• Journal of the Korean Wood Science and Technology
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• 제23권3호
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• pp.33-39
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• 1995

To accelerate the cure of phenolic resin adhesives for plywood, the complexation with melamine resin and the addition of cure-accelerating agents were discussed. The hot-pressing temperature and time of phenol resin could be decreased by complexation with melamine resin. but the wet glue-joints strength of phenol melamine resin was lower than that of ordinary phenol resin in case of plywood using spruce veneer at core layer. Among the tested cure-accelerating agents. the sodium carbonate showed the greatest effect on shortening gelation time of phenolic resin. In addition, in the manufacturing scale test, the hot-pressing time of phenol resin with the addition of 5 parts sodium carbonate could be shortened about 20% compared with ordinary phenol resin which had same glue-joints properties.

• Journal of the Korean Wood Science and Technology
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• 제18권4호
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• pp.79-85
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• 1990

Many kinds of acetosolv lignin including ricestraw and spruce lignin were pyrolyzed. and liquefied in the autoclave reactor using 50% tetralin and m-cresol solution respectively as soluble solvent and Co-Mo as catalyst. In order to promote deoxyhydrogenolysis reaction $H_2$ gas was supplied into the reactor. The ratio between lignin and the soluble solvent are lg and 10cc. The reaction conditions are $200^{\circ}-700^{\circ}C$ of reaction temperature, 10-50 atms of reaction pressure and 100-500rpm of the reactor stirrer. By the deoxyhydrogenolysis liquefaction reaction, the main chemical structures of lignin which are aryl-alkyl-${\beta}$-0-4 ether, phenylcoumaran and biphenyl etc. are easily destroyed into liqufied aromatic compounds and aliphatic compunds linked with aromatic compounds. The percent yield of monomeric phenols on the weight bvase of lignin reacted reached to 12-14% by the chemical analytic GC-MS etc.

• 한국화재소방학회논문지
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• 제33권1호
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• pp.50-59
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• 2019

과환기 화재조건에서 화원과 측벽의 거리에 따른 화재특성에 관한 실험 및 수치해석 연구가 수행되었다. 1/3 축소된 ISO 9705 화재실이 제작되었으며, Spruce wood crib이 연료로 사용되었다. 구획 내부의 현상 이해를 위하여 Fire Dynamics Simulator (FDS)를 활용한 시뮬레이션이 수행되었다. 개방된 공간 화재에 비해 구획실 화재는 벽면의 열 피드백 효과로 인하여 질량 감소율과 열발생률이 증가됨이 확인되었다. 측벽과 화원의 거리가 감소됨에 따라 화염으로의 공기 유입 제한에도 불구하고 주요 화재특성인 최대 질량 감소율, 열발생률, 화재 성장률, 온도 및 열유속이 증가되었다. 특히 측벽과 화원이 접촉되었을 때 이들 물리량의 가장 큰 변화가 확인되었다. 추가로 화원과 측벽의 거리에 따른 구획 내부의 유동구조의 변화로 인하여 온도의 수직분포에 상당한 변화가 발생됨이 확인되었다.

• Journal of the Korean Wood Science and Technology
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• 제24권1호
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• pp.75-80
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• 1996

The purpose of this study is to clarify the mechanism of moisture transfer depend on the thickness of the spruce(Picea sitchensis Carr.). Therefore, as the basic research of moisture transmission, the amount of moisture transmission and the moisture distribution in specimens and temperature of it's surfaces in vapor transmission process were investigated. The experiment was conducted in a steady state. and the moisture distribution was measured by knife cutting and weighing the specimens. The following conclusions were obtained ; 1. It can be found that distribution of moisture in the specimen can be approximated by two different straight lines intersecting at nine or ten percent moisture content. The amount of moisture movement defends on the gradient of moisture in the wood. 2. It is investigated that the wood surface moisture contents(MCs) are less for thinner specimens than for thick ones on the absorption side. On the other hand, the wood surface MCs are greater for thinner specimens than for thick ones on the desorption side. The main factor that affects the EMC of wood would be temperature when the relative humidity of atmosphere is constant. The specimen generate heat with the absorption and desorption process. In addition, the velocities of moisture transmission varied with the thicknesses of specimens. If the temperature of wood becomes greater, its MC decreases. Then the difference between surface MC and EMC of adsorption and desorption side becomes greater for thinner specimens. Therefore it is considered that the coefficients of moisture transfer decreases with the increases of the specimens' thicknesses.

