• Title/Summary/Keyword: Stability of oxidation

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Natural Antioxidants (천연 항산화 성분)

  • 하귀현
    • The Korean Journal of Food And Nutrition
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    • v.8 no.2
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    • pp.135-144
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    • 1995
  • Lipid oxidation in foods produce the peroxidation products, toxic substance and rancidity odor. In vivo, lipid peroxidation by free radicals or molecular singlet oxygen cause such as a damage of DNA, cancer and aging. Accordingly, the development of new compound Inhibit lipid oxidation in foods and in vivo is very important. Antioxidants are generally used as a protection material of oxidation for a storage and preservation of foods. In terms of stability of foods and health for human, development of high effective antioxidants In a nature is required. In this point of view, this paper presents the research trends of a kind of natural antioxidative substances and its antioxidative activity.

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Development of ILSAC GF3 Gasoline Engine Oil (ILSAC GF3 가솔린엔진유 개발)

  • 류재곤;조연근;문우식
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.143-148
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    • 2001
  • ILSAC GF 3/API SL specification will be adopted in July 2001. The background and characteristics of GF3 specification is reviewed. GF3 specification consists of five new engine tests, two new bench tests and new limits on three bench tests currently used to define ILSAC GF-2. GF 3 engine oil shows good performance compared to GF2 engine oil in fuel efficiency, protecting ability the emission catalyst and high temperature oxidation stability.

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Oxidative stability of omega-3 dietary supplements according to product characteristics

  • Kwon, Hyeon Jeong;Yun, Ho Cheol;Lee, Ji Yoon;Jeong, Eun Jung;Cho, Hyun Nho;Kim, Da Young;Park, Sung Ah;Lee, Seung Ju;Kang, Jung Mi
    • Analytical Science and Technology
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    • v.33 no.5
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    • pp.215-223
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    • 2020
  • The objectives of the present study were to assess the oxidative stability of South Korean n-3 (omega-3 fatty acid) supplements carried out from 2018 to 2019 and evaluate the influence of product characteristics on oxidative safety. A total of 76 n-3 supplements were analysed for oxidation safety by four markers, including acid value (AV), primary oxidation (peroxide value, PV), secondary oxidation (p-anisidine value, pAV) and total oxidation value (TOTOX). Among the supplements tested, 5.3 %, 55.3 %, 28.9 % and 46.1 % exceeded the international voluntary recommended levels for AV, PV, pAV and TOTOX, respectively. Purity (%) of products, remainder of expiration date (suggested shelf life), package in press through package (PTP) and products with additives had statistically significant differences oxidation assessment levels (p < 0.05). In addition, n-3 group found in Algae oil had significantly lower AV levels than the group that did not, and product with Alaska pollack oil, had significantly higher pAV levels than without group (p < 0.05). The high oxidation status of South Korean n-3 products in the present study could not be considered a public health problem right now. However, the levels of oxidation may affect a lot the efficacy and safety of using n-3 supplements. Thus, current oxidation safety limits should be reestablished by regulatory bodies to ensure the safety and efficacy of n-3 supplements, so that the standards could be applied to the products available to consumers.

Effect of Doenjang (Korean Fermented Soybean Paste) on Lipid Oxidation and Cooking Properties of Pork Patties

  • Oh, Hyun-Ju;Kim, Chang-Soon
    • Food Science and Biotechnology
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    • v.18 no.5
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    • pp.1138-1144
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    • 2009
  • This study was carried out to investigate the cooking properties and lipid oxidation stability during storage at $4{\pm}1^{\circ}C$ when the various levels (5 to 20%) of doenjang (Korean fermented soybean paste) were added to pork patties cooked by pan frying (PF) and convection oven (CO). With increasing the addition of doenjang, cooking properties of pork patties revealed the improved cooking yield, less diameter reduction, and less thickness increase. Also, the shear force, hardness, and chewiness of pork patties were reduced. The PF cooking method showed better cooking properties than CO. Lipid oxidation expressed by the thiobarbituric acid reactive substances (TBARS) values was significantly reduced by the addition of more than 5% doenjang (p<0.05). The TBARS values of cooked pork patties by PF were significantly lower than CO during the 8 days of the storage (p<0.05). The development of warmed-over flavor (WOF) in cooked pork patties was delayed as the amount of the doenjang was increased. It was suggested that the addition of doenjang and PF favorably affected the cooking properties and stability of lipid oxidation in pork patties.

