• Title/Summary/Keyword: Spin distribution

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The Effect of Iron Content on the Atomic Structure of Alkali Silicate Glasses using Solid-state NMR Spectroscopy (비정질 알칼리 규산염 원자구조의 철 함량 효과에 관한 고체 NMR 분광학 연구)

  • Kim, Hyo-Im;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.4
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    • pp.301-312
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    • 2011
  • The study on the atomic structure of iron-bearing silicate glasses has significant geological implications for both diverse igneous processes on Earth surface and ultra-low velocity zones at the core-mantle boundary. Here, we report experimental results on the effect of iron content on the atomic structure in iron-bearing alkali silicate glasses ($Na_2O-Fe_2O_3-SiO_2$ glasses, up to 16.07 wt% $Fe_2O_3$) using $^{29}Si$ and $^{17}O$ solid-state NMR spectroscopy. $^{29}Si$ spin-lattice ($T_1$) relaxation time for the glasses decreases with increasing iron content due to an enhanced interaction between nuclear spin and unpaired electron in iron. $^{29}Si$ MAS NMR spectra for the glasses show a decrease in signal intensity and an increase in peak width with increasing iron content. However, the heterogeneous peak broa-dening in $^{29}Si$ MAS NMR spectra suggests the heterogeneous distribution of $Q^n$ species around iron in iron-bearing silicate glasses. While nonbridging oxygen ($Na-O-Si$) and bridging oxygen (Si-O-Si) peaks are partially resolved in $^{17}O$ MAS NMR spectrum for iron-free silicate glass, it is difficult to distinguish the oxygen clusters in iron-bearing silicate glass. The Lorentzian peak shape for $^{29}Si$ and $^{17}O$ MAS NMR spectra may reflect life-time broadening due to spin-electron interaction. These results demonstrate that solid-state NMR can be an effective probe of the detailed structure in iron-bearing silicate glasses.

Change of Plantar Pressure Distribution according to Stance Patterns during Tennis Forehand (테니스 포핸드의 스탠스 유형에 따른 족저압력분포의 변화)

  • Lee, Tae-Keun;Kim, Seung-Jae;Choi, Ji-Young
    • Korean Journal of Applied Biomechanics
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    • v.15 no.2
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    • pp.185-196
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    • 2005
  • Recently among several tennis techniques forehand stroke has been greatly changed in the aspect of spin, grip and stance. The most fundamental factor among the three factors is the stance which consists of open, square and closed stance and it is very important to know the patterns of plantar pressure distribution for the better understanding of forehand stroke. Therefore, the purpose of this study was to investigate the change of plantar pressure distribution according to close, square and open stance patterns during forehand stroke in tennis. Three high school tennis players were recruited for the study and required to perform forehand stroke five consecutive trials in the condition of open, square and close stance. The forehand strokes were filmed with two digital video cameras and measured with pedar system for plantar pressure. The plantar regions under the foot were divided into 3 regions, which were forefoot, midfoot, and rear foot.. In conclusion, the first hypothesis, "The plantar pressure of close stance during forehand stroke would be distributed more largely to the left foot.", was rejected and the result showed that The plantar pressure of close stance during forehand stroke was distributed transferring from right foot to left foot similar to square stance. The second hypothesis, "The plantar pressure of square stance during forehand stroke would be distributed transferring from right foot to left foot." was accepted. The third hypothesis, "The plantar pressure of open stance during forehand stroke would be distributed more largely to the right foot.", was accepted.

Use of Magnetic Resonance Neurography for Evaluating the Distribution and Patterns of Chronic Inflammatory Demyelinating Polyneuropathy

  • Xiaoyun Su;Xiangquan Kong;Zuneng Lu;Min Zhou;Jing Wang;Xiaoming Liu;Xiangchuang Kong;Huiting Zhang;Chuansheng Zheng
    • Korean Journal of Radiology
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    • v.21 no.4
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    • pp.483-493
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    • 2020
  • Objective: To evaluate the distribution and characteristics of peripheral nerve abnormalities in chronic inflammatory demyelinating polyneuropathy (CIDP) using magnetic resonance neurography (MRN) and to examine the diagnostic efficiency. Materials and Methods: Thirty-one CIDP patients and 21 controls underwent MR scans. Three-dimensional sampling perfections with application-optimized contrasts using different flip-angle evolutions and T1-/T2- weighted turbo spin-echo sequences were performed for neurography of the brachial and lumbosacral (LS) plexus and cauda equina, respectively. Clinical data and scores of the inflammatory Rasch-built overall disability scale (I-RODS) in CIDP were obtained. Results: The bilateral extracranial vagus (n = 11), trigeminal (n = 12), and intercostal nerves (n = 10) were hypertrophic. Plexus hypertrophies were observed in the brachial plexus of 19 patients (61.3%) and in the LS plexus of 25 patients (80.6%). Patterns of hypertrophy included uniform hypertrophy (17 [54.8%] brachial plexuses and 21 [67.7%] LS plexuses), and multifocal fusiform hypertrophy (2 [6.5%] brachial plexuses and 4 [12.9%] LS plexuses) was present. Enlarged and/or contrast-enhanced cauda equina was found in 3 (9.7%) and 13 (41.9%) patients, respectively. Diameters of the brachial and LS nerve roots were significantly larger in CIDP than in controls (p < 0.001). The largest AUC was obtained for the L5 nerve. There were no significant differences in the course duration, I-RODS score, or diameter between patients with and without hypertrophy. Conclusion: MRN is useful for the assessment of distribution and characteristics of the peripheral nerves in CIDP. Compared to other regions, LS plexus neurography is more sensitive for CIDP.

