• Title/Summary/Keyword: Sr and Fe

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Formation Mechanism of Sr-Ferrite by Molten Salt Method (용융염법에 의한 Sr-ferrite의 생성기구)

  • 박준홍;신효순;이병교
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1181-1187
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    • 1994
  • Sr-ferrite powders were synthesized by molten salt method. The process of powder formation was investigated by controlling the size and shape (sphere and acicular) of starting materials. The morphology of resulting ferrite was plate-like regardless of the shape of starting materials, Fe2O3 powders. As a result, the formation of Sr-ferrite in the molten salt was proceeded by solution-precipitation.

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Electrical Transport Properties of $La_{0.7}Sr_{0.3}FeO_{3}$ ($La_{0.7}Sr_{0.3}FeO_{3}$ 세라믹스의 전기전도 특성)

  • 정우환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.376-382
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    • 2001
  • Magnetic and transport properties in the ceramic specimen of L $a_{0.7}$S $r_{0.3}$Fe $O_3$ with orthohombic structure has been investigated. Weak ferromagnetism has been observed in a ceramic sample of L $a_{0.7}$S $r_{0.3}$Fe $O_3$. Large dielectric relaxation of Debye type is observed in paramagnetic states within the temperature range of 130K~200K. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dispersion is related to holes hopping between F $e^{3+}$ and F $e^{4+}$ ions. The temperature dependencies of thermoelectric power and Dc conductivity suggest that the charge carrier responsible for the conduction are strongly localized. These experimental results have been interpreted in terms of a hopping process involving small polaron.n.laron.n.

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SPIN POLARIZED PHOTOEMISSION AND MAGNETIC CIRCULAY DICHROISM STUDY OF FeAl THIN FILMS

  • Kim, K.W.;Kudryavtsev, Y.V.;Chang, G.S.;Whang, C.N.;Lee, Y.P.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.53-58
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    • 1997
  • It is well known that the equiatomic FeAl alloy crystallizes in a paramagnetic CsCl structure and is very stable in a wide temperature range owing to a significant charge transfer from Al to Fe. A presence of structural defects normally enhances the magnetic and magneto-optical properties of this alloy. In this study spin-resolved photoemission and magnetic circular dichroism (MCD) were carried out on both ordered and disordered $Fe_{0.52}Al_{0.48}$ alloy films. The disordered state in the alloy films was obtained by a vapor quenching deposition on cooled substrates. It is shown that the order-disorder transition in the Fe0.52Al0.48 alloy films leads to a significant change in the spin polarization. Form the MCD results the orbital and spin magnetic moments of the constituent atoms are obtained. According to the sum rule the spin and orbital magnetic moments of Fe in the disordered FeAl film are $\mu\frac{SR}{spin}=0.8\mu_B$ and $\mu\frac{SR}{orb}=0.14\mu_B$ respectively. The spin magnetic moment is also evaluated to be $\mu\frac{BR}{spin}=0.77\mu_B$ by the branching ration method employing a photon polarization of 90%.

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Sintering Effects on Fe/Mo Ordering and Magnetoresistance in Double Perovskite Sr2FeMoO6

  • Kim, J;Park, B.J;Lee, B.W
    • Journal of Magnetics
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    • v.9 no.1
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    • pp.9-12
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    • 2004
  • We have investigated sintering effects on Fe/Mo ordering and magnetoresistance (MR) in double perovskite-reflection lines due to $Sr_2FeMoO_6$ (SFMO). Polycrystalline samples have been prepared by the conventional solid-state reaction by sintering in a stream of 5% $H_2/Ar$ gas. All samples are single phase and exhibit a series of superstructurecation ordering at Fe and Mo sites. As sintering temperature increases from 900 to $1300^{\circ}C$, the degree of Fe/Mo ordering increases from 82 to 92%, magnetization (15 K, 7 kOe) increases from 1.6 to 2.7 ${\mu}_B/f.u.,$ and Curie temperature increases at a rate of 4.3 K/% with the increase of Fe/Mo ordering ratio. The magnitude of MR measured at 5 K is 19% for sample prepared at $1000^{\circ}C$ with magnetic fields of 7 kOe. The observed MR is proportional to the square of magnetization indicating that the MR feature in SFMO is explained by the spin-polarized tunneling at grain boundaries.

Precipitation of cations by alginate, polyguluronate and polymannuronate

  • Jeong, Dae-Yeong;Seo, Hyeong-Pil;Lee, Dong-Su;Byeon, Jae-Hyeong;Lee, Jin-U
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.495-499
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    • 2000
  • The relative affinity of seaweed alginate, polyguluronate and polymannuronate for cations was investigated. The cations used in this study were $Ca^{2+}$, $Cd^{2+}$, $Co^{2+}$, $Cu^{2+}$, $Fe^{3+}$, $Hg^{2+}$, $Mg^{2+}$, $Mn^{2+}$, $Pb^{2+}$, $Rb^{1+}$, $Sr^{2+}$ and $Zn^{2+}$. The ability of cations to precipitated polymers was determined as the relative affinity of seaweed alginate, polyguluronate and polymannuronate for cations. The relative affinity of polymers for cations in order are as follow: Seaweed alginate: $Fe^{3+}$,$Cu^{2+}$,$Cd^{2+}>Pb^{2+}>Co^{2+}$,$Zn^{2+}>Ca^{2+}>Sr^{2+}$,$Rb^{1+}>Mn^{2+}>Mg^{2+}$,$Hg^{2+}$ Ployguluronate:$Fe^{3+}$,$Cu^{2+}$,$Cd^{2+}>Ca^{2+}$,$Co^{2+}$,$Pb^{2+}>Sr^{2+}$,$Rb^{1+}$,$Zn^{2+}>Hg^{2+}$,$Mn^{2+}>Mg^{2+}$ Polymannuronate:$Fe^{3+}$,$Cd^{2+}$,$Cu^{2+}>Ca^{2+}$,$Pb^{2+}>Zn^{2+}$,$Rb^{1+}$$Sr^{2+}$,$Hg^{2+}>Co^{2+}>Mn^{2+}>Mg^{2+}$

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Structural and Electrical Properties of (La0.7Sr0.3)(Mn1-xFex)O3 Thin Films Prepared by Sol-Gel Method for Thermistor Devices (서미스터 소자로의 응용을 위한 솔-젤법으로 제작한 (La0.7Sr0.3)(Mn1-xFex)O3 박막의 구조적, 전기적 특성)

  • Ji-Su Yuk;Sam-Haeng Yi;Myung-Gyu Lee; Joo-Seok Park;Young-Gon Kim;Sung-Gap Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.2
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    • pp.164-168
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    • 2024
  • (La0.7Sr0.3)(Mn1-xFex)O3 (LSMFO) (x = 0.03, 0.06, 0.09, 0.12) precursor solution are prepared by sol-gel method. LSMFO thin films are fabricated by the spin-coating method on Pt/Ti/SiO2/Si substrate, and the sintering temperature and time are 800℃ and 1 hr, respectively. The average thickness of the 6-times coated LSMFO films is about 181 to 190 nm and average grain size is about 18 to 20 nm. As the amount of Fe added in the LSMFO thin film increased, the resistivity decreased, and the TCR and B25/65-value increased. Electrical resistivity, TCR and B25/65-value of the (La0.7Sr0.3)(Mn0.88Fe0.12)O3 thin film are 0.0136 mΩ-cm, 0.358%/℃, and 328 K at room temperature, respectively. The resistivity properties of LSMFO thin films matched well with Mott's VRH model.