• Journal of the Korean Wood Science and Technology
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• 제49권2호
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• pp.181-190
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• 2021

Screw-type fasteners are widely used to make connections between wood members or between wood and steel connectors because they can tolerate the applied loads by withdrawal or shearing. In this study, we evaluated the withdrawal resistances of the screw-type fasteners and analyzed the effects of the lead-hole size, relative grain direction (tangential, radial, and cross-sections) of the wood member, screw diameter, screw type, and species. Two wood species, including domestic larch and imported spruce, and three screw-type fasteners, including domestic lag screws (diameters of 9.46, 7.79, and 6.27 mm), domestic tapping screw (diameter, 6.3 mm), and imported Sherpa screw (diameter, 8.0 mm) were used. To assess the effect of lead-hole size, the lead holes with diameters corresponding to 68.7%, 70.8%, and 74.0% of the shank diameter of the lag screw were predrilled. The lead hole corresponding to 74% of the shank diameter was selected for this study because the smaller lead holes required higher rotational force for installation, which may cause damage in the screw neck, although there was no significant difference in the withdrawal resistance depending on the lead-hole sizes applied in this study. The lag screws installed on the tangential and radial surfaces showed similar withdrawal resistances to each other, which were greater than those installed on the cross-sectional surface. As the lag screw diameter increased from 6.27 mm to 9.46 mm, the withdrawal resistance also increased proportionally. The withdrawal resistance of the tapping screw having a diameter of 6.3 mm was almost 1.6 times higher than that of the lag screw having a similar diameter of 6.27 mm, while that of Sherpa screw having a diameter of 8.0 mm was around 1.4 times higher than that of the lag screw having a similar diameter of 7.79 mm.

• Interaction and multiscale mechanics
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• 제5권3호
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• pp.229-265
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• 2012

Hygroexpansion of wood is a known and undesired characteristic in civil engineering. When wood is exposed to changing environmental humidity, it adsorbs or desorbs moisture and warps. The resulting distortions or - at restrained conditions - cracks are a major concern in timber engineering. We herein present a multiscale model for prediction of the macroscopic hygroexpansion behavior of individual pieces of softwood from their microstructure, demonstrated for spruce. By applying poromicromechanics, we establish a link between the swelling pressure, driving the hygroexpansion of wood at the nanoscale, and the resulting macroscopic dimensional changes. The model comprises six homogenization steps, which are performed by means of continuum micromechanics, the unit cell method and laminate theory, all formulated in a poromechanical framework. Model predictions for elastic properties of wood as functions of the moisture content closely approach corresponding experimental data. As for the hygroexpansion behavior, the swelling pressure has to be back-calculated from macroscopic hygroexpansion data. The good reproduction of the anisotropy of wood hygroexpansion, based on only a single scalar calibration parameter, underlines the suitability of the model. The multiscale model constitutes a valuable tool for studying the effect of microstructural features on the macroscopic behavior and for assessing the hygroexpansion behavior at smaller length scales, which are inaccessible to experiments. The model predictions deliver input parameters for the analysis of timber at the structural scale, therewith enabling to optimize the use of timber and to prevent moisture-induced damage or failure.

• Journal of the Korean Wood Science and Technology
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• 제37권1호
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• pp.1-11
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• 2009

외장용 기둥재는 년중 사용환경에서 액상수와 직접 접촉할 수가 있으나, 이에 대한 연구는 그다지 많지 않다. 목재의 섬유방향에서 결합수와 자유수 확산계수를 포함한 수분확산계수를 측정하기 위해 상온에서 흡수실험을 실시하였다. 흡수성은 느릅나무, 까치박달나무, 헴록, 가문비나무, 라디에타 소나무, 고로쇠나무 순으로 크게 나타났다. Boltzmann 변환법으로 구한 확산계수는 저함수율에서 섬유포화점 부근까지 감소하다가 최대함수율 부근에서 급격히 증가하는 경향을 나타내었다. 함수율 변화에 따른 확산계수는 $10^{-10}{\sim}10^{-7}m^2/s$ 정도의 값을 나타내었다.

