• 제목/요약/키워드: Stainless steel electrode

검색결과 123건 처리시간 0.03초

스테인레스 강의 전해연마 가공특성에 관한 연구 (A Study on the Machining Characteristics of Electropolishing for Stainless Steel)

  • 박정우
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 1998년도 추계학술대회 논문집
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    • pp.186-191
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    • 1998
  • Electropolishing is the anodic dissolution process in the transpassive state. It removes non-metallic inclusions and improves mechanical and corrosion resistance of stainless steel. If there is a Bailby layer, it will be recovered again. Electropolishing is normally used to remove a very thin layer of material on the surface of a metal component. The aim of this study is to determine the tendencies of electropolishing STS316L tubes in terms of current density, machining time, temperature, electrode gap and surface roughness.

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마이크로 드로플릿 셀 기법을 이용한 예민화 된 304 스테인리스강의 미세전기화학 특성 (Micro-electrochemical Characteristics of Sensitized 304 Stainless steel Using Micro-droplet cell Techniques)

  • 김규섭;이재봉
    • Corrosion Science and Technology
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    • 제9권6호
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    • pp.300-309
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    • 2010
  • The influences of sensitization on localized corrosion resistance of 304 stainless steel, were investigated, using micro-dropletcell techniques. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local current with the potentiodynamic polarization, linear polarization and a.c. impedance. Micro-electrochemical tests were carried out inside of the grain and on grain boundaries separately. It was found that sensitization decreased the pitting potential, increasing corrosion current density around grain boundaries. Galvanic current density was also measured between grain and grain boundaries.

PEMFC용 금속분리판 코팅 기술 개발 : II. 코팅 금속분리판 연료전지 성능 특성 연구 (Development of Surface Coating Technology for Metallic Bipolar Hate in PEMFC : II. Study on the PEMEC Performance of Coated Metallic Bipolar Plate)

  • 윤용식;정경우;양유창;안승균;전유택;나상묵
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.352-355
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    • 2006
  • As the stainless steel has good corrosion resistance, mechanical property and ease of manufacture, it has been studied as the candidate material of metallic bipolar plate for automotive PIMFC. But, metal is dissolved under fuel cell operating conditions Dissolved ions contaminate a membrane electrode assembly (MEA) and, decrease the fuel cell performance. In addition, metal oxide formation on the surface of stainless steel increases the contact resistance in the fuel cell. These problems have been acted as an obstacle in the application of stainless steel to bipolar plate. Therefore, many kinds of coating technologies have been examined in order to solve these problems. In this study, stainless steel was coated in order to achieve high conductivity and corrosion resistance by several methods. Contact resistance was measured by using a tensile tester and impedance analyzer Corrosion characteristics of coated stainless steel were examined by Tafel-extrapolation method from the polarization curves in a solution simulating the anodic and cathodic environment of PEMFC. Fuel cell performance was also evaluated by single cell test. We tested various coated metal bipolar plate and conventional and graphite were also tested as comparative samples. In the result, coated stainless steel bipolar plate exhibited better cell performance than graphite to bipolar plate.

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전기분해를 이용한 크롬과 아연함유 폐수처리 (Treatment of Wastewater containing Cromium and Zinc by Electrolysis)

  • 김재용;엄명헌
    • 환경위생공학
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    • 제16권3호
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    • pp.87-95
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    • 2001
  • We've been investegated to find the optimum operation condition of electrlysis which have an influance on disposal efficiency of heavy metals. When we electrolyzed the testing wastewaters containing each 250mg/L of Cr and Zn ions, we exerimented with using variables like as pH, NaCl, electrode gap, electric current strength, the number of electrodes, after fastening positive electrode plate with Al, Fe, Ti and negative electrode plate with Stainless Steel Plate.

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알칼리 용액이 수소배관으로 사용되는 Stainless steel에 미치는 영향 분석 (An Analysis on Stainless Steel for Hydrogen Generator' Pipeline Interacting with Alkaline Solution)

  • 변창섭;최진영;임수곤;황갑진;최호상;신훈규
    • 한국수소및신에너지학회논문집
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    • 제23권3호
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    • pp.207-212
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    • 2012
  • This study was performed to observe the change of stainless steel pipe interacting with alkaline solution. We used STS316L and STS304 as samples which were soaked in alkaline solution. We measured the samples by use of FE-SEM, EDX, SIMS to observe the surface and depth profile of both samples. The result showed that the precipitate appeared on the surface of both samples from 5 days. but the precipitate was confirmed to be decreased as time passes. but the quantitative change of precipitates at both samples was different as time passed. The EDX showed that the precipitate is Potassium from solution of Electrolysis. The result also showed that the primary elements of stainless steel pipeline and of Alkaline Solution were changed. The change of primary elements was severe between 5 days to 16 days and was stable around 40 days at both samples. The reaction of STS316L with alkaline solution was lower than STS304. We hoped that this study would be the foundation of developing the electrode of the alkaline hydrogen generator.

