• 제목/요약/키워드: Spherical mechanism

검색결과 143건 처리시간 0.025초

용매열법을 이용한 CuInSe2 나노 입자 합성 (Synthesis of CuInSe2 Nanoparticles by Solvothermal Method)

  • 김기현;전영갑;박병옥;윤경훈
    • 한국재료학회지
    • /
    • 제14권10호
    • /
    • pp.737-742
    • /
    • 2004
  • $CuInSe_2$ (CIS) nanoparticles of chalcopyrite structure were directly synthesized by a solvothemal method in an autoclave with diethylamine as a solvent. A morphology change of the nanoparticles was observed as a function of reaction temperatures and times. Dense rod-type CIS nanoparticles with width of $5\sim10mm$ and length in the range of 30-80 nm were obtained at $180^{\circ}C$ for 36 hrs whereas spherical particles with diameter in the range of 5-10 nm were observed at $250^{\circ}C$ for 36 hrs. The formation of the rod-like nanoparticles in diethylamine, without double N-chelation, was explained by the Solution-Liquid-Solid (SLS) mechanism.

Kinetically Controlled Growth of Gold Nanoplates and Nanorods via a One-Step Seed-Mediated Method

  • Hong, Soonchang;Acapulco, Jesus A.I. Jr.;Jang, Hee-Jeong;Kulkarni, Akshay S.;Park, Sungho
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권6호
    • /
    • pp.1737-1742
    • /
    • 2014
  • In this research, we further developed the one-step seed mediated method to synthesize gold nanoparticles (GNPs) and control their resulting shapes to obtain hexagonal, triangular, rod-shaped, and spherical gold nanostructures. Our method reveals that the reaction kinetics of formation of GNPs with different shapes can be controlled by the rate of addition of ascorbic acid, because this is the critical factor that dictates the energy barrier that needs to be overcome. This in turn affects the growth mechanism process, which involves the adsorption of growth species to gold nanoseeds. There were also observable trends in the dimensions of the GNPs according to different rates of addition of ascorbic acid. We performed further analyses to investigate and confirm the characteristics of the synthesized GNPs.

Extracellular vesicles as emerging intercellular communicasomes

  • Yoon, Yae Jin;Kim, Oh Youn;Gho, Yong Song
    • BMB Reports
    • /
    • 제47권10호
    • /
    • pp.531-539
    • /
    • 2014
  • All living cells release extracellular vesicles having pleiotropic functions in intercellular communication. Mammalian extracellular vesicles, also known as exosomes and microvesicles, are spherical bilayered proteolipids composed of various bioactive molecules, including RNAs, DNAs, proteins, and lipids. Extracellular vesicles directly and indirectly control a diverse range of biological processes by transferring membrane proteins, signaling molecules, mRNAs, and miRNAs, and activating receptors of recipient cells. The active interaction of extracellular vesicles with other cells regulates various physiological and pathological conditions, including cancer, infectious diseases, and neurodegenerative disorders. Recent developments in high-throughput proteomics, transcriptomics, and lipidomics tools have provided ample data on the common and specific components of various types of extracellular vesicles. These studies may contribute to the understanding of the molecular mechanism involved in vesicular cargo sorting and the biogenesis of extracellular vesicles, and, further, to the identification of disease-specific biomarkers. This review focuses on the components, functions, and therapeutic and diagnostic potential of extracellular vesicles under various pathophysiological conditions.