• 한국화재소방학회논문지
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• 제31권2호
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• pp.37-43
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• 2017

이 연구에서는 4종의 삼나무, 스프러스, 나왕, 레드파인 시험편을 콘칼로리미터(Cone calorimeter, ISO 5660-1, 2)와 연기밀도시험기(ASTM E 662)를 이용하여 연소성을 시험하였다. 그 결과, 삼나무가 착화시간이 가장 빨랐고 평균열방출율($HRR_{mean}$)이 $58.52kW/m^2$으로 가장 낮게 나타났다. 그리고 레드파인의 평균열방출율($HRR_{mean}$)이 $71.75kW/m^2$으로 가장 높게 나타났다. CO 발생량에서는 나왕과 삼나무가 가장 많이 발생하였고, 반대로 $CO_2$ 발생량에서는 레드파인과 스프러스가 가장 많이 발생하였다. 동적방법에서의 총연기방출율은 레드파인이 연기가 가장 많이 발생하였고, 스프러스가 가장 적게 발생하였다. 정적방법에서의 연기밀도는 레드파인이 훈소(Non-flaming) 방식과 불꽃(Flaming) 방식에서 가장 높았다. 나왕은 훈소(Non-flaming) 방식에서 2번째로 연기가 많이 발생한 데 반하여 불꽃(Flaming) 방식에서는 가장 적게 발생한 것을 알 수 있었다. 열방출율 측면에서 화재위험성은 4가지 시험편 중 레드파인이 가장 높았다. 연기발생 관점으로 보아도 동적인 방식과 정적인 방식 모두 레드파인이 화재 위험성이 가장 높은 재료였다.

• Journal of the Korean Wood Science and Technology
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• 제42권3호
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• pp.290-300
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• 2014

이 연구에서는 가문비나무를 이용하여 직교형적층재를 제작하였고, 섬유직각방향라미나의 연륜경사각이 직교형적층재의 정적 휨 강도성능에 미치는 영향을 조사하였다. 3층 모두가 섬유직각방향라미나로 구성된 평행형적층재($P_{\bot}$ 타입)의 휨 강도성능은 연륜경사각 $90^{\circ}$ > $0^{\circ}$ > $45^{\circ}$의 순이었고, 연륜경사각 $45^{\circ}$에서 휨 탄성계수는 0.0989 GPa, 휨 강도는 3.25 MPa로 가장 적은 값을 나타내었다. $P_{\bot}$ 타입의 중층에 섬유방향라미나를 배열하는 것에 의해 휨 강도성능은 현저히 향상되었다. 표층이 섬유직각방향라미나로 구성된 직교형적층재($C_{\bot}$ 타입)의 경우, 휨 강도성능은 연륜경사각 $90^{\circ}$ > $0^{\circ}$ > $45^{\circ}$의 순이었으나, 연륜경사각에 의한 차이는 평행형적층재에 비해 감소하였다. 중층에 섬유직각방향라미나를 배열한 직교형적층재($C_{\parallel}$ 타입)의 경우, 휨 강도성능은 $P_{\bot}$ 타입 및 $C_{\bot}$ 타입과 다르게 $45^{\circ}$ > $90^{\circ}$ > $0^{\circ}$의 순으로 연륜경사각 $45^{\circ}$에서 휨 탄성계수는 12.0 GPa, 휨 강도는 55.8 MPa로 가장 높은 값을 나타내는 것이 확인되었다.

• Journal of the Korean Wood Science and Technology
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• 제38권6호
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• pp.561-567
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• 2010

본 연구는 diethyl oxalate 처리로부터 얻어진 가문비나무 가수분해산물을 이용하여 에탄올 생산에 적합한 조건을 탐색하였다. 가문비나무 가수분해산물의 단당류 분석 결과 아라비노오스를 제외한 발효가능한 당 농도 는 29.04 g/${\ell}$이었으며 가수분해산물에 포함된 올리고머로부터 분해된 단당은 대부분 만노오스(39.26 g/${\ell}$)와 갈락토오스(12.83 g/${\ell}$)가 차지하였다. 발효저해물질인 5-HMF, furfural의 농도는 각각 0.09 g/${\ell}$, 0.04 g/${\ell}$, acetic acid는 1.4 g/${\ell}$, total phenolic compounds는 2.83 g/${\ell}$로 나타났다. 가수분해산물을 이용한 에탄올 생산 최적 pH는 6.0으로 발효 48시간 후 11.7 g/${\ell}$의 에탄올을 생산하였다. 시간당 에탄올 생산량은 pH 5.0와 5.5에서 0.15 (g/(${\ell}^*h$))로 나타났으며 pH 6.0에서는 0.24 (g/(${\ell}^*h$))로 나타났다. 시간당 생성된 에탄올 생산량은 에탄올 발효 초기 pH에 따라 차이를 나타냈다. 가수분해산물에 xylanase 20 IU를 첨가하여 올리고머를 분해한 후 발효를 실시한 결과 48시간 후 14.3 g/${\ell}$의 에탄올을 생산하였다. 이것은 xylanase를 첨가하지 않았을 때 보다 에탄올 생산량이 22.2% 증가되었음을 나타내고 있다.