• Title/Summary/Keyword: Spent Fuel

Search Result 1,162, Processing Time 0.025 seconds

A preliminary study of pilot-scale electrolytic reduction of UO2 using a graphite anode

  • Kim, Sung-Wook;Heo, Dong Hyun;Lee, Sang Kwon;Jeon, Min Ku;Park, Wooshin;Hur, Jin-Mok;Hong, Sun-Seok;Oh, Seung-Chul;Choi, Eun-Young
    • Nuclear Engineering and Technology
    • /
    • v.49 no.7
    • /
    • pp.1451-1456
    • /
    • 2017
  • Finding technical issues associated with equipment scale-up is an important subject for the investigation of pyroprocessing. In this respect, electrolytic reduction of 1 kg $UO_2$, a unit process of pyroprocessing, was conducted using graphite as an anode material to figure out the scale-up issues of the C anode-based system at pilot scale. The graphite anode can transfer a current that is 6-7 times higher than that of a conventional Pt anode with the same reactor, showing the superiority of the graphite anode. $UO_2$ pellets were turned into metallic U during the reaction. However, several problems were discovered after the experiments, such as reaction instability by reduced effective anode area (induced by the existence of $Cl_2$ around anode and anode consumption), relatively low metal conversion rate, and corrosion of the reactor. These issues should be overcome for the scale-up of the electrolytic reducer using the C anode.

Analysis of AM and AEM Oxides Behavior in a SF Electrolytic Reduction Process (사용후핵연료 전기환원 공정에서의 알카리, 알카리토 금속 산화물들의 거동 분석)

  • 박병흥;강대승;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2004.06a
    • /
    • pp.268-277
    • /
    • 2004
  • process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

  • PDF

Treatment of Simulated Soil Decontamination Waste Solution by Ferrocyanide-Anion Exchange Resin Beads (Ferrocyanide-음이온 교환수지에 의한 모의 토양제염 폐액 처리)

  • Won Hui Jun;Kim Min Gil;Kim Gye Nam;Jung Chong Hun;Park Jin Ho;Oh Won Zin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.3 no.1
    • /
    • pp.41-47
    • /
    • 2005
  • Preparation of ferrocyanide-anion exchange resin and adsorption test of the prepared resin on the Cs$^{+}$$ion were performed. Adsorption capability of the prepared resin on the Cs$^{+}$ion in the simulated citric acid based soil decontamination waste solution was 4 times greater than that of the commercial cation exchange resin. Adsorption equilibrium of the prepared resin on the Cs$^{+}$ion reached within 360 minutes. Adsorption capability on the Cs$^{+}$ion became to decrease above the necessary Co$^{2+}$ion concentration in the experimental range. Recycling test of the spent ion exchange resin by the successive application of hydrogen peroxide and hydrazine was also performed. It was found that desorption of Cs$^{+}$ion from the resin occurred to satisfy the electroneutrality condition without any degradation of the resin.

  • PDF

A Feasibility Study on the Polymer Solidification of Evaporator Concentrated Wastes (폐액증발기 농축폐액 폴리머고화 타당성 연구)

  • Yang, Ho-Yeon;Kim, Ju-Youl
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.5 no.4
    • /
    • pp.297-308
    • /
    • 2007
  • The granulation equipment of concentrated wastes is manufactured for the polymer solidification of concentrated wastes. It uses liquid sodium silicate as a granulating agent for the granulating of dried powder containing boric acid. The granulating agent is sprayed in the form of droplet and mean size of dried granules is $2{\sim}4mm$. The new technology which has been used for the polymer solidification of spent resin in U.S. and certified by Nuclear Regulatory Commission (NRC) is successfully applied to concentrated wastes. This uses in-situ solidification process within drum without mechanical mixing. Maximum loading of waste can be achieved without increasing of waste volume. Polymer waste forms were evaluated with several test such as fire test, compressive strength test, leaching test, immersion test, irradiation test, and thermal cycling test according to standard test procedures.

  • PDF

Economics Assessments of Spent Fuel Management Options in Korea (사용후핵연료관리에 관한 경제성 분석)

