• Title/Summary/Keyword: Stack degradation

Search Result 58, Processing Time 0.024 seconds

Para-virtualized Library for Bare-metal Network Performance in Virtualized Environment (가상화 환경의 고성능 I/O를 위한 반가상화 라이브러리)

  • Lee, Dongwoo;Cho, Youngjoong;Eom, Young Ik
    • Journal of KIISE
    • /
    • v.41 no.9
    • /
    • pp.605-610
    • /
    • 2014
  • Now, virtualization is no more emerging research area, and we can easily find its application in our circumstance. Nevertheless, I/O workloads are reluctant to be applied in virtual environment since they still suffer from unacceptable performance degradation due to virtualization latency. Many previous papers identified that virtual I/O overhead is mainly caused by exits and redundant I/O stack, and proposed several techniques to reduce them. However, they still have some limitations. In this paper, we introduce a novel I/O virtualization framework which improves I/O performance by exploiting multicore architecture. We applied our framework to the virtual network, and it improves TCP throughput up to 169%, and decreases UDP latency up to 38% on the network with the 10Gbps NIC.

Fault Detection and Diagnosis Methods for Polymer Electrolyte Fuel Cell System (고분자전해질연료전지를 위한 고장 검출 및 진단 기술)

  • LEE, WON-YONG;PARK, GU-GON;SOHN, YOUNG-JUN;KIM, SEUNG-GON;KIM, MINJIN
    • Journal of Hydrogen and New Energy
    • /
    • v.28 no.3
    • /
    • pp.252-272
    • /
    • 2017
  • Fuel cell systems have to satisfy acceptable operating reliability, sufficient lifetime and price to enter the market in competition with existing products. Fuel cells are made up of complex element technologies and various problems related to the failure of the components can affect the reliability and safety of the system. This problem can be overcome by introducing a monitoring and supervisory control system in addition to automatic control to detect the failure of the fuel cell quickly and properly diagnose the performance degradation. For the fault detection and diagnosis of polymer electrolyte fuel cells, the model based method using the theoretical superposition value and the non-model based method of checking the signal tendency or the converted signal characteristic can be applied. The methods analyzed in this paper can contribute to the development of integrated monitoring and control technology for the whole system as well as the stack.

Fabrication of Cu2ZnSnS4 Films by Rapid Thermal Annealing of Cu/ZnSn/Cu Precursor Layer and Their Application to Solar Cells

  • Chalapathy, R.B.V.;Jung, Gwang Sun;Ko, Young Min;Ahn, Byung Tae;Kwon, HyukSang
    • Current Photovoltaic Research
    • /
    • v.1 no.2
    • /
    • pp.82-89
    • /
    • 2013
  • $Cu_2ZnSnS_4$ thin film have been fabricated by rapid thermal annealing of dc-sputtered metal precursor with Cu/ZnSn/Cu stack in sulfur ambient. A CZTS film with a good uniformity was formed at $560^{\circ}C$ in 6 min. $Cu_2SnS_3$ and $Cu_3SnS_4$ secondary phases were present at $540^{\circ}C$ and a trace amount of $Cu_2SnS_3$ secondary phase was present at $560^{\circ}C$. Single-phase large-grained CZTS film with rough surface was formed at $560^{\circ}C$. Solar cell with best efficiency of 4.7% ($V_{oc}=632mV$, $j_{sc}=15.8mA/cm^2$, FF = 47.13%) for an area of $0.44cm^2$ was obtained for the CZTS absorber grown at $560^{\circ}C$ for 6 min. The existence of second phase at lower-temperature annealing and rough surface at higher-temperature annealing caused the degradation of cell performance. Also poor back contact by void formation deteriorated cell performance. The fill factor was below 0.5; it should be increased by minimizing voids at the CZTS/Mo interface. Our results suggest that CZTS absorbers can be grown by rapid thermal annealing of metallic precursors in sulfur ambient for short process times ranging in minutes.

Ti Prepared by ionized physical vapor deposition (I-PVD) and TiN prepared by metal-organic chemical vapor deposition(MOCVD) as underlayers of aluminum TiN (Al 박막의 underlayer로서의 Ionized Physical Vapor Deposition (I-PVD) Ti 또는 I-PVD Ti/Metal-Organic Chemical Vapor Deposition TiN)

  • 이원준;나사균
    • Journal of the Korean Vacuum Society
    • /
    • v.9 no.4
    • /
    • pp.394-399
    • /
    • 2000
  • The effects of the type and thickness of underlayer on the crystallographic texture and the sheet resistance of aluminum thin film were studied. Ti and Ti/TiN were examined as the underlayer of aluminum. Ti and TiN were prepared by ionized physical vapor deposition (I-PVD) metalorganic chemical vapor deposition (MOCVD), respectively. The texture and the sheet resistance of metal thin film stacks were investigated at various thicknesses of Ti or TiN, and the sheet resistance was measured after annealing at $400^{\circ}C$ in an nitrogen ambient. For I-PVD Ti underlayer, the excellent texture of aluminum <111> was obtained even at top of 5 nm of Ti. However, the sheet resistance of the metal stack was greatly increased after annealing due to the interdiffusion and reaction of Al and Ti. MOCVD TiN between Ti and Al could suppress the Al-Ti reaction without severe degradation of aluminum <111> texture. Excellent texture of aluminum was obtained for the MOCVD TiN thinner than 4 nm.

