• Title/Summary/Keyword: Spherical aggregate

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Effect of Heat Treatment on the Morphology and Transparency of Thick Inorganic-Organic Hybrid Films Prepared by the Electrophoretic Sol-Gel Deposition of Polyphenylsilsesquioxane Particles

  • Hasegawa, Koichi;Katagiri, Kiyofumi;Matsuda, Astunori;Tatsumisago, Masahiro;Minami, Tsutomu
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.15-20
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    • 2000
  • Thick inorganic-organic hybrid films were prepared on ITO-coated glass substrates by the electrophoretic sol-gel deposition of polyphenylsilsesquioxane particles. The morphology of the deposited films changed from the aggregate of the spherical particles to monolith by heat treatment at temperatures higher than $200^{\circ}C$. Transparency of the films was significantly improved accompanied by the morphological change of the particles. The degree of the morphological change was governed by two factors; maximum heat treatment temperature and heating rate. Transparent thick films of ca. 3$\mu\textrm{m}$ in thickness were obtained only by heat treatment at $400^{\circ}C$ for 2h with rapid heating from room temperature to $400^{\circ}C$. These films obtained were strongly adhered to the ITO-coated glass substrates and has a very smooth surface.

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Three Viruses Isolated form Gentiana spp. in Korea (용담(Gentiana spp.)에서 분리한 3종의 바이러스)

  • 노성환;장무웅
    • Korean Journal Plant Pathology
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    • v.14 no.5
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    • pp.425-432
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    • 1998
  • Gentian plants (Gentiana spp.) showing yellow ringspot, mosaic, necrotic fleck and malformation were collected from their growing areas in Taegu, Kyungpook province and Alpine Agricultural Experiment Station, Korea. Three viruses isolated from the naturally infected gentian were identified as broad bean wilt virus (BBWV), cucumber mosaic virus (CMV) and clover yellow vein virus identified as broad bean wilt virus (CIYVV) by their host range, immunosorbent electron microscopy (ISEM) and electron microscopy. Electron microscopic examination of negatively stained preparations showed that BBWV and CMV are spherical particles of 28 nm and 30 nm in diameter, and CIYVV is filamentous particles of ca. 780 nm in length. By ISEM, BBWV was detected mainly in gentian showing yellow ringspot and mottle, CIYVV in necrotic fleck leaf of gentian and CMV in narrow and distorted mosaic leaf of gentian. BBWV and CMV are the most prevalent in the cultivated gentian. In ultrathin sections of BBWV infected tissues, large aggregates of crystalline array of virus particles and vesicular body were found in the cytoplasm and vacuole of mesophyll cells. In case of CIYVV, pinwheel- and laminated aggregate-type inclusions as well as filamentous virus particles were observed in the cytoplasm of mesophyll cells.

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The Properties of Underwater-Hardening Epoxy Mortar Used the Rapidly Cooled Steel Slag (RCSS) (급냉 제강슬래그를 사용한 수중 경화형 에폭시 모르타르의 특성)

  • Kim, Jin-Man;Kwak, Eun-Gu;Bae, Kee-Sun
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.549-555
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    • 2007
  • Although blast furnace slag has been widely used in concrete as a cementitious admixture or aggregate for many years, the slowly cooled steel slag is not used in concrete but mainly in road. Its use in concrete operates problem such as the lack of volume stability due to high free CaO content, which can be potentially hazardous in concrete. However, the rapidly cooled steel slag by atomization has a low free CaO content, a high density, and a spherical shape, so it is expected to use in concrete so much. This paper is to understand the probability that the rapid cooled steel slag can replace the silica sand used as aggregate in the epoxy mortar. We did the experimental study on the properties of the epoxy mortar having various replacement proportion of rapidly cooled steel slag. This study shown that increasing content of the rapidly cooled steel slag in epoxy mortar lead to increase largely the passing time of nozzle by O-lot, compressive strength and flexural strength. However except the flow is almost same level. So we understand that the rapidly cooled steel slag has positive effect on increasing of properties in epoxy mortar.

The treatment of coal fly ash for the recycling as ceramic raw materials : I. The effect of calcination and elutriation (요업원료로 재활용하기 위한 석탄회의 처리 : I. 하소 및 수비의 영향)

  • 김유택;이준호;정철원;허화범;신건철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.4
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    • pp.414-422
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    • 1995
  • Coal fly ash was calcined and elutriated for recycling as ceramic raw materials. C Crystal phases, morphologies, chemical components, particle size distributions and Ig. loss of as-received, calcined and elutriated coal fly ash were investigated to study the effects of the calci nation and elutriation on the coal fly ash classification. The experimental equations, which were used in elutriation of clay, were examined in order to find out which equation is appropriated for coal fly ash classification. It turned out that Rittinger's equation is relatively well matched for the fly ash. Having nothing to do with the treatment conditions, the crystal phases of coal f fly ash were mullite, quartz. Calcite peak was detected in as - received and elutriated coal fly a ash; however, it disappeared in calcined coal fly ash. As - received coal fly ash consists of various type of particles such as a cenosphere, coke type, silicate type, whisker type and aggregat e ed type. In case of calcined coal fly ash, coke type particles were eliminated and agglomerated type particles were relatively increased. Most of the particles that were relatively spherical cenosphere in the 4th step of elutriator. Particle size distribution was narrowed by calcination a and elutriation. Especially, in elutriation, particle size distribution was very narrow.

