• Title/Summary/Keyword: Standard gas

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Comparison of Formaldehyde Emission of Wood-based Panels with Different Adhesive-hardener Combinations by Gas Chromatography and Standard Methods

  • Eom, Young Geun;Kim, Sumin;Baek, In-Chan;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.2 s.130
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    • pp.29-39
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    • 2005
  • Formaldehyde emissions from wood-based panels bonded with pine and wattle tannin-based adhesives, urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), and co-polycondensed resin of urea-melamine-formaldehyde (UMF) were measured by the Japanese standard method using a desiccator (JIS A 1460) and the EN 120 (European Committee For Standardization, 1991) method using the perforator value. In formaldehyde emission, all particleboards made using the wattle tannin-based adhesive with three different hardeners, paraformaldehyde, hexamethylenetetramine, and tris(hydroxyl)nitromethan (TN), satisfied the requirements of grade $E_1$. But only those made using the pine tannin-based adhesive with the hexamine as hardener met the grade $E_1$ requirements. Hexamine was effective in reducing formaldehyde emission in tannin-based adhesives when used as the hardener. While the UF resin showed a desiccator value of $7.1mg/{\ell}$ and a perforator value of 12.1 mg/100 g, the MF resin exhibited a desiccator value of $0.6mg/{\ell}$ and a perforator value of 2.9 mg/100 g. According to the Japanese Industrial Standard and the European Standard, the formaldehyde emission level of the MDF panels made with UF resin in this study came under grade $E_2$. The formaldehyde emission level was dramatically reduced by the addition of MF resin. The desiccator and perforator methods produced proportionally equivalent results. Gas chromatography, a more sensitive and advanced method, was also used. The samples for gas chromatography were gathered during the experiment involving the perforator method. The formaldehyde contents measured by gas chromatography were directly proportional to the perforator values.

A Study on the Safety Improvement by CFD Analysis for Packaged Type Hydrogen Refueling System (CFD 툴을 활용한 패키지형 수소충전시스템의 안전성 향상 연구)

  • HWANG, SOON-IL;KANG, SEUNG-KYU;HUH, YUN-SIL
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.243-250
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    • 2019
  • In this study, to ensure the safety of the packaged hydrogen refueling system, the improvement plan was derived by using 3-dimensional CFD program (FLACS). We also confirmed the effectiveness of risk reduction and the suitability of safety standard. By ventilation performance evaluation according to the position of the vent, it demonstrated that the vent should be installed at the ceiling to safely ventilate without stagnation of the leaked gas. In case of ventilation system according to KGS standard, risk situation could be resolved after about 5 minutes in the worst leaked condition. The result showed that jet fire and explosion inside the packaged system could affect the surrounding facilities. This proves that the standard for installing flame detectors, emergency shut down system and protection wall is appropriate.

Analysis Method of Volatile Sulfur Compounds Utilizing Separation Column and Metal Oxide Semiconductor Gas Sensor

  • Han-Soo Kim;Inho Kim;Eun Duck Park;Sang-Do Han
    • Journal of Sensor Science and Technology
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    • v.33 no.3
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    • pp.125-133
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    • 2024
  • Gas chromatography (GC) separation technology and metal oxide semiconductor (MOS) gas sensors have been integrated for the effective analysis of volatile sulfur compounds (VSCs) such as H2S, CH3SH, (CH3)2S, and (CH3)2S2. The separation and detection characteristics of the GC/MOS system using diluted standard gases were investigated for the qualitative and quantitative analysis of VSCs. The typical concentrations of the standard gases were 0.1, 0.5, 1.0, 5.0, and 10.0 ppm. The GC/MOS system successfully separated H2S, CH3SH, (CH3)2S, and (CH3)2S2 using a celite-filled column. The reproducibility of the retention time measurements was at a 3% relative standard deviation level, and the correlation coefficient (R2) for the VSC concentration was greater than 0.99. In addition, the chromatograms of single and mixed gases were almost identical.

