• Title/Summary/Keyword: Spray Structure

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Synthesis of porous-structured (Ni,Co)Se2-CNT microsphere and its electrochemical properties as anode for sodium-ion batteries (다공성 구조를 갖는 (Ni,Co)Se2-CNT microsphere의 합성과 소듐 이차전지 음극활물질로서의 전기화학적 특성 연구)

  • Yeong Beom Kim;Gi Dae Park
    • Clean Technology
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    • v.29 no.3
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    • pp.178-184
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    • 2023
  • Transition metal chalcogenides have garnered significant attention as anode materials for sodium-ion batteries due to their high theoretical capacity. Nevertheless, their practical application is impeded by their limited lifespan resulting from substantial volume expansion during cycling and their low electrical conductivity. To tackle these issues, this study devised a solution by synthesizing a nanostructured anode material composed of porous CNT (carbon nanotube) spheres and (Ni,Co)Se2 nanocrystals. By employing spray pyrolysis and subsequent heat treatments, a porous-structured (Ni,Co)Se2-CNT composite microsphere was successfully synthesized, and its electrochemical properties as an anode for sodium-ion batteries were evaluated. The synthesized (Ni,Co)Se2-CNT microsphere possesses a porous structure due to the nanovoids that formed as a result of the decomposition of the polystyrene (PS) nanobeads during spray pyrolysis. This porous structure can effectively accommodate the volume expansion that occurs during repeated cycling, while the CNT scaffold enhances electronic conductivity. Consequently, the (Ni,Co)Se2-CNT anode exhibited an initial discharge capacity of 698 mA h g-1 and maintained a high discharge capacity of 400 mA h g-1 after 100 cycles at a current density of 0.2 A g-1.

A study on drainage system of the room-and-pillar underground structure considering groundwater conditions (지하수 유출수 조건을 고려한 주방식 지하구조의 배수시스템 연구)

  • Lee, Chulho;Hyun, Younghwan;Hwang, Jedon;Chang, Soo-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.6
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    • pp.675-683
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    • 2015
  • The room-and-pillar construction method for underground space is adopted from the room-and-pillar mining method which is one of the most popular underground mining method in the world. Drainage system in the room-and-pillar underground construction method can be similar with the concept of single shell in tunnel because additional reinforcement except the TSL (thin spray-on liner) is not applied in the room-and-pillar construction method. That is, to decrease groundwater level and maintain safety in tunnel, the drainage pin hole inside lining (shotcrete) can be used. However, if total amount of outflow in the underground structure is relatively small or groundwater is not detected, such drainage system will not be useful and cause additional construction cost. In this study, outflow of conventional tunnels in South Korea was investigated and the criteria to determine whether the drainage pin hole is effective was suggested. And the guided drainage system was suggested when drainage pin hole was not applied in the room-and-pillar construction method.

Improvement of Corrosion Resistance by Mg Films Deposited on Hot Dip Aluminized Steel using a Sputtering Method (용융알루미늄 도금 강판 상에 스퍼터링법으로 형성된 마그네슘 코팅막에 의한 내식성 향상)

  • Park, ae-Hyeok;Kim, Soon-Ho;Jeong, Jae-In;Yang, Ji-Hoon;Lee, Kyung-Hwang;Lee, Myeong-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.51 no.4
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    • pp.224-230
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    • 2018
  • In this study, Mg films were prepared on hot dip aluminized steel (HDA) by using a sputtering method as a high corrosion resistance coating. The corrosion resistance of the Mg films was improved by controlling the morphology and the crystal structure of films by adjusting the Ar gas pressure during the coating process. Anodic polarization measurement results confirm that the corrosion resistance of the Mg films was affected by surface morphology and crystal structure. The corrosion resistance of the Mg coated HDA specimen increased with decreasing crystal size of the Mg coating and it was also improved by forming a film with denser morphology. The crystal structure oriented at Mg(101) plane showed the best corrosion resistance among crystal planes of the Mg metals, which is attributed to its relatively low surface energy. Neutral salt spray test confirmed that corrosion resistance of HDA can be greatly improved by Mg coating, which is superior to that of HDG (hot dip galvanized steel). The reason for the improvement of the corrosion resistance of Mg films on hot dip aluminized steel was due to the barrier effect by the Mg corrosion products formed by the corrosion of the Mg coating layer.

