• Title/Summary/Keyword: Stacking fault

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Energetics of adsorptions on fcc(111) and binary system; An application of the modified embedded atom method

  • Hy. Shin;J. Seo;Kim, J.S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.188-188
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    • 1999
  • The embedded atom method (EAM) of Daw and Baskes as a semiempirical method, has been successfully applied to the fcc or nearly filled d-band transition metals due to its computational feasibility and its methodological simplicity. Then Baskes modified the EAM (MEAM) to include directional bonding and applied it to metals, semiconductors, and diatomic gases, all of which have different types of bondings. Here, we present a detailed study of the energetics of adsorption on the fcc(111) surfaces and binary system within the framework of MEAM. In adsorption on fcc(111) surfaces, there are two energetically favored sites, so called, fcc site and hcp site, which may trigger stacking fault in the growth of films and might switch growth mode between 3D growth and layer by layer growth. We scrutinized the role of the hcp sites, which would offer dynamic growth pathways although the dynamics are not yet clear within the limited experimental resolution. Featuring these transient motions in the atomic level should contribute to the understanding the growth mechanisms on fcc(111) surface. And we also applied MEAM for initial stage energetics at the Cr coverage of sub- monolayer on W(110). We hope that recently observed extraordinary growth behavior at the Cr coverage of 0.7 monolayer, self- organized nano-scale lines, can be resolved in this MEAM binary system calculation.

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Development of Alloy with High Strength and Damping Capacity for High-Performance of Precision Devices by Vibration Control (진동제어에 의한 정밀기기의 고성능화를 위한 고강도 및 고감쇠능 합금개발)

  • Kana, Chang-Yong;Kim, Ik-Su
    • Journal of Ocean Engineering and Technology
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    • v.22 no.6
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    • pp.46-51
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    • 2008
  • The effect of the addition of Co and N and subzero treatment on tensile strength and damping capacity was investigated in Fe-Cr-Mn alloy. Austenite was transformed into martensite by cold rollins increasing the degree of cold rollins led to an increase in the volume fraction of martensite. The damping capacity linearly increased with increasing volume fraction of ${\varepsilon}$ martensite in cold rolled specimens and subzero treated specimens after cold rolling. The volume fraction of ${\varepsilon}$ martensite, tensile strength and damping capacity was also increased by the addition of Co, while this treatment decreased the elongation. However, the volume fraction of ${\varepsilon}$ martensite, elongation and damping capacity were reduced by the addition of N, although the tensile strength increased. Tensile strength and damping capacity werealso increased by subzero treatment, while elongation decreased.

Microstructural Investigation of the of the Cu Thin Films for ULSI Application) (ULSI용 Cu 박막의 미세조직 연구)

  • 박윤창
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.121-121
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    • 2000
  • 반도체 산업의 발달에 따라 소자의 보다 빠른 동작 속도와 큰 집적도를 갖은 ULSI 구조를 얻기 위해, 새로운 금속배선 재료가 요구되고 있다. 기존의 금속 배선인 Al 및 Al 합금은 비교적 낮은 비저항과 박막형성의 용이함으로 인하여 현재까지 금속배선 재료로 사용되고 있으나, 고집적화에 따라 RC Time Delay와 Electromigration의 문제점을 들어내었다. 이러한 문제를 해결할 새로운 배선 재료로 Al보다 낮은 비저항을 가지며, electromigration 저항성을 갖는 Cu 금속배선 재료가 활발히 연구되고 있다. 본 실험에서는 (100) Si 웨이퍼를 기판으로 사용하였으며, 각층은 SiO2/Si3N4/EP Cu/Seed Cu/ TaN/SiO2/Si wafer 상태로 증착하였다. 확산방지막으로 TaN을 사용하였고, seed Cu는 sputtering 으로 증착하였으며, seed Cu 만으로 된 박막과 seed Cu + electro plating Cu로 구성된 박막을 제작하였다. 제작 완료된 박막은 N2 분위기에서 20$0^{\circ}C$ 120 min, 45$0^{\circ}C$ 60min 동안 열처리하여 Cu 박막의 조직 변화를 TEM 및 여러 분석방법을 이용하여 분석하였다. Plan-view TEM결과, 45$0^{\circ}C$, 60min 열처리함에 따라 결정립 성장이 일어난 것을 확인 할 수 있었다. 그러나, 성장후에도 twin boundary, stacking fault, dislocation, small defect 등은 여전히 남아 있음이 관찰된다. 그림 1(a)는 as-deposit 상태이며, 그림 1(b)는 45$0^{\circ}C$, 60min 열처리한 plan-view TEM 사진이다.