  • 전풍일
    • Nuclear industry
    • /
    • v.4 no.6 s.22
    • /
    • pp.19-23
    • /
    • 1984
  • 현재 우리나라에는 3기의 원전이 운전중에 있으며 6기가 건설중에 있다. 즉, 2기의 가압경수로(PWR)의 1기의 가압중수로(HWR)가 운전중에 있으며 건설중인 것은 모두 PWR이다. 현재 추진되고 있는 원전계획을 수행하면, 1990년에는 사용후핵연료가 년간 약200톤씩 방출될 것이며, 2000년에는 500톤 정도가 방출되게 된다. 이와 같은 핵사용후연료는 현재 소내저장하고 있으나 '90년대 중반 부터는 소내저장용량이 한계에 달하게 될 것으로 전망되고 있다. 따라서 본교에서의 이와 같은 소내저장 한계성에 대처할 수 있는 가능한 방안을 검토하고, 이를 경제성 측면에서 분석하고자 하였다. 사용후핵연료의 관리방안에 대한 경제성 분석을 위해서는 장래의 원전계획, 원자로형 및 핵연료주기방식 등에 대한 여러 가지 가정이 필요하게 된다. 원전계획은 정부에서 발표한 $\ulcorner$5차5개년 수정계획$\lrcorner$에 의거하여 원전시설용량은 현재의 2GWe에서 2000년에는 22GWe로, 2025년에는 44GWe로 늘어나는 것으로 보았다. 이와 같은 원전계획을 바탕으로 6가지 핵연료주기에 관한 시나리오를 설정하였다. 즉, 사용후핵연료를 비순환방식으로 운영하는 2가지 경우, 순환방식으로 운영되는 3가지 경우 그리고 FBR에 활용하는 1가지의 경우에 대하여 검토하였다. 사용후핵연료의 관리방식에 따른 장기적인 안목에서의 경제성 분석은 핵연료주기비용 뿐만아니라 원전의 투자비도 함께 분석하는 것이 합리적이며, 따라서 본교에서는 계획기간 동안의 6가지 시나리로에 따른 원전 및 핵연료주기에 관한 총 투자비를 비교하였고, 1982년 가격으로 현가화한 단가도 비교${\cdot}$검토 하였다. 이와 같은 6가지 시나리오에 대한 경제성을 비교해 본 결과, 핵연료주기선택의 경제성평가에 큰 영향을 주는 핵연료주기요소는 재처리비, 재처리시 방출되는 폐기물의 처리${\cdot}$처분비 그리고 사용후핵연료 저장방식으로 판명되었으며 6가지 시나리오에 대한 경제성 비교평가 결과, 다음과 같은 결론을 얻었다. 단기적인 안목에서는 소내저장용량을 확장하는 방안이 가장 바람직하며, 중기적인 관점에서는 소외집중저장설비가 활발히 수행되는 시점에서는 사용후핵연료를 재처리하여 재활용하는 방안도 강구되어야 할 것이다.

  • PDF

Recovery of Zirconium from Spent Pickling Acid through Precipitation Using BaF2 and Electrowinning in Fluoride Molten Salt (BaF2 침전 및 불화물 용융염 전해 제련을 통한 폐 산세액 내 지르코늄 회수)

  • Han, Seul Ki;Nersisyan, Hayk H.;Lee, Young Jun;Choi, Jeong Hun;Lee, Jong Hyeon
    • Korean Journal of Materials Research
    • /
    • v.26 no.12
    • /
    • pp.681-687
    • /
    • 2016
  • Zirconium(Zr) nuclear fuel cladding tubes are made using a three-time pilgering and annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zr is dissolved in HF and $HNO_3$ mixed acid during the process and pickling waste acid, including dissolved Zr, is totally discarded after being neutralized. In this study, the waste acid was recycled by adding $BaF_2$, which reacted with the Zr ion involved in the waste acid; $Ba_2ZrF_8$ was subsequently precipitated due to its low solubility in water. It is very difficult to extract zirconium from the as-recovered $Ba_2ZrF_8$ because its melting temperature is $1031^{\circ}C$. Hence, we tried to recover Zr using an electrowinning process with a low temperature molten salt compound that was fabricated by adding $ZrF_4$ to $Ba_2ZrF_8$ to decrease the melting point. Change of the Zr redox potential was observed using cyclic voltammetry; the voltage change of the cell was observed by polarization and chronopotentiometry. The structure of the electrodeposited Zr was analyzed and the electrodeposition characteristics were also evaluated.

A study of Korean traditional Food in Kang Won Do (I) (강원 지역 농촌 주부들의 전통 식생활 관리 현황에 관한 실태 조사(I) -식생활에 대한 태도와 일반적 현황을 중심으로-)

  • 김은실
    • Korean journal of food and cookery science
    • /
    • v.11 no.4
    • /
    • pp.342-350
    • /
    • 1995
  • The purpose of this study was to improve and hand down traditional dining habits. Questionnaires were distributed to rural house wives in Kangwon-do. The results were as follows; 1. 30.8% of the respondents was 40 to 49 years old. 35.2% of their education was primary school. 49.5% of them had husbands and children. 44.2% of them had 3 to 4 family members. 26.9% of them earned 8 to 11 millon won yearly. 2. Their housing environment showed that 52.5% of housing was a Korean traditional house or Hanok. 72.1% of kitchen was a stand-up one. 66% of fuel was oil. 3. 99.3% of the respondents had refrigerators. 66.3% electronic range, 95.9% electronic rice cooker, 97.2% gas range, 59.6% mixer, 62% electronic fry pan respectively. 4. 73.5% of the respondents got information about Korean traditional food from seniors or friends. 36.6% of them learned new recipe from TV, newspapers and magazines. 43.3% of them thought their concern about meals was average. 48.4% of them paid much attention to prepare meals for themselves. 52.7% of them spent a half to one hour for preparing dinner. 48.3% of them ate processed foodstaffs often. 31.5% of them dined out once every two or three months. 5. 79.5% of them had rice for breakfast, 74.5% for lunch, and 98.4% for dinner respectively. 96.2% of the respondents made Kimchi and 55% among them had two kinds of Kimchi. 91.1% of them had two to three kinds of dishes except Kimchi for breakfast. 68% of them used a synthetic flavoring. 6. 16.2% of the respondents ate beef once a week, 40% pork, 23% chicken, 3% dog meat respectively. 37% of them ate mackerel pike, 25.5% mackerel once a week, 11.6% hairtail, 25.5% mackerel pike, 25.6% yeemunshu, 13.7% tuna respectively. Freshwater fishes such as mudfish, trout and Israel carp were their favorite onces.