A Study on the Surface and Manufacturing Method of Nanostructure for Amplification of Plasmonic Phenomena of Nanoparticles (나노 입자의 플라즈모닉 현상 증폭을 위한 나노구조 표면과 제작방법에 관한 연구)

  • Yi, Jae Won;Jeong, Myungyung
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.55-59
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    • 2022
  • In this paper, we compared the electric field and absorptance of nano particles in nanostructures by amplifying the electric field around the nanoparticles through plasmon resonance and comparing the structure that can increase the absorptance with the nanostructure by using the Finite Different Time Domain (FDTD) simulation. In addition, the width of the nanostructure was adjusted to 240 nm ~ 300 nm, and the light absorptance rate was higher as the gap between the particles was short. In addition, a study was conducted on the formation of nanoparticles and nanostructures on the surface through UV imprint. In order to form particles in the structure, the nano particles were first arranged in the mold used for the fabrication of the structure using spray coating, and then fabricated through UV imprinting. The nanostructure and particles were formed together by scanning electron microscopy.

Bacterial Community Structure and Diversity of the Zoysia japonica Soil Treated with Liquid Fertilizer Containing Amino Acids (아미노산 액비를 처리한 들잔디 토양 미생물 군집구조 및 다양성)

  • Kim Dong-Il;Kim Dong-Hun
    • Korean Journal of Microbiology
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    • v.42 no.2
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    • pp.103-110
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    • 2006
  • T-RFLP analysis and clone sequencing analysis based on bacterial 16S rDNA were conducted to assess bacterial community structure and diversity in Zoysia japonica soil treated with liquid fertilizer containing amino acids(LFcAA) after spray with herbicide. The results of T-RFLP (terminal restriction fragment length poly-morphism) analysis using restriction enzyme Hae III showed that the T-RFs of various size appeared evenly in the 32 clones of KD3 and 38 clones of KD4 respectively that had been treated with liquid fertilizer containing amino acid(LFcAA) compared to 23 clones of KD2 hat had not been treated with LFcAA. The microbial com- munity structure in KD2 appeared less diverse than those in KD3 and KD4. Analysis of partial sequences for 110 clones from KDI (control), KD2 (non-treated), KD3 (LFcAA 1X), KD4 (LFcAA 2X), respectively, revealed that most bacteria were related with uncultured bacteria in a 16S rDNA sequence similarity range of 91-99% through blast search. Otherwise, the other clones were members of proteobacteria, Acidobacteria, Act-inobacteria, Sphingobacteria and Planctomyces groups. Especially in KD4, members of Alpha Proteobacteria, Rhizobiales, Sphigomonadales, Caulobacterales, Gamma Proteobacteria, the genus Pseudomonas, Betapro-teobacteria, Nitrosomonadales and genus Nitrosospira appeared to be dominant. In addition, Acidobacteria group, Actinobacteria group, Planctomycetacia and Sphingobacteria were also shown. The microbial com-munity structure in Z. japonica soil sprayed with herbicide was affected by LFcAA.

A Numerical Study on the Combustion Characteristics in a Liquid Rocket Engine with Film Cooling Effect (막냉각 효과를 고려한 액체로켓 엔진의 연소 특성에 관한 연구)

  • Byeon,Do-Yeong;Kim,Man-Yeong;Baek,Seung-Uk
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.8
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    • pp.69-76
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    • 2003
  • For stable combustion and safety of a structure of the propulsion system, a cooling system to the liquid rocket engine should be incorporated. In this study, Eulerian-Lagrangian scheme for two phase combustion, nongray radiation and soot formation effect, and film-wall interaction have been introduced to study the effect of film cooling. After briefly introducing the governing equation, combustion characteristics with change of wall temperature has been investigated by varying such parameters as fuel mass fraction for film cooling, diameter of the fuel droplet, overall mixture fraction of oxygen to fuel. Also, radiative heat flux is compared with the conductive one at the combustor wall.