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Analysis of Twin in Mg Alloys Using Electron Backscatter Diffraction Technique

  • Lee, Jong Youn;Kim, Won Tae;Kim, Do Hyang
    • Applied Microscopy
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    • v.44 no.1
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    • pp.34-39
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    • 2014
  • Electron backscatter diffraction (EBSD) is widely used for quantitative microstructural analysis of the crystallographic nature of variety of materials such as metals, minerals, and ceramics. EBSD can provide a wide range of information on materials including grain size, grain orientation, texture, and phase identity. In the case of metallic alloys, EBSD now has become an essential technique to analyze the texture, particularly when severe deformation is applied to the alloys. In addition, EBSD can be one of the very useful tools in identification of twin, particularly in Mg alloys. In Mg alloys different type of twin can occur depending on the c/a ratio and stacking fault energy on the twinning plane. Such an occurrence of different type of twin can be most effectively analyzed using EBSD technique. In this article, the recent development of Mg alloys and occurrence of twin in Mg are reviewed. Then, recently published example for identification of tension and compression twins in AZ31 and ZX31 is introduced to explain how EBSD can be used for identification of twin in Mg.

A Die-Selection Method Using Search-Space Conditions for Yield Enhancement in 3D Memory

  • Lee, Joo-Hwan;Park, Ki-Hyun;Kang, Sung-Ho
    • ETRI Journal
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    • v.33 no.6
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    • pp.904-913
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    • 2011
  • Three-dimensional (3D) memories using through-silicon vias (TSVs) as vertical buses across memory layers will likely be the first commercial application of 3D integrated circuit technology. The memory dies to stack together in a 3D memory are selected by a die-selection method. The conventional die-selection methods do not result in a high-enough yields of 3D memories because 3D memories are typically composed of known-good-dies (KGDs), which are repaired using self-contained redundancies. In 3D memory, redundancy sharing between neighboring vertical memory dies using TSVs is an effective strategy for yield enhancement. With the redundancy sharing strategy, a known-bad-die (KBD) possibly becomes a KGD after bonding. In this paper, we propose a novel die-selection method using KBDs as well as KGDs for yield enhancement in 3D memory. The proposed die-selection method uses three search-space conditions, which can reduce the search space for selecting memory dies to manufacture 3D memories. Simulation results show that the proposed die-selection method can significantly improve the yield of 3D memories in various fault distributions.

Effects of Strain Rate and Temperature on Tensile Properties of High Mn Twinning Induced Plasticity Steels (고망간 Twinning Induced Plasticity 강의 인장 특성에 미치는 변형률 속도와 온도의 영향)

  • Lee, Junghoon;Lee, Sunghak;Shin, Sang Yong
    • Korean Journal of Materials Research
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    • v.27 no.12
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    • pp.643-651
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    • 2017
  • Four types of high Mn TWIP(Twinning Induced Plasticity) steels were fabricated by varying the Mn and Al content, and the tensile properties were measured at various strain rates and temperatures. An examination of the tensile properties at room temperature revealed an increase in strength with increasing strain rate because mobile dislocations interacted rapidly with the dislocations in localized regions, whereas elongation and the number of serrations decreased. The strength decreased with increasing temperature, whereas the elongation increased. A martensitic transformation occurred in the 18Mn, 22Mn and 18Mn1.6Al steels tested at $-196^{\circ}C$ due to a decrease in the stacking fault energies with decreasing temperature. An examination of the tensile properties at $-196^{\circ}C$ showed that the strength of the non-Al added high Mn TWIP steels was high, whereas the elongation was low because of the martensitic transformation and brittle fracture mode. Although a martensitic transformation did not occur in the 18Mn1.9Al steel, the strength increased with decreasing temperature because many twins formed in the early stages of the tensile test and interacted rapidly with the dislocations.

Microstructure and Mechanical Properties of High Mn TWIP Steels (고 Mn계 TWIP 강의 미세조직과 기계적 성질)

  • Jung, J.K.;Lee, O.Y.;Park, Y.K.;Kim, D.E.;Jin, K.G.;Kim, S.K.;Song, K.H.
    • Korean Journal of Metals and Materials
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    • v.46 no.10
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    • pp.627-633
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    • 2008
  • The austenitic Fe-Mn alloys have received considerable attention as a possible candidate for the automotive structural materials due to their high strength and high formability with high elongation. This research investigates the effect of alloying elements on the phase transformation, deformation behavior and mechanical properties in high Mn steels for the development of a high strength high ductility steel. The mechanical stability of austenitic phases is very important for high ductility and it depends largely on the composition of carbon, manganese and aluminum. The dominant deformation mode shifts from TRIP to TWIP mode as the amount of C, Mn and Al is increased. Especially, even a small amount of Al addition facilitates significantly TWIP deformation due to the increase of stacking fault energy in Fe-Mn alloys, this leads to increase the ductility and also decrease the crack sensitivity.

Electrochemical Hydrogen Permeation Behaviors of Pre-Strained Fe-Mn-C TWIP Steel With or Without Zn Coating (소성인장변형 몇 아연도금된 Fe-Mn-C계 TWIP 강의 전기화학적 수소투과거동)

  • Sung Jin Kim
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.297-303
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    • 2023
  • This study aimed to evaluate hydrogen permeation behaviors of pre-strained twinning-induced plasticity steel with or without Zn coating using electrochemical permeation technique. In contrast to un-strained and 30% strained samples, permeation current density was measured in the 60% strained sample. Tensile pre-straining at 60% involved microstructural modifications, including a high level of dislocation density and stacking fault with a semi-coherent twin boundary, which might provide a high diffusion path for hydrogen atoms. However, reproducibility of measurements of hydrogen permeation current was low due to non-uniform deformation and localized stress concentration. On the other hand, the permeation current was not measured in pre-strained TWIP steel with Zn coating. Instead, numerous blisters with some cracks were observed on the surface of the coating layer. In locally damaged Zn coating under tensile straining, hydrogen atoms could relatively easily permeate through the coating layer. However, they were trapped at the interface between the coating layer and the substrate, which might delay hydrogen penetration into the steel substrate.