Oxidation and Isomerization of Lycopene under Thermal Treatment and Light Irradiation in Food Processing

  • John Shi;Ying Wu;Mike Bryan;Maguer, Le Marc
    • Preventive Nutrition and Food Science
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    • v.7 no.2
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    • pp.179-183
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    • 2002
  • Lycopene as a natural antioxidant may provide protection against a broad range of epithelial cancers and chronic diseases. Lycopene concentrate extracted from tomatoes can be used as functional food. Lycopene would undergo degradation via isomerization and oxidation under different processing conditions, which impact its bioactivity and reduce the fuuctionality for health benefits. Heat and light induce lycopene oxidation and isomerization of all-trans form to cis form. The effects of thermal treatment and light irradiation on the stability of lycopene were determined. Results have shown that lycopene stability depends on the extent of oxidation and isomerization. Cir-isomers are less stable than trans-isomers. The level of cis-isomers increased as treatment time increased but only for a short period during the beginning of the treatment. The major effect of thermal treatment and light irradiation was a significant decrease in the total lycopene content. A true assessment of health benefits of lycopene concentrate depends on the lycopene content and the composition of all trans-isomers and cia-isomers.

Lipid Oxidation and Stability of Tocopherols and Phospholipids in Soy-added Fried Products During Storage in the Dark

  • Yoon, Young-Jin;Choe, Eun-Ok
    • Food Science and Biotechnology
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    • v.18 no.2
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    • pp.356-361
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    • 2009
  • Lipid oxidation and contents of tocopherols and phospholipids (PL) in soy-added fried products during storage in the dark were studied. Flour dough containing soy flour at 0, 10, 20, and 30% on a weight basis was fried in corn oil at $180^{\circ}C$ for 2.5 min. The fried products were stored at $60^{\circ}C$ for 11 days in the dark. Lipid oxidation of the fried products was evaluated by conjugated dienoic acid (CDA) and p-anisidine values (PAV). Tocopherols and PL were determined by high performance liquid chromatography (HPLC). CDA contents and PAV of the fried products were increased during storage, and addition of soy flour improved lipid oxidative stability of the fried products, which was partly related to increased amount of tocopherols and PL in the soy-added fried products. Tocopherols and PL were degraded during the dark storage of the fried products. Soy flour addition to the dough did not affect the rate of tocopherols degradation during storage of the fried products; however, PL degradation was higher in the soy-added fried products. Residual amounts of $\alpha$-tocopherol and phosphatidylinositol showed high correlations with the lipid oxidation of the fried products during storage in the dark.

Effect of Antioxidants on the Oxidative Stability of Biodiesel Fuels (항산화제가 바이오디젤유의 산화안정성에 미치는 영향)

  • Ryu, Kyung-Hyun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.81-86
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    • 2007
  • Biodiesel fuel that consists of saturated and unsaturated long-chain fatty acid alkyl esters is an alternative diesel fuel produced from vegetable oils or animal fats. However, air causes autoxidation of biodiesel fuel during storage, which can reduce fuel quality by adversely affecting its properties, such as the kinematic viscosity and acid value. One approach for improving the resistance of fatty derivatives to autoxidation is to mix them with antioxidants. This study investigated the effectiveness of five such antioxidants in mixtures with biodiesel fuels produced by three biodiesel manufacturers : tert-butylhydroquinone (TBHQ), butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), propyl gallate (PrG) and $\alpha$-tocopherol. Oxidation stability was determined using Rancimat equipment. The results show that TBHQ, BHA, and BHT were the most effective and $\alpha$-tocopherol was the least effective at increasing the oxidation stability of biodiesel. This study recommends that TBHQ and PrG be used for safeguarding biodiesel fuel from the effects of autoxidation during storage.