Angular Dependence of Ferromagnetic Resonance Linewidth in Exchange Coupled CoFe/MnIr Bilayers (교환 결합력을 갖는 CoFe/MnIr 박막에서 강자성 공명 선폭의 각도 의존성 연구)

  • Yoon, Seok Soo;Kim, Dong Young
    • Journal of the Korean Magnetics Society
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    • v.26 no.2
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    • pp.50-54
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    • 2016
  • We analyzed the angular dependence of ferromagnetic resonance linewidth in exchange coupled CoFe/MnIr bilayers. The maximum and minimum linewidth was observed in the easy and hard direction of unidirectional anisotropy by exchange coupling, respectively, and it was well agreed with the angular dependence of exchange bias field. The maximum linewidth was due to the twist of CoFe magnetization near CoFe/MnIr interface from direction of pinned MnIr spin to direction of applied magnetic field. While, minimum linewidth more higher than that of CoFe was related to rotatable anisotropy field, and explained by easy axis distribution of MnIr grains.

Photometric observations of the Baptistina asteroid family

  • Kim, Myung-Jin;Choi, Young-Jun;Moon, Hong-Kyu;Erece, Orhan;Ries, Judit Gyorgyey;Kaynar, Suleyman;Kaplan, Murat;Eker, Zeki
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.84.1-84.1
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    • 2015
  • The Baptistina family is one of the typical young asteroid families with an age estimated to be about 140-320 Myrs old (Masiero et al. 2012); considered to have not enough time to experience a significant collisional and dynamical evolution since it was formed. Therefore, it may offer a unique insight into spin rate distribution of relatively fresh fragments and physical mechanism of a family break-up event. Observations of the Baptistina family asteroids were conducted during 111 nights from 2013 Oct. to 2015 Feb., using 0.5 m- to 2 m- class telescopes at 6 observatories in the northern hemisphere. We used CCD cameras on the Sobaeksan Optical Astronomy Observatory (SOAO) 0.6 m telescope on Mt. Sobaek, Korea, the Lemmonsan Optical Astronomy Observatory (LOAO) 1.0 m telescope on Mt. Lemmon, USA, the Tubitak Ulusal Gozlemevi (TUG) 1.0 m telescope in Bakirlitepe, Turkey, the Bohyunsan Optical Astronomy Observatory (BOAO) 1.8 m telescope on Mt. Bohyun, Korea, the McDonald Observatory 2.1 m Otto Struve Telescope on Mt. Locke, USA, and the National Astronomical Research Institute of Thailand (NARIT) Observatory 2.4 m telescope on Mt. Doi Inthanon, Thailand. Here, we will present our preliminary results for lightcurve analyses of Baptistina family members.

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Determinants of Technology Commercialization Ecosystem for Universities in Kazakhstan

  • ALIBEKOVA, Gulnaz;TLEPPAYEV, Arsen;MEDENI, Tunc D.;RUZANOV, Rashid
    • The Journal of Asian Finance, Economics and Business
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    • v.6 no.4
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    • pp.271-279
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    • 2019
  • The purpose of this study is to identify the barriers of university and industry cooperation and to develop recommendations for the internal ecosystem of technology commercialization. The research method used is a survey of three categories of experts from 9 universities of Almaty (researchers, technology transfer managers, spin-off-owners). Despite the strong efforts of the government of Kazakhstan in building innovation infrastructure, there is a low level of innovation activity, less than 5% of university inventions are transferred into the industry. The results of the expert survey showed that the main barriers for cooperation between university and industry are: lack of resources to build university-industry links, lack of time due to high teaching load, poor qualification of technology transfer managers and lack of networking with industry. Based on the results of the expert survey, it is proposed to develop the ecosystem for the commercialization of university-based technologies, for which the following economic activities are important: human resources, financing, intellectual property management system, and intermediary infrastructure. The results of this study can be applied in developing the strategies and policies for universities, public research organizations, as well as for national R&D and higher education policies.