Effective Wavefield Separation of Reflected P- and PS-Waves in Multicomponent Seismic Data by Using Rotation Transform with Stacking (다성분 탄성파탐사자료에서 회전 변환과 중합을 이용한 효과적인 P파 반사파와 PS파 반사파의 분리)

  • Jeong, Soocheol;Byun, Joongmoo;Seol, Soon Jee
    • Geophysics and Geophysical Exploration
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    • v.16 no.1
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    • pp.6-17
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    • 2013
  • Multicomponent seismic data including both P- and PS-waves have advantages in discriminating the type of pore fluid, characterizing the lithologic attributes and producing the high resolution image. However, multicomponent seismic data recorded at the vertical and horizontal component receivers contain both P- and PS-waves which have different features, simultaneously. Therefore, the wavefield separation of P- and PS-waves as a preprocessing is inevitable in order to use the multicomponent seismic data successfully. In this study, we analyzed the previous study of the wavefield separation method suggested by Jeong and Byun in 2011, where the approximated reflection angle calculated only from one refernce depth is used in rotation transform, and showed its limitation for seismic data containing various reflected events from the multi-layered structure. In order to overcome its limitation, we suggested a new effective wavefield separation method of P- and PS-waves. In new method, we calculate the reflection angles with various reference depths and apply rotation transforms to the data with those reflection angles. Then we stack all results to obtain the final separated data. To verify our new method, we applied it to the synthetic data sets from a multi-layered model, a fault model, and the Marmousi-2 model. The results showed that the proposed method separated successfully P- and PS-reflection events from the multicomponent data from mild dipping layered model as long as the dip is not too steep.

사파이어 단결정 기판의 EPD 측정 및 신뢰성 연구

  • Lee, Yu-Min;Kim, Yeong-Heon;Ryu, Hyeon;Kim, Chang-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.317-317
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    • 2012
  • 사파이어는 우수한 광학적, 물리적, 화학적 특성을 가지고 있는 물질 중의 하나이며, 청색 발광특성을 나타내는 GaN와 격자상수, 열팽창 계수가 가장 유사할 뿐만 아니라 가격도 상대적으로 저렴하여 GaN 성장을 위한 기판으로 사용된다. 실제로 사파이어는 프로젝터와 전자파장치, 군사용 장비 등 다양한 분야에 응용되고 있으며, 발광 다이오드(LED)를 위한 기판으로 활용됨으로써 그 수요가 급격히 증가하고 있다. 그러나 사파이어 결정의 성장 중에 생길 수 있는 전위(dislocation)와 적층결함(stacking fault) 등의 결정 결함들은 결정 내에 존재하여 역학적, 전기적 성질에 큰 영향을 미칠 수 있다. 특히 사파이어가 청색 발광소자의 기판으로 사용되는 경우, 사파이어 기판 내부의 결정 결함은 증착되는 박막 특성에 영향을 미치게 된다. 따라서 사파이어의 보다 나은 응용을 위해서는 결함의 형성 메커니즘과 결정 결함의 평가기술 등에 대한 이해가 필요하고, 특히 결함의 정량적 평가 기술의 개발은 사파이어의 상용화에 중요한 핵심요소 중 하나이다. 결정 내 결함이 위치하는 부분은 분자나 원자간의 결합이 약하거나 높은 에너지 상태이므로, 결정의 표면을 적절한 산이나 염기 등을 이용하여 에칭하면 에칭반응은 결정의 전위 위치에 해당하는 부분부터 일어나 결정의 표면에 에치핏을 형성한다. 따라서 결정 표면에 나타나는 에치핏의 개수를 관찰하면 결정의 전위 밀도 파악이 비교적 간단하고, 에칭반응의 이러한 특징은 전위의 정량적 평가에 이용이 가능하다. 본 연구는 4인치 사파이어 조각기판을 수산화칼륨(KOH)으로 습식에칭 후 표면에 나타나는 에치핏의 형성거동과 이의 시간 및 온도 의존성에 관한 연구를 진행하였다. 또한 단결정의 전위밀도를 예측하기 위해 사파이어 조각시편의 단위면적당 에치핏의 개수를 파악하여 에치핏밀도(EPD, etch pid density)를 계산하였고, 값의 불확도(uncertainty)를 계산하여 전위밀도의 신뢰도를 평가하였다. 그 결과, 사파이어 조각시편의 에치핏밀도는 단위면적($cm^2$)당 약 ${\sim}10^2$개로 확인되었고, 이 값은 약 2%의 상대불확도를 가지는 것으로 나타났다.

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