• Title/Summary/Keyword: Spherical Particle

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Preparation of Monosized Titanium Dioxide Powder from TEOT (TEOT로부터 $TiO_2$단분산 분말 합성에 관한 연구)

  • 안영필;최석홍
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.509-517
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    • 1988
  • The controlled Ti(CO2H5)4 hydrolysis reactions for the synthesis of Spherical Monodispersed Titania powders are described. Increasing the concentration of TEOT and the molar ratio of water to TEOT in alcohol solution decrease the reaction time and the particle size. The reaction time is delalyed by increasing the chain length and the number of carbon branches of alcohol as a solvent. The prepared powders with an average diameter of 0.8$\mu$ and the spherical monodispersed transfer to Rutile phase at 55$0^{\circ}C$.

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Migration in concentrated suspension of spherical particles dispersed in polymer solution

  • Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.13 no.1
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    • pp.19-27
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    • 2001
  • In this symposium paper, the migration and hydrodynamic diffusion of non-colloidal, spherical particles suspended in polymer solutions are considered under Poiseuille or torsional flows. The migration phenomena in polymer solutions are compared with those in Newtonian fluids and the effect of fluid elasticity is discussed. The experimental results on particle migration in dilute polymer solution reveal that even a slight change in the rheological property of the dispersing medium can induce drastic differences in flow behavior and migration of particles, especially in dilute and semi-concentrated suspensions.

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Characterization of Spherical Particles by Light Scattering

  • Sangwook Park;Jungmoon Sung;Taihyun Chang
    • Bulletin of the Korean Chemical Society
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    • v.12 no.3
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    • pp.322-328
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    • 1991
  • We have studied a characterization method of accurate size of spherical particles by fitting experimental light scattering profile to the rigorous theoretical scattering function. An efficient software has been developed for computation of the theoretical scattering function and regression analysis. A light scattering instrument has been built and the necessary data acquisition and analysis are carried out by use of a personal computer with an emphasis on the reduction of analysis and time aiming that this study will be extended toward a development of a practical particle sizing apparatus. The performance of the instrument and the software has been evaluated with latex spheres and found to be satisfactory.

Change of Particle Size of Spherical Alumina Powders Prepared by Emulsion Method in the Region of Low Hydroxypropylcellulose Concentration (저농도의 HPC 영역에서 에멀젼법에 의해 제조된 구형 알루미나 분말의 입자 크기 변화)

  • Ahn, C.W.;Park, K.S.;Yoo, H.S.;Cho, K.;Lee, Y.W.;Yang, M.S.
    • Journal of the Korean Ceramic Society
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    • v.32 no.5
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    • pp.594-600
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    • 1995
  • Spherical alumina gel powders were produced by hydrolysis of aluminum sec-butoxide (Al(sec-OC4H9)3) in a n-octanol/acetonitrile mixed solvent. The enlargement of particle size was induced by increasing HPC (hydroypropylcellulose) concentration (0.005, 0.1, and 0.05 g/ι) and emulsion-state aging time (10 min and 360 min). Mean particle sizes of dried alumina gel powders increased from 1.4 ${\mu}{\textrm}{m}$ to 3.5${\mu}{\textrm}{m}$ at 10-min emulsion-state aging time and from 1.9${\mu}{\textrm}{m}$ to 4.1${\mu}{\textrm}{m}$ at 360-min emulsion-state aging time as HPC concentration increased from 0.005 g/ι to 0.05 g/ι. At the same HPC concentration, particle size of dried alumina gel powder increased with increasing of emulsion-state aging time from 10 min to 360 min. The increase in the average particle size of dried alumina gel powder with increase in HPC concentration was interpreted as the enlargement of particles from alkoxide emulsions unprotected by HPC. The produced dried gel powder calcined at 115$0^{\circ}C$ for one hour transformed to $\alpha$-alumina.

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Motion Characteristics of Particle in Model GIS (모의 GIS내 금속이물의 거동특성)

  • 김경화;이재걸;곽희로
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.4
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    • pp.152-159
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    • 1999
  • This paper describes the rmtion characteristics of a particle in GIS under AC voltage. To measure the motion characteristics of the particle, a model gas chamber and parallel plain electrodes were designed and manufactured lift-off voltages of wire and spherical particles on the electrode were calculated and rreasured, and electric charge was calculated. By using a high speed carrera, the rmtion characteristics of various particles with aw}ied voltages, such as motion pattern, lift-off time, lift-off height, were analyzed 1be lift-off voltages were greatly affected by diarreters of wire and spherical particles. At voltage around lift-off voltage, the stand-up particle in vertical state rmved up and down between electrodes and the height of the lift-off particle was low. At voltage around breakdown voltage, the particle repeated vertical rotation a few times while they were being lifted off, and then, they were floating between the electrodes.trodes.

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A NUMERICAL METHOD TO ANALYZE GEOMETRIC FACTORS OF A SPACE PARTICLE DETECTOR RELATIVE TO OMNIDIRECTIONAL PROTON AND ELECTRON FLUXES

  • Pak, Sungmin;Shin, Yuchul;Woo, Ju;Seon, Jongho
    • Journal of The Korean Astronomical Society
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    • v.51 no.4
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    • pp.111-117
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    • 2018
  • A numerical method is proposed to calculate the response of detectors measuring particle energies from incident isotropic fluxes of electrons and positive ions. The isotropic flux is generated by injecting particles moving radially inward on a hypothetical, spherical surface encompassing the detectors. A geometric projection of the field-of-view from the detectors onto the spherical surface allows for the identification of initial positions and momenta corresponding to the clear field-of-view of the detectors. The contamination of detector responses by particles penetrating through, or scattering off, the structure is also similarly identified by tracing the initial positions and momenta of the detected particles. The relative contribution from the contaminating particles is calculated using GEANT4 to obtain the geometric factor of the instrument as a function of the energy. This calculation clearly shows that the geometric factor is a strong function of incident particle energies. The current investigation provides a simple and decisive method to analyze the instrument geometric factor, which is a complicated function of contributions from the anticipated field-of-view particles, together with penetrating or scattered particles.

