations whose business model depends mainly on advertisements, rather than subscriptions, it is particularly crucial to understand what makes the website attractive to their visitors, what drives users to stay on the website, and what factors affect a user's exit decision. The current research examines individual news consumers' choices to find patterns of increase or decrease in user engagement relative to a variety of topics, as well as to the mood or tone of the content. Using clickstream data from a major news organization, the authors develop a user-level dynamic model of clickstream behavior that takes into account the content of both headlines and stories that visitors read. The authors find that readers appear to exhibit state dependence in the tone of the articles that they read. They also show how the topics expressed in headlines can affect the amount of content readers consume when visiting the news organization to a much larger degree than the topics expressed in the content of the article. Online publishers can make use of such findings to present visitors with content that is likely to maintain and/or increase their engagement and consequently drive advertising revenue.

Temperature Dependence of Oxygen Diffusivity in the PVC Film on Gold Electrode Using Steady-State Rotating Disk Electrode Technique and Modulated Electrohydrodynamic Impedance Technique (정상상태 회전원판전극(RDE) 방법과 유체역학적 요동에 의한 전기화학적(EHD) 임피던스방법을 이용한 금전극표면에 형성된 PVC 피막내 산소확산계수의 온도의존성에 대한 연구)

  • Yeon Jei-Won;Pyun Su-Il;Lee Woo-Jin;Choi In-Kyu
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.49-56
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    • 2000
  • In the present we.k, temperature dependence of oxygen diffusivity in the polyvinyl chloride (PVC) film $D_f$ formed on gold electrode was investigated using steady-state rotating disk electrode (RDE) technique and modulated electrohydrodynamic (EHD) impedance technique. Both the diffusion rate defined as the ratio of oxygen diffusivity in the PVC film to the film thickness $D_f/\delta_f$ and the time constant $\delta_f^2/D_f$ for oxygen diffusion through the PVC film were obtained from plot of the limiting current versus disk rotation speed and from filing the EHD impedance spectra experimentally measured to those theoretically calculated on the basis of the diffusion equation for mass transport through the non-conductive and porous film, respectively. By combining measured $D_f/\delta_f$ with $\delta_f^2/D_f$, we determined $\delta_f\;and\;D_f$ at room temperature separately. As temperature increased, it appeared that the $D_f$ value measured for the PVC film-covered gold RDE was enhanced more rapidly than that $D_s$ value in the solution measured for the PVC film-free gold RDE. This means that the pores glowing with increasing temperature act as effective diffusion paths within the film. The present in-situ steady-state and modulated EHD measurements prove to be effective for determining $\delta_f\;and\;D_f$, separately and at the same time the porosity of the PVC film at temperatures below glass temperature $T_g$ of the film.

Anxiety, Impulsiveness, and Drinking Problems in Employed Women (직장 여성의 불안, 충동성과 음주문제)

  • Lee, Hyun Jae;Han, Doug Hyun;Lee, Young Sik;Kee, Baik Seok;Kwon, Hye Jin;Park, Doo Byung
    • Anxiety and mood
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    • v.7 no.2
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    • pp.73-78
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    • 2011
  • Objectives : This study examined drinking habits, anxiety, and impulsiveness in employed women. Methods : We sampled 925 residents aged over 20 years in Gwanak-gu of Seoul. In the process, we divided subjects into employed women and unemployed women groups and then used the Korean Version of Alcohol Use Disorder Identification Test (AUDIT-K), State-Trait Anxiety Inventory (STAI), and Barratt Impulsiveness Scale (BIS) to identify patterns in subjects' alcohol drinking, anxiety and impulsiveness. Results : Among the 925 respondents, 95.7% drank alcohol, and after the analysis, female problematic drinking ($12{\leq}AUDIT-K{\leq}25$) and alcohol dependence ($AUDIT-K{\geq}26$) was apparent in 61 (9.5%) and 2 respondents (0.3%), respectively. Female respondents who had jobs tended to drink more and exhibit higher ratios of problematic drinking, with a higher exposure to alcohol than those that were unemployed. The psychological attributes related to female respondents' alcohol problems related to state of anxiety and impulsiveness. Employed women respondents also showed a higher state of anxiety and impulsiveness than unemployed women. Conclusion : Controlling the frequency of exposure to alcohol, anxiety, and impulsiveness in employed women should be considered to be crucial controlling factors related to the hazards of excessive drinking.

Electrode Dependence of Asymmetric Behavior of (La,Sr)CoO₃/Pb(Zr,Ti)O₃/(La,Sr)CoO₃ Thin Film Capacitors ((La,Sr)CoO₃/Pb(Zr,Ti)O₃/(La,Sr)CoO₃박막 캐패시터의 비대칭성의 전극 의존성)

  • 최치홍;이재찬;박배호;노태원
    • Journal of the Korean Ceramic Society
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    • v.35 no.7
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    • pp.647-647
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    • 1998
  • (La,Sr)CoO3/Pb(Zr,Ti)O3/(La,Sr)CoO3 (LSCO) heterostructures have been grown on LaAlO3 substrates by pulsed laser deposition (PLD) to investigate asymmetric polarization of Pb(Zr,Ti)O3 (PZT) thin flims with different electrode configuration. P-V hysteresis loop of LSCO/PZT/LSCO was symmetric. However, LaCoO3 (LCO_/PZT/LSCO showed a largely asymmetric P-V hystersis loop and large relaxation of the remanent polarization at the negatively poled state, which means that the negatively poled state was unstable. On the other hand, LSCO/PZT/LCO exhibited large relaxation of the positively poled state. The asymmetric behavior of the polarized states implies the presence of an interal electric firld inside the PZT layer. It is suggested that internal electric field is caused by built-in voltages at LCO/PZT and LSCO/PZT interfaces. The built-in voltages at LCO/PZT and CSCO/PZT interfaces were 0.6 V and -0.12 V, respectively.