A Development of Representative Condition Evaluation Standard for LNG Storage Tank Structures (LNG 저장탱크 구조물의 종합적 상태평가기준 개발)

  • Kim, Jung-Hoon;Jo, Young-Do
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.44-51
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    • 2018
  • As the LNG storage tank is aged, if there is a crack in the outer wall concrete or corrosion of the reinforcing steel, there is a risk of a major accident such as collapse of the structure depending on the type and degree of damage. Since 2014, LNG storage tanks have undergone precise safety diagnosis and safety inspection has been carried out. The condition evaluation criteria for each component have been revised and applied in January 2016. The condition evaluation standard is to evaluate the status of storage tanks based on the appearance survey and material test results of LNG storage tanks and it is important for maintenance. In addition, the representative condition evaluation standard that shows the comprehensive state of each LNG storage tank is important in maintenance, but the related standard for LNG storage tank outer concrete is not available in Korea and abroad, and development of the condition evaluation standard is necessary. In this paper, we examined the structural characteristics of LNG storage tanks, analyzed the status of the condition evaluation criteria for each member, and developed a comprehensive status rating system by weighting the members. We used the AHP(Analytic Hierarchy Process) technique and developed a representative conditon evaluation criteria through surveys of professional organizations.

A Study on the Development and Accuracy Improvement of an IR Combustible Gas Leak Detector with Explosion Proof (방폭형 적외선 가연성가스 누출검지기 개발 및 정확도 향상 연구)

  • Park, Gyou-Tae;Lyu, Geun-Jun;Jo, Young-Do;Kwon, Jeong-Rock;Ahn, Sang-Guk;Kim, Hie-Sik
    • Journal of the Korean Institute of Gas
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    • v.18 no.3
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    • pp.1-12
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    • 2014
  • In this paper, we developed an explosion proof type and portable combustible gas leak detector and proposed an algorithm to improve the accuracy for measuring gaseous concentrations. The nation's first we developed an infrared gas leak detector with explosion proof standard(Ex d ib) and improved measuring accuracy by using linearization recursion equation and 2nd Lagrange interpolation polynomial. Together, we advanced their performances and added their easy functions after investigating field demands. To compare our and other company's detectors, we performed measurement tests with eight standard gases made by Korea Gas Safety Corporation. We demonstrated the excellence of our instruments in measuring accuracy other than detecters through experimental results.

Determination of Bi Impurity in Lead Stock Standard Solutions by Hydride-generation Inductively Coupled Plasma Mass Spectrometry

  • Park, Chang J.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.233-236
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    • 2004
  • Total impurity analysis of a primary standard solution is one of the essential procedures to determine an accurate concentration of the standard solution by the gravimetry. Bi impurity is determined in Pb standard solutions by inductively coupled plasma mass spectrometry (ICP-MS). The direct nebulization of the Pb standard solution produces a significant amount of the Pb matrix-induced molecular ions which give rise to a serious spectral interference to the Bi determination. In order to avoid the spectral interference from the interferent $^{208}PbH^+$, the hydride generation method is employed for the matrix separation. The Bi hydride vapor is generated by reaction of the sample solution with 1% sodium borohydride solution. The vapor is then directed by argon carrier gas into the ICP after separation from the mixture solution in a liquid-gas separator made of a polytetrafluoroethylene membrane tube. The presence of 1000 ${\mu}$g/mL Pb matrix caused reduction of the bismuthine generation efficiency by about 40%. The standard addition method is used to overcome the chemical interference from the Pb matrix. Optimum conditions are investigated for the hydride-generation ICPMS. The detection limit of this method is 0.5 pg/mL for the sample solutions containing 1000 ${\mu}$g/mL Pb matrix.

