• 한국수소및신에너지학회논문집
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• 제27권6호
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• pp.737-746
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• 2016

This article describes a comparison on laminar burning velocity measured by Bunsen and spherical flame methods of synthetic natural gas (SNG) with various composition of hydrogen. In this study, the laminar burning velocity measurements were employed by Bunsen burner and cylindrical constant combustor at which flame images were captured by Schlieren system. These results were also compared with numerical based on CHEMKIN package with GRI 3.0, USC-II and UC Sandiego mechanism. In case of spherical flames, the suitable flame radius range and theoretical models were verified using the well-known previous results in methane/air flames. As an experimental condition, hydrogen content of SNG was adjusted 0% to 11%. Equivalence ratios of Bunsen flames were adjusted from 0.8 to 1.6. On the other hand, those of spherical flames were adjusted from 0.6 to 1.4, relatively. From results of this study, the both laminar burning velocities measured in Bunsen and spherical flame methods were resulted in similar tendency. As the hydrogen content increased, the laminar burning velocity also increased collectively. Laminar burning velocity of measured SNG-air flames was best coincided with GRI 3.0 mechanism by comparison of reaction mechanisms.

• 한국연소학회지
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• 제17권2호
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• pp.1-8
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• 2012

Laminar flame speeds of Methane at elevated temperatures and pressures were investigated using constant volume spherical chamber. Pressure trace during combustion was measured in each test and this was used in calculating laminar flame speed of Methane. To have large amount of data, experimental apparatus was fabricated with fully automatically controlled feature. A calculating code which calculates laminar flame speeds at various temperatures and pressures with one experimental result was used to calculate laminar flame speeds. The experimental and calculating methods were verified using the calculated laminar flame speed result with PREMIX code.

• 한국재료학회지
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• 제14권8호
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• pp.600-606
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• 2004

$Zn_{2}SiO_{4}:Mn$ phosphor particles were prepared by a flame spray pyrolysis method. It has been generally known that the high-temperature flame enables fast drying and decomposition of droplets. In the present investigation, the morphology and luminescent property of $Zn_{2}SiO_{4}:Mn$ phosphor were controlled in a severe flame preparation condition. The particle formation in the flame spray pyrolysis process was achieved by the droplet-to-particle conversion without any evaporation of precursors, which made it possible to obtain spherical $Zn_{2}SiO_{4}:Mn$ particles of a pure phase from a droplet. Using colloidal solutions wherein dispersed nano-sized silica particles were adopted as a silicon precursor. $Zn_{2}SiO_{4}:Mn$ particles with spherical shape and filled morphology were prepared and the spherical morphology was maintained even after the high-temperature heat treatment, which is necessary to increase the photoluminescence intensity. The $Zn_{2}SiO_{4}:Mn$ particles with spherical shape, which were prepared by the flame spray pyrolysis and posttreated at $1150^{\circ}C$, showed good luminescent characteristics under vacuum ultraviolet (VUV) excitation.

• 대한기계학회논문집B
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• 제24권10호
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• pp.1351-1358
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• 2000

Two dimensional aerosol dynamics considering the effects of particle generation, coagulation, thermophoresis, sintering and convection has been studied to obtain the growth of non-spherical silica particles in conjunction with determining flame temperature by performing combustion analysis of premixed flat flame. Heat and mass transfer analysis includes 16 species, 29 chemical reaction steps together with oxidation and hydrolysis of SiCl4. The effect of radiation heat loss has also been included. The predictions of flame temperatures and the evolution of particle size distributions were in a reasonable agreement with the existing experimental data.

• Journal of Mechanical Science and Technology
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• 제18권11호
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• pp.2058-2065
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• 2004

A light collecting probe named Multi-color Integrated Cassegrain Receiving Optics (MICRO) is applied to spark-ignited spherical spray flames to obtain the flame propagation speed in freely falling droplet suspension produced by an ultrasonic atomizer. Two MICRO probes are used to monitor time-series signals of OH chemiluminescence from two different locations in the flame. By detecting the arrival time difference of the propagating flame front, the flame propagation speed is calculated with a two-point delay-time method. In addition, time-series images of OH chemiluminescence are simultaneously obtained by a high-speed digital CCD camera to ensure the validity of the two-point delay-time method by the MICRO system. Furthermore, the relationship between the spray properties measured by phase Doppler anemometer (PDA) and the flame propagation speed are discussed with three different experimental conditions by changing the fuel injection rate. It was confirmed that the two-point delay-time method with two MICRO probes is useful and convenient to obtain the flame propagation speed and that the flame propagation speed depends on the spray properties.