  • PDF

Performance Enhancement and Recovery Method of Open Cathode PEMFC (오픈 캐소드형 고분자전해질 연료전지의 성능향상과 회복기법)

  • Lee, Kitaek;Kim, Junbom
    • Applied Chemistry for Engineering
    • /
    • v.28 no.1
    • /
    • pp.118-124
    • /
    • 2017
  • An air cooling, open cathode type polymer electrolyte membrane fuel cell (PEMFC) has the advantages of system simplification and cost effectiveness. Open cathode PEMFC could suffer from reduced performance due to the membrane dehydration in low humidity of air. Effects of the cathode air flow rate, anode purge interval and long term storage on PEMFC performance were investigated in this work. Fan voltage is an important factor on air cooling PEMFC performance because the cathode air flow rate and stack temperature were controlled by fan voltage. The dead ended anode (DEA) method was applied to increase hydrogen usage. Periodical purge was used to discharge accumulated water and gas. The influence of long term non-operating condition on PEMFC performance degradation due to the membrane dehydration was also studied and the quick recovery method was developed.

Study on the Short Resistance and Shorting of Membrane of PEMFC (PEMFC 고분자 막의 Short 저항 및 Shorting에 관한 연구)

  • Oh, Sohyeong;Gwon, Jonghyeok;Lim, Daehyeon;Park, Kwonpil
    • Korean Chemical Engineering Research
    • /
    • v.59 no.1
    • /
    • pp.6-10
    • /
    • 2021
  • The shorting resistance (SR) of the PEMFC(Proton Exchange Membrane Fuel Cell) polymer membrane is an important indicator of the durability of the membrane. When SR decreases, shorting current (SC) increases, reducing durability and performance. When SR becomes less than about 0.1 kΩ·㎠, shorting occurs, the temperature rises rapidly, and MEA(Membrane Electrode Assembly) is burned to end stack operation. In order to prevent shorting, we need to control the SR, so the conditions affecting the SR were studied. There were differences in the SR measurement methods, and the SR measurement method, which improved the DOE(Department of Energy) and NEDO(New Energy and Industrial Technology Development Organization) method, was presented. It was confirmed that the SR decreases as the relative humidity, temperature and cell compression pressure increase. In the final stage of the accelerated durability evaluation process of the polymer membrane, SR rapidly decreased to less than 0.1 kΩ·㎠, and the hydrogen permeability became higher than 15 mA/㎠. After dismantling the MEA, SEM(Scanning Electron Microscope) analysis showed that a lot of platinum was distributed inside the membrane.

Iron Ion Contamination and Acid Washing Effect of Polymer Membrane and Electrode in Polymer Electrolyte Fuel Cell (고분자전해질 연료전지에서 고분자 막과 전극의 철 이온 오염 및 산 세척 효과)

  • Yoo, Donggeun;Park, Minjeong;Oh, Sohyeong;Park, Kwon-Pil
    • Korean Chemical Engineering Research
    • /
    • v.60 no.1
    • /
    • pp.20-24
    • /
    • 2022
  • In the process of long-term use of PEMFC (Proton Exchange Membrane Fuel Cells), chemical degradation of membrane electrode assembly (MEA) occurs due to corrosion of stack elements and contamination of supply gas. In this study, we investigated whether chemically degraded MEA can be recovered by acid washing. The performance was measured and compared in a PEMFC cell after contamination with iron ions and washing with an aqueous sulfuric acid solution. The performance was reduced by about 25% by 0.5 ppm iron ion contamination, and 97.1% performance recovery was possible by washing of 0.15 M sulfuric acid. The membrane resistance was increased due to iron ion contamination of the polymer membrane, and the ionic conductivity was restored by washing the iron ions from the membrane while minimizing the loss of the electrode catalyst by washing with a low-concentration sulfuric acid aqueous solution. The possibility of solving the decrease in durability caused by chemical contamination of PEMFC MEA by the acid washing was confirmed.

A Rational Design of Coin-type Lithium-metal Full Cell for Academic Research (차세대 리튬 금속 전지 연구 및 개발을 위한 코인형 전지의 효율적 설계)

  • Lee, Mingyu;Lee, Donghyun;Han, Jaewoong;Jeong, Jinoh;Choi, Hyunbin;Lee, Hyuntae;Lim, Minhong;Lee, Hongkyung
    • Journal of the Korean Electrochemical Society
    • /
    • v.24 no.3
    • /
    • pp.65-75
    • /
    • 2021
  • Coin cell is a basic testing platform for battery research, discovering new materials and concepts, and contributing to fundamental research on next-generation batteries. Li metal batteries (LMBs) are promising since a high energy density (~500 Wh kg-1) is deliverable far beyond Li-ion. However, Li dendrite-triggered volume fluctuation and high surface cause severe deterioration of performance. Given that such drawbacks are strongly dependent on the cell parameters and structure, such as the amount of electrolyte, Li thickness, and internal pressure, reliable Li metal coin cell testing is challenging. For the LMB-specialized coin cell testing platform, this study suggests the optimal coin cell structure that secures performance and reproducibility of LMBs under stringent conditions, such as lean electrolyte, high mass loading of NMC cathode, and thinner Li use. By controlling the cathode/anode (C/A) area ratio closer to 1.0, the inactive space was minimized, mitigating the cell degradation. The quantification and imaging of inner cell pressure elucidated that the uniformity of the pressure is a crucial matter to improving performance reliability. The LMB coin cells exhibit better cycling retention and reproducibility under higher (0.6 MPa → 2.13 MPa) and uniform (standard deviation: 0.43 → 0.16) stack pressure through the changes in internal parts and introducing a flexible polymer (PDMS) film.