  • PDF

Adsorption of Textile Wastewater on Sawdust (톱밥에 의한 염색폐수의 흡착처리)

  • Kim, Tak-Hyun;Park, Chul-Hwan;Kim, Sang-Yong
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.30 no.4
    • /
    • pp.439-445
    • /
    • 2008
  • Sawdust is considered one of the cheapest and abundantly available adsorbents, and it is not necessary to regenerate. The spent sawdust can be incinerated or reused as a fuel. The sawdust adsorption can be applied to the removal of color and metal cations from the wastewater. The aim of this study was to evaluate the adsorptive capacities of sawdust with respect to color, COD, SS, turbidity, metal cation from textile wastewater. Langmuir, Freundlich, BET and Sips adsorption isotherm were obtained for the sawdust adsorption of Fe(III). The effects of particle size and amount of sawdust on the adsorption of Fe(III) were also studied. COD, SS, color, turbidity and Fe(III) removal efficiencies were examined at the continuous fixed-bed adsorption test. It was showed the removal efficiencies of SS 50.0%, Fe(III) 25.0%, turbidity 79.4%, color 48.6% and COD 50.9%. In addition, the changes of surface structure between before and after adsorption were investigated through SEM analysis. It is confirmed that the waste sawdust can be successfully used as an adsorbent for wastewater treatment.

PERFORMANCE OF SMALL SCALE LIVESTOCK/CROP DEMONSTRATION-CUM-TRAINING FARMS IN SRI LANKA

  • de Jong, R.;Kuruppu, L.G.;Jayawardena, Q.W.;Ibrahim, M.N.M.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.7 no.4
    • /
    • pp.571-582
    • /
    • 1994
  • Three livestock/crop demonstration-cum-training farms have been established on plots of half, one and two acres, typical of the "Kandyan Forest Garden System" Vegetables, bananas, pepper, coffee, coconut and fruit trees are widely spaced, for intercropping with grass, and have been surrounded with live fences that also provide fodder for livestock to increase the family income. Each unit is operated by a selected employee and his family under a monthly incentive scheme based upon the gross margin. On these farms the technical parameters in dairying are better than elsewhere in the Mid-Country. Economic performance over 1985-1992 showed that dairying contributed most to the total gross margin of the half, one and two acre units, i.e. 31, 63 and 69%, respectively. Next came crops (29%, 37% and 19%), poultry (22%, 0% and 9%), and goats (18%, 0% and 3%). In the three farms the cash income per Sri Lankan Rupee spent was 1.5, 4.6 and 2.1, respectively. The overall ratio was 3.2 for dairying, 1.1 for poultry, 4.5 for goats and 9.9 for crops. Actual family labour in the three farms was 548, 548 and 639 days, compared to the 270, 330 and 440 days anticipated in the initial feasibility study. The average incentive payments, which were 20% (half acre), 61% (one acre) and 133% (two acres) of the parastatal salary of the employee, were only insufficient for the extra labour applied in the half acre unit. Dairying and goats proved to be attractive cash earners with a domestic fuel were important benefits. Poultry did little to improve farm income.

A Deterministic Safety Assessment of a Pyro-processed Waste Repository (A-KRS 처분 시스템 결정론적 안전성 평가)

  • Lee, Youn-Myoung;Jeong, Jongtae;Choi, Jongwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.10 no.3
    • /
    • pp.171-188
    • /
    • 2012
  • A GoldSim template program for a safety assessment of a hybrid-typed repository system, called "A-KRS," in which two kinds of pyro-processed radioactive wastes, low-level metal wastes and ceramic high-level wastes that arise from the pyro-processing of PWR nuclear spent fuels are disposed of, has been developed. This program is ready both for a deterministic and probabilistic total system performance assessment which is able to evaluate nuclide release from the repository and farther transport into the geosphere and biosphere under various normal, disruptive natural and manmade events, and scenarios. The A-KRS has been deterministically assessed with 5 various normal and abnormal scenarios associated with nuclide release and transport in and around the repository. Dose exposure rates to the farming exposure group have been evaluated in accordance with all the scenarios and then compared among other.