A Fundamental Study on the Determination of Optimal Mixing Ratio for Development of Standard Reference Materials for Concrete (콘크리트용 표준물질(Standard Reference Materials)개발의 최적배합비율 결정을 위한 기초연구)

  • Lee, Dong Kyu;Choi, Myoung Sung
    • Journal of the Korean Society of Safety
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    • v.34 no.5
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    • pp.111-118
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    • 2019
  • Recently, a variety of special concrete structures have been designed in domestic and overseas construction markets and more advanced construction technology is required. Therefore, it is necessary to secure quantitative construction technology. For this purpose, it is essential to develop a standard reference material having a constant flow performance and quality to evaluate quantitative performance. On the other hand, the flowability of the concrete is greatly influenced by the flowability of the cement paste. Also, in consideration of design strength and workability, mix design is carried out at various mixing ratios according to the purpose of the site. Therefore, in this study, based on the derived components of standard reference materials for cement paste, we suggested mixing ratio of standard reference materials that can uniformly simulate the flow characteristics of cement paste according to W/C. As a result, it was found that the yield stress was determined by the ratio of water and glycerol but plastic viscosity was controled by limestone content. Finally, the ratio of standard reference materials to simulate the rheological range of cement paste by W/C was suggested.

Influence of SF6/N2 Gas Mixture Ratios on the Lightning Streamer Propagation Characteristics of 22 kV MV Circuit Breaker

  • Gandhi, R.;Chandrasekar, S.;Nagarajan, C.
    • Journal of Electrical Engineering and Technology
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    • v.13 no.4
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    • pp.1663-1672
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    • 2018
  • In recent times, gas insulated medium voltage (MV) circuit breakers (CB) form a vital component in power system network, considering its advantages such as reduced size and safety margins. Gas insulation characteristics of circuit breakers are generally measured by lightning impulse (LI) test according to IEC standard 60060-1 as a factory routine test. Considering the environmental issues of $SF_6$ gas, many research works are being carried out towards the mixture of $SF_6$ gases for high voltage insulation applications. However, few reports are only available regarding the LI withstand and streamer propagation characteristics (at both positive and negative polarity of waveform) of $SF_6/N_2$ gas mixture insulated medium voltage circuit breakers. In this paper, positive and negative polarity LI tests are carried out on 22 kV medium voltage circuit breaker filled with $SF_6/N_2$ gas mixture at different gas pressures (1-5 bar) and at different gas mixture ratios. Important LI parameters such as breakdown voltage, streamer velocity, time to breakdown and acceleration voltage are evaluated with IEC standard LI ($1.2/50{\mu}s$) waveform. Weibull distribution analysis of LI breakdown voltage data is carried out and 50% probability breakdown voltage, scale parameter and shape parameter are evaluated. Results illustrate that the $25%SF_6+75%N_2$ gas filled insulation considerably enhances the LI withstand and breakdown strength of MV circuit breakers. LI breakdown voltage of circuit breaker under negative polarity shows higher value when compared with positive polarity. Results show that maintaining the gas pressure at 0.3 MPa (3 bar) with 10% $SF_6$ gas mixed with 90% $N_2$ will give optimum lighting impulse withstand performance of 22 kV MV circuit breaker.

The Design & Manufacture of Multi-coil Eddy Current Sensor and Characteristic Analysis (다중코일 와전류 센서 설계제작 및 특성분석)

  • Ahn, Y.S.;Gil, D.S.;Park, S.G.
    • Journal of Power System Engineering
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    • v.15 no.3
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    • pp.65-69
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    • 2011
  • This paper introduces the multi-coil eddy current sensor and its characteristic in magnetic material gas turbine rotor. In the past, magnetic particle inspection method was used for qualitative defect evaluation in magnetic material gas turbine rotor. And the ultrasonic inspection method was used for quantitative defect evaluation. Nowadays, eddy current method is used in magnetic gas turbine rotor inspection due to advanced sensor design technology. We developed multi-coil eddy current sensor for the rotor dovetail inspection. At first, rotor stress is analyzed for the determination of sensor position and number. The sensor coils are designed to cover the stress concentration area of rotor dovetail. We select optimum frequency according to material standard penetration data and experiment results. The rotor mock-up and artificial defects were made for the signal detection and resolution analysis of multi-coil eddy current sensor. The results show that signal detection and resolution capabilities are enhanced in comparison to the commercialized sensor enough for the gas turbine rotor inspection. So, this developed multi-coil eddy current sensor substituted for commercialized one and it applied in real gas turbine rotor inspection.