The Cooling Characteristics of a Gas Deflector Using Water Spray Cooling System in Launch Pad (물 분사 냉각시스템을 이용한 발사대 화염유도로의 냉각특성)

  • Lee, Kwang-Jin;Chung, Yong-Gahp;Cho, Nam-Kyung;Nam, Jung-Won;Jung, Il-Hyung;Ra, Seung-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.756-762
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    • 2011
  • A gas deflector cooling system plays an important role in the suppression of shock wave generated during the ignition of a launch vehicle engine. Also, this system decrease a large vibration of damaging the payload and structure of the launch vehicle. The gas deflector cooling system in the launch pad of NARO space center was constructed to directly inject water into the plume of the launch vehicle engine. The flight test result of NARO space launch vehicle showed that this method had a good performance on the viewpoint of cooling the gas deflector.

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A Numerical Study on Mixing Characteristics for Recess Length of Swirl Coaxial Injector (스월 동축형 분사기의 리세스 길이에 따른 혼합특성에 관한 수치적 연구)

  • Kim, Young-Jun;Hong, Moon-Geun;Lee, Soo-Yong;Sohn, Chae-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.74-77
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    • 2011
  • A mixing characteristics on recess length change of Gas-centered swirl coaxial injector using high-performance staged combustion rocket engine carry out study through CFD(Computational fluid dynamics). propellant phase that combined gas-liquid simulate gas-gas. In order to measure spreading angle, velocity distribution to injector exit and spray structure of propellant analyzed. Axial velocity increase by increasing recess length, but tangential velocity decrease. The result confirmed qualitative characteristics that the spreading angle decreases.

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Study for Design and Performance Characteristics of Small Bipropellant Thruster using $H_2O_2$/Kerosene (과산화수소/케로신 소형 이원추진제 추력기의 설계 및 성능특성에 관한 연구)

  • Kim, Jung-Hoon;Lee, Jae-Won;Jeon, Young-Jin;Chae, Byoung-Chan;Jeon, Jun-Su;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.41-45
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    • 2009
  • The small-sized bi-propellant thruster using a high concentrated hydrogen peroxide and kerosene as the oxidizer and fuel was designed and fabricated in this study. The water cold-flow test was performed to verify the performance characteristics of the injector. The mixing head assembly used in this model thruster was designed as a structure to combine igniter, injectors and film cooling, which are capable of regulating each mass flowrate. This maximize the experimental verification and efficiency of the design optimization. Finally, the mass flowrate and spray pattern of injector were evaluated by the hydraulic test. Therefore, the design validity of the mixing head was verified.

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Fine Particle Removal by a Vehicle Air Cleaner (차량용 에어클리너의 미세입자 제거특성)

  • Park, Byung-Hyun;Kim, Sang-Bum;Kim, Gyung-Soo;Lee, Sang-Ryul;Lee, Myong-Hwa
    • Journal of ILASS-Korea
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    • v.12 no.2
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    • pp.86-93
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    • 2007
  • There is a growing interest to develop an eco-friendly air cleaner with high performance through a remanufacturing process. Two kinds of polyurethane filter media, a coarse (Filter-A) and a fine filter media (Filer-B), are used in this study to protect a vehicle engine from airborne particles. In order to improve the collection performance of the filters (Filter-A, Filter-B), an oil coating technology on the filter surface was introduced. As a result, inertial force is a dominant collection mechanism for a dry filter media, so that collection efficiency increases with increasing filtration velocity. However, intra-structure change of an oil-coated filter media influences on the collection mechanism, which shows a non-linear collection efficiency curve in terms of filtration velocity. The result shows that the developed filter media are eco-friendly and effective to protect a vehicle engine from airborne particles especially at low filtration velocity.

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