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Analysis of Soot Particle Morphology Using Rayleigh Debye Gans Scattering Theory (RDG 산란 이론을 이용한 그을음 탄소 입자의 형상 분석)

  • Seo, Hyoungseock;Kim, Kibum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.641-646
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    • 2016
  • Soot particles generated by fossil fuel combustion normally have fractal morphology with aggregates consisting of small spherical particles. Thus, Rayleigh or Mie elastic light scattering theory is not feasible for determining the fractal properties of soot aggregates. This paper describes a detailed process for applying Rayleigh-Debye Gans (RDG) scattering theory to effectively extract the morphological properties of any nano-scale particles. The fractal geometry of soot aggregates produced from an isooctane diffusion flame was observed using ex situ transmission electron microscopy (TEM) after thermophoretic sampling. RDG scattering theory was then used to analyze their fractal morphology, and various properties were calculated, such as the diameter of individual soot particles, number density, and volume fraction. The results show indiscernible changes during the soot growth process, but a distinct decreasing trend was observed in the soot oxidation process. The fractal dimension of the soot aggregates was determined to be around 1.82, which is in good agreement with that produced for other types of fuel. Thus, it can be concluded that the value of the fractal dimension is independent of the fuel type.

High-Velocity Impact Experiment on Impact Resistance of Steel Fiber-Reinforced Concrete Panels with Wire Mesh (와이어매쉬와 강섬유로 보강된 콘크리트 패널의 내충격성 규명을 위한 고속충격실험)

  • Kim, Sang-Hee;Hong, Sung-Gul;Yun, Hyun-Do;Kim, Gyu-Yong;Kang, Thomas H.K.
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.103-113
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    • 2015
  • This paper studies impact performance of wire-mesh and steel fiber-reinforced concrete based on high-velocity impact experiments using hard spherical balls. In this experimental study, panel specimens were tested with various parameters such as steel fiber volume fraction, presence/absence of wire mesh, panel thickness, impact velocity, and aggregate size for the comparison of impact resistance performance for each specimen. While improvement of the impact resistance for reducing the penetration depth is barely affected with steel fiber volume fraction, the impact resistance to scabbing and perforation is improved substantially. This was due to the fact that the steel fiber had bridging effects in concrete matrix. The wire mesh helped minimizing the crater diameter of front and back face and enhanced the impact resistance to scabbing and perforation; however, the wire mesh did not affect the penetration depth. The wire mesh also reduced the bending deformation of the specimen with wire mesh, though some specimens had splitting bond failure on the rear face. Additionally, use of 20 mm aggregates is superior to 8 mm aggregates in terms of penetration depth, but for reducing the crater diameter on front and back faces, the use of 8 mm aggregates would be more efficient.

Impact Resistance of Steel Fiber-Reinforced Concrete Panels Under High Velocity Impact-Load (고속충격하중을 받는 강섬유보강콘크리트 패널의 내충격성능)

  • Kim, Sang-Hee;Kang, Thomas H.K.;Hong, Sung-Gul;Kim, Gyu-Yong;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.26 no.6
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    • pp.731-739
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    • 2014
  • This paper describes the evaluation of the impact performance of steel fiber-reinforced concrete based on high-velocity impact experiments using hard spherical balls. In this experimental study, panel specimens with panel thickness to ball diameter (h/d) ratios of 3.5 or less were tested with variables of steel fiber volume fraction, panel thickness, impact velocity, and aggregate size. Test results were compared with each other to evaluate the impact resistance. The results showed that the percentage of weight and surface loss decreased as the steel volume fraction increased. However, the penetration depth increased with up to steel fiber volume fraction of 1.5%. Particularly the results of specimens with 20 mm aggregates showed poorer performance than those with 8 mm aggregates. The results also confirmed that the impact performance prediction formulas are conservative with (h/d) ratios of 3.5 or less. Despite the conservative predictions, the modified NDRC formula and ACE formula predict the impact performance more consistently than the Hughes formula.

Submicroscopy of Forest Soils (kandiustults) Derived from Granite in Southern Part of Korea (우리나라 남부지역(南部地域) 화강암질(花崗巖質) 삼림토양(森林土壤)의 SEM과 TEM에 의한 관찰(觀察))