The stability of $WO_3$ thin film prepared by thermal oxidation method (열산화 방법으로 제작한 $WO_3$박막의 안정성 연구)

  • 조형호;임원택;안일신;이창효
    • Journal of the Korean Vacuum Society
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    • v.8 no.2
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    • pp.136-140
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    • 1999
  • The stability and response time of $WO_3$ thin films for EC device are critical problems being solved. Those are affected by the species of electrolyte, preparation conditions and fabricating methods of specimen. In this paper, we compared the stabilities of three kinds of tungsten oxide film in electrolyte. Each of three films was prepared by different manufacturing conditions, that is, one is a thermal oxidation film of tungsten metal deposited on pure glass substrate, another is a $WO_3$ film made on ITO glass directly, the other is a thermally oxidized film on tungsten plate. It was observed that thermally oxidized $WO_3$ films has a remarkable stability (the lifetime was above $10^6$ cycle). From these results, we found that the stability was closely related to the stoichiometric bonding between tungsten and oxygen atoms in addition to crystallinity and density of film.

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Study of Lubrication and Oxidation Stability as Mixture Ratio of FAMEs in Lubricating Base Oil (윤활기유 내 지방산메틸에스테르 혼합비율에 따른 윤활특성 및 산화안정성 연구)

  • Kim, Shin;Yim, Eui-Soon;Jung, Choong-Sub;Na, Byung-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.715-725
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    • 2013
  • FAMEs produced from vegetable oil via transesterification reaction were known as alternative fuels. Lubrication and Wear properties of FAMEs were investigated to confirm the alternative possibility as lubricating base oil. In this study, lubrication properties and physical characteristics of mixture oils were examined using blended FAMEs(soybean, palm, waste oils) in two kinds of lubricating base oils. The oxidation stability of mixed samples were analyzed using ASTM D 2272 method and investigated for oxidation states of mixture oils after the shell four ball test. The results showed that the increase of FAMEs contents improved lubrication due to the intrinsic characteristics, however, increased the contents of oxidation which deteriorate the lubrication, and we found optimum mixture ratio as results of each base biodiesel (FAME).

Effect of Amine-Based Antioxidants as Stabilizers for Biodiesel (바이오디젤용 산화방지제인 아민안정제들의 효과)

  • Park, Soo-Youl;Kim, Hun-Soo;Kim, Seung-Hoi
    • Tribology and Lubricants
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    • v.31 no.6
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    • pp.258-263
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    • 2015
  • Biodiesel is an environmentally-friendly fuel with low smoke emission because it contains about 10% oxygen. Biodiesel fuel prepared by transesterification of vegetable oil or animal fats is susceptible to auto-oxidation. The rate of auto-oxidation depends on the number of methylene double bonds contained within the fatty acid methyl or ethyl ester groups. Biodiesel may be easily oxidized under several conditions, i.e., upon exposure to sunlight, temperature, oxygen environment. Maintenance of the fuel quality of biodiesel requires the development of technologies to increase the resistance of biodiesel to oxidation. Treatment with antioxidants is a promising approach for extending the shelf-life or storage time of biodiesel. The chemical properties of various amine-based antioxidants were evaluated after synthesis of the antioxidants by condensation of phenylenediamine with alkylamines at room temperature. In general, the oxidative stability can be assessed based on various experimental parameters. Such parameters may include temperature, pressure, and the flow rate of air through the samples. The Rancimat method (EN14112) was selected because it is a rapid technique that requires very little sample and provides good precision for oxidative degradation analysis. Specifically, the EN 14112 technique provides enhanced efficiency for oxidative stability evaluation when a larger ester head group is utilized. Therefore, this technique was employed for evaluation of the oxidation stability of biodiesel by the Rancimat method (EN14112).