Microstructure and shear modulus in concentrated dispersions of bidisperse charged spherical colloids

  • Chun, Myung-Suk;Lee, Sangwoo;Lee, Tae-Seok;Cho, Jae-Seol
    • Korea-Australia Rheology Journal
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    • v.16 no.1
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    • pp.17-26
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    • 2004
  • We examine rigorous computations on microstructural as well as rheological properties of concentrated dispersions of bidisperse colloids. The NVT Monte Carlo simulation is applied to obtain the radial distribution function for the concentrated system. The long-range electrostatic interactions between dissimilar spherical colloids are determined using the singularity method, which provides explicit solutions to the linearized electrostatic field. The increasing trend of osmotic pressure with increasing total particle concentration is reduced as the concentration ratio between large and small particles is increased. From the estimation of total structure factor, we observe the strong correlations developed between dissimilar spheres. As the particle concentration increases at a given ionic strength, the magnitude of the first peak in structure factors increases and also moves to higher wave number values. The increase of electrostatic interaction between same charged particles caused by the Debye screening effect provides an increase in both the osmotic pressure and the shear modulus. The higher volume fraction ratio providing larger interparticle spacing yields decreasing high frequency limit of the shear modulus, due to decreasing the particle interaction energy.

Characteristics of ultrafine $SiO_2$ particle synthesized by Electro-hydyodynamic spray (전기-수력학적 분사에 의해 합성된 초미세 $SiO_2$ 입자의 특성)

  • Yoon, J.U.;Yang, T.H.;Ahn, K.H.;Choi, M.S.
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.174-179
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    • 2000
  • Ultrafine particles have been used widely in many high technology industrial areas. The spherical nonagglomerated and uniform nanometer-size $SiO_2$ particles are synthesized by the direct injection of TEOS(Tetraethyorthosilicate) using electro-hydrodynamic spray ins method. Electro-hydrodynamic spray can generate in the range of submicron-size TEOS particles with high electric charge by applying a high electric field between the liquid injection nozzle and the reaction tube. This TEOS particles are thermally decomposed or oxidized to produce nanometresized $SiO_2$ particles in the reaction tube. Spherical, nonagglomerated and ultrafine particle generated and examined at furnaced temperature, $800^{\circ}C$ and TEOS flowrate of 0.49 or $1.00cm^3/hr$ using SEM and SMPS. As the total gas flowrate changes from 1.51pm to 5.01pm, the mean diameter of $SiO_2$ particle decreases from 120 nm to 68nm.

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A review on modelling and monitoring of railway ballast

  • Ngamkhanong, Chayut;Kaewunruen, Sakdirat;Baniotopoulos, Charalampos
    • Structural Monitoring and Maintenance
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    • v.4 no.3
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    • pp.195-220
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    • 2017
  • Nowadays, railway system plays a significant role in transportation, conveying cargo, passengers, minerals, grains, and so forth. Railway ballasted track is a conventional railway track as can be seen all over the world. Ballast, located underneath the sleepers, is the most important elements on ballasted track, which has many functions and requires routine maintenance. Ballast needs to be maintained frequently to prevent rail buckling, settlement, misalignment so that ballast has to be modelled accurately. Continuum model was introduced to model granular material and was extended in ballast. However, ballast is a heterogeneous material with highly nonlinear behaviour. Hence, ballast could not be modelled accurately in continuum model due to the discontinuities nature and material degradation of ballast. Discrete element modelling (DEM) is proposed as an alternative approach that provides insight into constitutive model, realistic particle, and contact algorithm between each particle. DEM has been studied in many recent decades. However, there are limitations due to the high computational time and memory consumption, which cause the lack of using in high range. This paper presents a review of recent ballast modelling with benefits and drawbacks. Ballast particles are illustrated either circular, circular crump, spherical, spherical crump, super-quadric, polygonal and polyhedral. Moreover, the gaps and limitations of previous studies are also summarized. The outcome of this study will help the understanding into different ballast modelling and particle. The insight information can be used to improve ballast modelling and monitoring for condition-based track maintenance.

Characteristics of Ultrafine SiO$_2$Particle Synthesized by Electro-Hydrodynamic Spray Injection in a Furnace (반응로내 전기-수력학적 분사에 의한 비응집 초미세 SiO$_2$ 입자 합성과 특성)

  • Yun, Jin-Uk;Yang, Tae-Hun;An, Gang-Ho;Choe, Man-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.5
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    • pp.660-665
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    • 2001
  • Ultrafine particles have been widely used in many high technology industrial areas. The spherical nonagglomerated and uniform nanometer-size SiO$_2$particles are synthesized by the direct injection of TEOS(Tetraethyorthosilicate) using electro-hydrodynamic spraying method. Electro-hydrodynamic spraying can generate submicron-size TEOS droplets having high electric charges by applying a high electric field between the liquid injection nozzle and the reaction tube. These TEOS droplets are evaporated, and thermally decomposed or oxidized to produce nanometresized SiO$_2$particles in the reaction tube. Spherical, nonagglomerated and ultrafine particles are generated in various conditions and examined by using SEM and SMPS. As the total gas flow rate in the furnace changes from 1.5 lpm, the mean diameter of SiO$_2$particle decreases from 120 nm to 68 nm. The synthesized particle charging fractions are also investigated.