Susceptibility Contrast Enhancement Imaging in MRI (핵자기 공명 단층 촬영에서의 자화율 강조 영상법)

  • Ro, Y.M.;Mun, C.W.;Lim, T.H.;Cho, Z.H.
    • Proceedings of the KOSOMBE Conference
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    • v.1992 no.05
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    • pp.85-91
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    • 1992
  • In MRI, an image contrast can be developed as a result of the susceptibility effect if an object has paramagnetic substances. This is mainly due to the non-uniform phase distribution or linear gradient developed by the magnetic susceptibility within a voxel, which in turn reduces the signal intensity; e.g., spin phases are dephased and thereby cancel each other resulting in a reduced signal. In this paper, a new concept for manipulating the susceptibility effect through the use of tailored RF pulses is proposed. As potential applications of the method, two different types of tailored RF pulses are introduced: one for susceptibility artifact correction and the other for contrast enhancement. The latter, for example, can be applied to angiography utilizing the paramagnetic property of deoxygenated blood. Both a theoretical study of the method and experimental results are reported.

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The Effect of Cr Dosage on FePt Nanoparticle Formation

  • Won, C.;Keavney, D.J.;Divan, R.;Bader, S.D.
    • Journal of Magnetics
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    • v.11 no.4
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    • pp.182-188
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    • 2006
  • The search for high-density recording materials has been one of most active and vigorous field in the field of magnetism. $FePt-L1_{0}$ nanoparticle has emerged as a potential candidate because of its high anisotropy. In this paper, we provide an overview of recent work at Argonne National Laboratory that contributes to the ongoing dialogue concerning the relation between structure and properties of the FePt nanoparticle system. In particular we discuss the ability to control structure and properties via dosing with Cr. Cr-dosed FePt films were grown via molecular beam epitaxy and annealed at $550^{\circ}C$ in an ultrahigh vacuum chamber, and were studied with the surface magneto-optic Kerr effect (SMOKE), scanning electron microscopy (SEM) and x-ray magnetic circular dichroism (XMCD). We found that small dosage of Cr helps to generate $L1_{0}$ phase FePt magnetic nanoparticles with small size, defined shape and regular spatial distribution on MgO (001) substrate. The nanostructures are ferromagnetic with high magnetic coercivity (${\sim}0.9T$) and magnetic easy axis in the desired out-of-plane orientation. We also show that controlling the lateral region where nanostructures exist is possible via artificial patterning with Cr.

Particle Dispersibility Improvement of Polyester Fibers with a New Line Injection

  • Park, Seong-Yoon;Kim, Hak-Yong;Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2637-2643
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    • 2010
  • In order to develop a new line injection system for spin draw yarn (FD SDY) fibers, the effect of various parameters in extrusion and melt line conditions on the dispersion and distribution of $TiO_2$ particles within FD PET fibers was investigated. As a result, the dispersibility of $TiO_2$ particles in a PET matrix is found to depend on the particle size and its surface characteristics. Surface modification of $TiO_2$ by dimethyl polysiloxane resulted in the improved dispersibility and affinity of $TiO_2$ particles in the PET matrix. Especially, residence time, mixing temperature, and mixing shear rate in the new line injection system under the SDY spinning process were very important parameters to minimize the agglomeration of $TiO_2$ particles. The FD SDY prepared by the new line injection system was superior to those using the polymerization process and the conventional masterbatch chip dosing process in the color-L and color-b values of the fibers.

The effect of mold rotation on solidification process of an Al-Cu alloy (주형의 회전이 Al-Cu 합금의 응고과정에 미치는 영향)

  • Yu, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.4
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    • pp.525-540
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    • 1997
  • The effect of mold rotation on the transport process and resultant macrosegregation pattern during solidification of an Al-Cu alloy contained in a vertical axisymmetric annular mold cooled from the inner wall is numerically investigated. The mold initially at rest starts to rotate at a prescribed angular velocity simultaneously with the beginning of cooling. Computed results for a representative case show that the mold rotation essentially suppresses the development of both thermal and solutal convections in the melt, creating distinct characteristics such as the liquidus front, flow pattern and temperature distribution from those for the stationary mold. Thermal convection which develops at the early stages of cooling is soon extinguished by the rotating flow induced during spin-up, and thus does not effectively remove the initial superheat from the melt. On the other hand, solutal convection, though it weakens considerably and is confined within the mushy zone, still predominates over the solute redistribution process. With increasing the angular velocity, the solute transport in the axial direction is enhanced, whereas that in the radial direction is reduced. The final macrosegregation formed in the mold rotating at moderate angular velocities appears to be favorable in comparison with the stationary casting, in that not only relatively homogenized composition is achieved, but also a severely positive-segregated channel is restrained.