  • Cho, Hi Doo;An, Ki Wan
    • Journal of Korean Society of Forest Science
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    • v.90 no.5
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    • pp.608-618
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    • 2001
  • To understand the weathering processes of the soil by submicroscopic method is very important to realize the properties of the soils. In this study soil formation processes show every steps to the changes in chemical and mechanical properties and the submicroscopic characteristics of soil weathering on the profiles of forest soils derived from granite in southern part of Korea. Fecal pellets(SEM) are given a full detail of the positive activities of the forest soil animals; mainly invertebrates in the O horizon and the E horizon. External shapes of fecal pellets have been divided into five groups : spherical, ellipsoidal, cylindrical, platy and threadlike. But doughnutlike form of fecal pellets is observed in this study. The soluble and suspended materials in the soils move downwards by percolation from the A horizon to the B or the BC horizons, and result in the illuviation cutans(SEM) on the ped surface of the lower horizon and deposited stack of kaolinite. Illuviated cutans are deposited on the ped surface even in the depth of 312cm in the BC horizon as well as the Bt horizon and comprise of fine silt, coarse clay and fine clay. A lot of halloysites are observed on the cutan surface. Halloysite formation from feldspars has been well known but a lot of hallyosite formation are observed in this study. The formation were predicted by Jackson(1962), inferred by Wada and Kakuto(1983a, b) and proved evidently by Cho and Mermut(1992a, b). This also suggests that halloysites in the soils derived from granite are formed a lot from ferruginous chlorites. The release of Fe from the chlorite structure are significant pedogenic processes and newly formed Fe oxides imparted a red color to the soils. The iron oxides particles, which are ejected and recrystalized, aggregate thickly on the edge of the ferruginous chlorites, and this indicates the release of structural Fe from weathered chlorites. Hematites and goethites are frequent in the fine clay in this soils.

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Influence of Fine Aggregate Properties on Unhardened Geopolymer Concrete (잔골재 특성이 굳지 않은 지오폴리머 콘크리트에 미치는 영향)

  • Cho, Young-Hoon;An, Eung-Mo;Lee, Su-Jeong;Chon, Chul-Min;Kim, Dong-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.101-111
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    • 2016
  • It is possible that aggregates add on to geopolymer based fly ash to mix mortar and concrete like cement. This is necessary to evaluate mineral composition, particle shape, surface, size distribution, density and absorption ratio for fine aggregates due to few detailed research to examine influence of fine aggregates properties on unhardened geopolymer concrete. In this research, used two different fine aggregates, Jumunjin sand(having quartz, mica, feldspar, pyroxene in mineral composition, more than 96% of total size between -0.60 and +0.30mm, angular shape and rough surface) and ISO sand(having almost all quartz in mineral composition, more than 51% size between -1.40 and +0.60mm, simultaneously varied size distribution, spherical shape and smooth surface). After an experimental result of the varied ratio of Si/Al=1.0-4.1 geopolymer paste, mix proportion respectively applied Si/Al=1.5 having the highest compressive strength to mortar and Si/Al=3.5 having the highest consistency to concrete. Geopolymer mortar by mixing with Jumunjin and ISO sand in varied range of 20-50wt.% showed flow size increase between 69.5 and 112.0mm, between 70.5 and 126.0mm respectively. Geopolymer concrete at an addition of 77wt.% of total aggregates ratio showed that average compressive strength was 32MPa and the consistency was favorable to molding. Since ISO sand observing varied size distribution, spherical shape, smooth surface, low absorption ratio resulted in advantageous properties on consistency of geopolymer, geopolymer concrete can be suitable for using the fine aggregates similar to ISO sand.

Spawning Behavior and Early Life History of Grass Puffer, Takifugu niphobles (Jordan et Snyder) (Teleostei: Tetraodontidae) (복섬, Takifugu niphobles(Jordan et Snyder)의 산란습성(産卵習性) 및 초기생활사(初期生活史))

  • Oh, Sung-Hyun;Han, Kyeong-Ho;Kim, Yong-Min;Joung, Hyun-Ho;Shin, Sang-Soo;Kim, Yong-Uk
    • Korean Journal of Ichthyology
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    • v.12 no.4
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    • pp.236-243
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    • 2000
  • The purpose of present the study was to describe the spawning behavior and early life history of the grass puffer, Takifugu niphobles. The grass puffer was caught at the spawning ground on the coast Dolsan, Korea from May to the 1998. Artificial fertilization was carried out to get fertilied eggs. Spawning season was from the end of May to the beginning of July on the coast of the Dolsan, Korea. Form 2~6 days before the spring tide the aduct males and females began to aggregate in the shore water, and they spawned in the upper part of intertidal zone exposed to air among pebble stone. The fertilized eggs were demersal, transparent and spherical in shape, and its diameter were 0.87~0.95 mm with several oil globules of 0.0014~0.0540 mm. Hatching began about 146 hours after fertilization under water temperature $21.2{\sim}22.3^{\circ}C$. The newly-hatched larva was 2.02~2.24 mm in total length (TL, mean: 2.14 mm), with 22~24(8~9+14~15) myotomes, and mouth and anus was not yet open. In 3 days after hatching it was measured 2.64~2.93 mm in TL (mean: 2.76 mm), and yolk sac was completely absorbed and transformed to postlarval stage. In 15 days after hatching it was measured 4.43~4.82mm in TL (mean: 4.59mm), and the caudal notochord flexion started. The larvae reached the juvenile stage in 28 days after hatching and attained 7.55~7.65mm in TL (mean: 7.60mm), and all fin-rays were formed.

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