고 출력 레이저에 의한 충격파 현상 연구 및 응용 (High Power Laser Driven Shock Compression of Metals and Its Innovative Applications)

  • 이현희;곽민철;최지혜;여재익
    • 대한기계학회논문집B
    • /
    • 제32권11호
    • /
    • pp.832-840
    • /
    • 2008
  • Ablation occurs at irradiance beyond $10^9\;W/cm^2$ with nanosecond and short laser pulses focused onto any materials. Phenomenologically, the surface temperature is instantaneously heated past its vaporization temperature. Before the surface layer is able to vaporize, underlying material will reach its vaporization temperature. Temperature and pressure of the underlying material are raised beyond their critical values, causing the surface to explode. The pressure over the irradiated surface from the recoil of vaporized material can be as high as $10^5\;MPa$. The interaction of high power nanosecond laser with a thin metal in air has been investigated. The nanosecond pulse laser beam in atmosphere generates intensive explosions of the materials. The explosive ejection of materials make the surrounding gas compressed, which form a shock wave that travels at several thousand meters per second. To understand the laser ablation mechanism including the heating and ionization of the metal after lasing, the temporal evolution of shock waves is captured on an ICCD camera through laser flash shadowgraphy. The expansion of shock wave in atmosphere was found to agree with the Sedov's self-similar spherical blast wave solution.

크롬 도금한 유압 실린더 로드와 시일 사이의 미끄럼접촉 해석 (Sliding Contact Analysis between Chromium Plated Hydraulic Cylinder Rod and Seals)

  • 박태조;김민규
    • 드라이브 ㆍ 컨트롤
    • /
    • 제15권1호
    • /
    • pp.10-15
    • /
    • 2018
  • The hydraulic cylinder seals are used not only to protect leakage of the working fluids but also to prevent incoming of foreign particles into the system. Chromium plating is generally applied to improve corrosion and wear resistance. It has been noticed that sealing surface damage occurs due to the hard foreign/wear particles contained in the hydraulic oil. In this study, a three-bodied sliding contact problem related with a PTFE seal, a spherical particle and chrome-plated steel substrate is modeled to investigate the relations to wear mechanism. Using the nonlinear finite element software, MARC/MENTAT, the deformed shapes, the von Mises and first principal stress distributions with plating thickness were compared. The sealing surface was mainly abraded by hard particles embedded in the seal. The plastic deformation of the steel substrate decreased with thicker plating. Hence it could be more effective to coat the sealing surface of a hydraulic cylinder with a hard material such as TiN, TiC and DLC.

Robust Cooperative Relay Beamforming Design for Security

  • Gong, Xiangwu;Dong, Feihong;Li, Hongjun;Shao, Wei
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • 제9권11호
    • /
    • pp.4483-4501
    • /
    • 2015
  • In this paper, we investigate a security transmission scheme at the physical layer for cooperative wireless relay networks in the presence of a passive eavesdropper. While the security scheme has been previously investigated with perfect channel state information(CSI) in the presence of a passive eavesdropper, this paper focuses on researching the robust cooperative relay beamforming mechanism for wireless relay networks which makes use of artificial noise (AN) to confuse the eavesdropper and increase its uncertainty about the source message. The transmit power used for AN is maximized to degrade the signal-to-interference-plus-noise-ratio (SINR) level at the eavesdropper, while satisfying the individual power constraint of each relay node and worst-case SINR constraint at the desired receiver under a bounded spherical region for the norm of the CSI error vector from the relays to the destination. Cooperative beamforming weight vector in the security scheme can be obtained by using S-Procedure and rank relaxation techniques. The benefit of the proposed scheme is showed in simulation results.

유압 피스톤 펌프의 실린더 블록과 밸브 플레이트 사이의 유막 특성 (Fluid Film Characteristics between Cylinder Block and Valve Plates in Oil Hydraulic Piston Pumps)

  • 정재연;송규근;오석형;김종기
    • 유공압시스템학회논문집
    • /
    • 제1권2호
    • /
    • pp.8-14
    • /
    • 2004
  • Abstract: In the oil hydraulic piston pumps the clearance between the valve plate and cylinder block plays an important role for volumetric and overall efficiency. Thus, adequate lubricational fluid film is needed for the interface. In this study, fluid film thickness is measured by a gap sensor and a slip ring under operational conditions to observe the behavior of the lubrication mechanism in detail. To investigate the effect according to the valve plate types in view of the fluid film, three different types were designed. Leakage flow rate and shaft torque were also measured to clarify the effect according to the valve plate types. A broad range of experiments were conducted to provide reasonable data on the effect of fluid film. In this experiments two main parameters were found, of which the one is the discharge pressure and the other is valve plate geometry. As a result, we found that the spherical valve plate could get more stable fluid film thickness, maintain good efficiency for high pressure range than the other types.