스텐철사를 전극으로 이용하는 미생물연료전지의 전류 발생 (Current Generation from Microbial Fuel Cell Using Stainless Steel Wire as Anode Electrode)

  • 장재경;김경민;변성아;유영선;장인섭;강연구;김영화
    • 대한환경공학회지
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    • 제36권11호
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    • pp.753-757
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    • 2014
  • 산화전극부 전극은 단순히 전자를 받아 전달할 수 있는 역할 뿐만 아니라 공극이 많아 표면적이 큰 구조로 미생물을 고정화할 수 있는 표면적을 제공할 수 있어야 한다. 미생물의 수가 많을수록 폐수처리 효율과 전류발생을 높일 수 있기 때문이다. 따라서 전극은 미생물연료전지의 효율을 높일 수 있는 중요한 역할을 하는 인자 중의 하나이다. 본 연구는 미생물연료전지에 사용하는 고가의 흑연펠트를 스텐철사 타래(철 수세미)로 대체할 수 있는지 알아보기 위한 것이다. 이 연구에 사용된 가축분뇨는 전처리를 거친 후 유기오염물질(COD)로 500 mg/L로 희석한 것을 이용하였고, 이때 전류 발생은 스텐철사 타래를 적용하였을 때 약 5% 정도 낮았지만 큰 차이가 없는 것으로 나타났다. 유기오염물질(COD)의 감소는 스텐철사 타래를 이용하였을 때 88.3%이었으며, 흑연펠트를 사용하였을 때 82.4%로 스텐철사 타래의 제거율이 더 높게 나타났다. 암모니아성 질소 이온의 경우는 두 경우 모두 반응시간에 따라 농도 변화가 거의 없는 것으로 나타났다. 이 결과 스텐철사 타래를 적용하였을 때 전류발생이나 수처리 측면 모두 효과가 유사하거나 더 좋은 결과를 보였으며, 초기 시스템을 구축하는 비용을 약 1/50 정도로 줄일 수 있는 것으로 예상되어. 흑연펠트 대체제로 적용이 가능할 것으로 판단된다.

부동화 금속의 미세 전해 가공 시 전극 전위의 선정 (Determination of Electrode Potential in Micro Electrochemical Machining of Passive Metals)

  • 남호성;김보현;주종남;박병진
    • 한국정밀공학회지
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    • 제23권4호
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    • pp.146-152
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    • 2006
  • In micro electrochemical machining (ECM), electrodes should be prevented from unfavorable oxide and Passive layer formation on the machined surface or overall corrosion of the entire surface. Generally, metal electrodes corrode, passivate or dissolve in the electrochemical cell according to the electrode potential. Therefore, each electrode must maintain its stable potential. Tn this paper, the stable electrode potentials of tool and workpiece were determined using the potentiodynamic polarization test and verified experimentally considering machining stability and surface quality. Stable workpiece electrode potentials of two different passive materials of 304 stainless steel and nickel were determined in the 0.1 M sulfuric acid. Experimental results show good machined surface and fast machining rate using the determined electrode potentials.

전기화학적 임피던스 Fitting 개선을 위한 전극/전해질 계면의 전기회로 모델 연구 (A Study on the Electrical Circuit Model of the Electrode/Electrolyte Interface for Improving Electrochemical Impedance Fitting)

  • 장종현;박정호
    • 전기학회논문지
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    • 제56권6호
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    • pp.1087-1091
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    • 2007
  • Exact impedance modeling of the electrode/electrolyte interface is important in bio-signal sensing electrode development. Therefore, the investigation of the equivalent circuit models for the interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. The proposed model consists of three resistors and two constant phase elements. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

Highly Flexible Dye-sensitized Solar Cell Prepared on Single Metal Mesh

  • Yun, Min Ju;Cha, Seung I.;Seo, Seon Hee;Lee, Dong Y.
    • Current Photovoltaic Research
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    • 제2권3호
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    • pp.79-83
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    • 2014
  • Dye-sensitized solar cells (DSSCs) are applied in the emerging fields of building integrated photovoltaic and electronics integrated photovoltaic like small portable power sources as demands are increased with characteristic advantages. Highly flexible dye-sensitized solar cells (DSSCs) prepared on single stainless steel mesh were proposed in this paper. Single mesh DSSCs structure utilizing the spraying the chopped glass paper on the surface treated stainless steel mesh for integrating the space element and the electrode components, counter electrode component and photoelectrode component were coated on each side of the single mesh. The fabricated single mesh DSSCs showed the energy-conversion efficiency 0.50% which show highly bendable ability. The new single mesh DSSCs may have potential applications as highly bendable solar cells to overcome the limitations of TCO-based DSSCs.

미세 내부 형상 가공을 위한 디스크 전극 이용 전해 가공 (Electrochemical Machining Using a Disk Electrode for Micro Internal Features)

  • 조찬희;김보현;주종남
    • 한국정밀공학회지
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    • 제25권7호
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    • pp.139-144
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    • 2008
  • Micro electrochemical machining was investigated to machine micro internal features. This method uses a micro disk tool electrode and can easily machine micro features inside of a micro hole, which are very difficult to make by the conventional processes. In order to limit the machining area and localize the electrochemical dissolution, ultra short pulses were used as power source and a micro disk electrode with insulating layer on its surface was used as a tool electrode. By electrochemical process, internal features, such as groove array, were fabricated on the stainless steel plate.