• 한국안전학회지
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• 제19권3호
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• pp.20-25
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• 2004

In order to obtain the flame Propagation speed in freely falling droplet suspension Produced by an ultrasonic atomizer, a light collecting probe named Multi-color Integrated Cassegrain Receiving Optics (MICRO) is applied to spark-ignited spherical spray flames. Two MICRO probes are used to monitor time-series signals of OH chemilumine-scence from two different locations in the flame. The flame propagation speed is calculated by detecting the arrival time difference of the propagating flame front. In addition, time-series images of OH chemiluminescence are simultaneously obtained by a high-speed digital CCD camera to ensure the validity of the MICRO system. Furthermore, relationship between the spray properties measured by phase Doppler anemometer (PDA) and the flame propagation speed are discussed with k different experimental conditions by changing the fuel injection rate. It was confirmed that the MICRO probe system was very useful and convenient to obtain the flame propagation speed and that the flame propagation speed was different depending on the spray properties.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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• pp.132-137
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• 2005

The burning characteristics of interacting spherical droplet in a turbulent flow are numerically investigated. The transient combustion of 3-dimensionally arranged droplets, both the fixed streamwise droplet distances of 3 radii and 10 radii and different turbulence intensities, is studied. The results obtained from the present numerical analysis show that droplet vaporization rate for heptane droplet is insensitive to turbulence intensity, and that the transient flame configuration and retardation of droplet surface temperature augmentation with streamwise droplet spacing substantially influence vaporization process of interacting droplets. Single flame mode in which individual flames are merged into single flame, with decreasing streamwise droplet spacing, becomes faster. Therefore, vaporization rate of the second droplet with decreasing streamwise droplet spacing decreases remarkably with flame movement.

• 한국자동차공학회논문집
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• 제1권1호
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• pp.59-65
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• 1993

In a spark ignition engine, in order to make research on flame propagation, attentive concentration should be paid on initial combustion stage about the formation and development of flame. In addition, the initial stage of combustion governs overall combustion period in a spark ignition engine. With the increase of the size of flame kernel, it could reach initial flame stage easily, and the mixture could proceed to the combustion of stabilized state. Therefore, we must study the theoretical calculation of minimum flame kernel radius which effects on the formation and development of kernel. To calculate the minimum flame kernel radius, we must know the thermal conductivity, flame temperature, laminar burning velocity and etc. The thermal conductivity is derived from the molecular kinetic theory, the flame temperature from the chemical reaction equations and the laminar burning velocity from the D.K.Kuehl's formula. In order to estimate the correctness of the theoretically calculated minimum flame kernel radius, the researcheres compared it with the RMaly's experimental values.

• 한국연소학회지
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• 제1권2호
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• pp.21-29
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• 1996

Flame propagation characteristics of propane-air mixtures were experimentally investigated in constant-volume combustion chambers. Flame propagation process was observed as a function of mixture strength, initial mixture temperature and initial mixture pressure in quiescent mixtures. A cylindrical combustion chamber and a spherical combustion chamber contain a pair of parallel windows through which optical access into the chamber can be provided. Laser two beam deflection method was adopted to measure the local flame propagation, which gave information on the flame size and flame propagation speed. Pressure development was also measured by a piezoelectric pressure transducer to characterize combustion in quiescent mixtures. Burning velocity was calculated from flame propagation and pressure measurements. The effect of flow on flame propagation was also investigated under flowing mixture conditions. Laser two beam method was found to be feasible in measuring flame propagation of quiescent mixtures. Flame was observed to propagate faster with higher initial mixture temperature and lower initial pressure. Combustion duration was shortened in the highly turbulent flowing mixtures.

• 대한기계학회논문집B
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• 제23권8호
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• pp.997-1009
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• 1999

Silica particle formation and growth process including chemical reaction, coagulation and sintering was studied in a counterflow diffusion flame burner. The counterflow geometry provides a one dimensional flow field, along the stagnation point streamline, which greatly simplifies interpretation of the particle growth characteristics. $SiCl_4$ has been used as the source of silicon in hydrogen/oxygen/argon flames. The temperature profiles obtained by calculation showed a good agreement with experiment data. Using one and two dimensional sectional method, aerosol dynamics equation in a flame was solved, and these two results were compared. The two dimensional section method can consider sintering effect and growth of primary particle during synthesis, thus it showed evolution of morphology of non-spherical particles (aggregates) using surface fractal dimension. The effects of flame temperature and chemical loading on particle dynamics were studied. Geometric mean diameter based on surface area and total number concentration followed the trend of experiment results, especially, the change of diameters showed the sintering effect in high temperature environment.