  • PDF

Comparative Study on Collision Strength of LNG Carriers

  • Choe, Ick-Hung;Kim, Jae-Hyun;Ahn, Ho-Jong;Kim, Oi-Hyun
    • Journal of Ship and Ocean Technology
    • /
    • 제5권3호
    • /
    • pp.36-44
    • /
    • 2001
  • The collision energy absorbing characteristics of side structure of the LNG carriers which have the cargo containment systems of the spherical and the membrane types are compared. A failure mechanism of the double hull side structures of 130, 000 $m^3$ class LNG carriers under sideways collision event has been simulated by using the detailed finite element calculations. In ship collision analysis, the finite element method based on explicit time integration has been use[1 with much success. Finite element modeling techniques for detail description of structural members antral ship motion regarding the dynamic behavior allowed to investigate the effect of bow shape and the initial contact position on side shell of collided ship. In the numerical simulations of the ship-to-ship sideways collision, the effect of the colliding bow shapes and the change of the colliding ship draft are investigated. The critical collision energy which is absorbed by a side structure of a collided ship until the fore-end of colliding ship arrives at the boundary of the cargo tank is calculated. The critical speed of specified colliding ships which can not penetrate the boundary of the LNG cargo tank of the collided ship under collision accident if evaluated.

  • PDF

Electrical Interconnection with a Smart ACA Composed of Fluxing Polymer and Solder Powder

  • Eom, Yong-Sung;Jang, Keon-Soo;Moon, Jong-Tae;Nam, Jae-Do
    • ETRI Journal
    • /
    • 제32권3호
    • /
    • pp.414-421
    • /
    • 2010
  • The interconnection mechanisms of a smart anisotropic conductive adhesive (ACA) during processing have been characterized. For an understanding of chemorheological mechanisms between the fluxing polymer and solder powder, a thermal analysis as well as solder wetting and coalescence experiments were conducted. The compatibility between the viscosity of the fluxing polymer and melting temperature of solder was characterized to optimize the processing cycle. A fluxing agent was also used to remove the oxide layer performed on the surface of the solder. Based on these chemorheological phenomena of the fluxing polymer and solder, an optimum polymer system and its processing cycle were designed for high performance and reliability in an electrical interconnection system. In the present research, a bonding mechanism of the smart ACA with a polymer spacer ball to control the gap between both substrates is newly proposed and investigated. The solder powder was used as a conductive material instead of polymer-based spherical conductive particles in a conventional anisotropic conductive film.

Synthesis and Optical Characteristics of PAM/HgS Nanocomposites

  • Qin, Dezhi;Yang, Guangrui;Zhang, Li;Du, Xian;Wang, Yabo
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권4호
    • /
    • pp.1077-1081
    • /
    • 2014
  • Polyacrylamide (PAM) -HgS nanocomposites were successfully prepared in polyacrylamide (PAM) matrix. From TEM and XRD characterizations, the synthesized HgS nanocrystals were chain-like spherical in shape with a diameter of about 40-60 nm and high crystalline quality. The quantum-confined effect of HgS nanocrystals was confirmed by UV-vis diffuse reflection spectra. The optical properties of products were investigated by using photoluminescence (PL) spectra, which showed that HgS nanocrystals exhibited good optical properties with maximum emission peak at about 640 and 650 nm at different reaction temperatures. The interaction of HgS nanocrystals with PAM was studied through FT-IR spectroscopy and TG analysis, which suggested that $Hg^{2+}$ could interact with functional groups of PAM. The experimental results indicated that PAM not only induced nucleation, but also inhibited further growth of HgS crystals and play an important role in the formation of PAM/HgS nanocomposites. In addition, the possible mechanism of HgS nanoparticles growth in PAM solution was also discussed.