• Title/Summary/Keyword: Spectrum Charge

Search Result 174, Processing Time 0.026 seconds

Electronic Structures of Giant Magnetocaloric $Gd_5Si_2Ge_2$ Alloy

  • Rhee, Joo-Yull
    • Journal of Korean Vacuum Science & Technology
    • /
    • v.6 no.4
    • /
    • pp.153-157
    • /
    • 2002
  • The electronic structures of Gd$_{5}$Si$_2$Ge$_2$ compound, which has a giant magnetocaloric effect, in the monoclinic and orthorhombic phases were calculated using the tight-binding linear-muffin-tin-orbital method within the atomic-sphere approximation. The calculated total energies of the monoclinic and orthorhombic structures in the paramagnetic phase confirm that the orthorhombic structure is more stable than monoclinic structure. The density of states (DOS) at the Fermi level of the orthorhombic phase is higher than that of the monoclinic phase in the paramagnetic phase, fulfilling the Stoner criterion. The calculated charge density verified the breaking of Ge(Si)-Ge(Si) bonding in the basal plane upon the orthorhombic-monoclinic phase transition. The DOS curve fairly well reproduces the photoemission spectrum.m.

  • PDF

Synthesis of Host Polymers and Guests for Electrophosphorescence

  • Holmes Andrew B.;Chan, Khai-Leok;Cho, Sung-Yong;Evans Nicholas R.;Grimsdale Andrew C.;Mak Chris S.K.;Sandee Albertus J.;Watkins Scott E.;Williams Charlotte K.
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.21-22
    • /
    • 2006
  • Significant progress has been realized in the design and synthesis of light emitting polymers with emission over the whole range of the visible spectrum. However up to seventy-five percent of charge recombination events can lead to triplet states that decay non-radiatively. Following the pioneering work in the field of small molecule organic light emitting devices it has been found that solution processible iridium polymer complexes can be used to harness the wasted triplet energy. In this paper new results concerning electrophosphorescence of solution processible tethered iridium polymer derivatives will be presented. Furthermore our approaches to the design of new high triplet energy conjugated polymer hosts will be reported.

  • PDF

A Study on Dot-Matrix Display using Powder Electroluminescent Device with High Brightness (고휘도 후막 전계발광소자을 이용한 Dot-Matrix Display에 대한 연구)

  • Lee, Jong-Chan;Park, Dae-Hee
    • Proceedings of the KIEE Conference
    • /
    • 1998.07d
    • /
    • pp.1255-1257
    • /
    • 1998
  • In this study,$ 5{\times}5$ dot-matrix display was implemented with powder electroluminescent device (PELD). Generally PELD which have a luminance from powder phosphor with electric field, inserted phosphor and dielectric layer between electrodes is basic structure. To make high brightness PELD compared to conventional device, new type of PELD was proposed as follows. New PELD had only one layer, which was mixed phosphor (ZnS:Cu) and dielectric (BaTiO3) material appropriately between electrodes. To compare and estimate the conventional and new type of PELD, the EL spectrum, transferred charge density, brightness and decay time was measured. As above result, we fabricated a hish brightness $ 5{\times}5$ dot-matrix display with new type of PELD. Its brightness was 6400 $cd/m^2$ at 200 V, 400Hz.

  • PDF

Synthesis of Host Polymers and Guests for Electrophosphorescence

  • Watkins Scott E.;Chan, Khai Leok;Cho, Sung-Yong;Evans Nicholas R.;Grimsdale Andrew C.;Holmes Andrew B.;Mak Chris S.K.;Sandee Albertus J.;Williams Charlotte K.
    • Macromolecular Research
    • /
    • v.15 no.2
    • /
    • pp.129-133
    • /
    • 2007
  • Significant progress has been realized in the design and synthesis of light emitting polymers that emit over the entire visible spectrum. However, up to seventy-five percent of charge recombination events can lead to triplet states that decay non-radiatively. Following the pioneering work in the field of small molecule organic light emitting devices, it has been found that solution processible iridium polymer complexes can be used to harness the wasted triplet energy. In this paper, new results with respect to the electrophosphorescence of solution processible tethered iridium polymer derivatives are presented. Furthermore, our approaches to the design of new high triplet energy conjugated polymer hosts are also reported.

A Study on Powder Electroluminescent Device through Structure and Thickness Variation (구조 및 두께 변화에 따른 후막 전계 발광소자에 관한 연구)

  • 오주열;정병선;이종찬;박대희
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
    • /
    • 1998.11a
    • /
    • pp.9-11
    • /
    • 1998
  • A phenomenon of electroluminescent radiate as electric field applied in the phosphor, in this paper, we produced the Powder Electroluminescent Device(PELD) which was changing the structure and the thickness of phosphor and insulator for realization of the PELD with high brightness. We made PELD with structure that is WK-1(ITO film/Phosphor/Insulator/Electrode), WK-2(ITO film/Phosphor/Insulator/Electro de), WK-3(ITO film/Phosphor/Insulator/Electrode), WK-4(ITO film/Phosphor+Insulator/ Electrode). The property of the produced PELD are analyzed by measuring the spectrum which electrical and optical property, the brightness and the transferred charge density. In this result, the structure of WK-4 have good luminescence property than others, it's effective thickness is 60${\mu}{\textrm}{m}$. At 100V 400Hz, High brightness of 2700cd/m2 was performed.

  • PDF

Development of data acquisition and analysis program modules for leakage current of polymeric insulators using the Labview software (Labview를 이용한 배전용 폴리머애자의 누설전류 측정 및 분석 프로그램 개발)

  • Cho, Seong-Soo;Han, Sang-Ok
    • Proceedings of the KIEE Conference
    • /
    • 2000.07c
    • /
    • pp.1969-1971
    • /
    • 2000
  • This paper presents a data acquisition and analysis program modules that has been developed using the Labview program. These program modules can use to acquire and analyze leakage current data of insulator under different contamination conditions. The experimental hardware made up salt fog chamber, AC/DC power supply, transducer (shunt resistor), measurement devices and PC with the GPIB (General Purpose Interface Bus). And analysis program modules can calculate pulse level count, accumulated charge, average leakage current, power spectrum, and harmonics. The result of applying these analytical program modules to polymeric insulator is available for evaluation of leakage current characteristic of outdoor insulators.

  • PDF

A Mossbauer Study on Al-Ferrite (Al-Ferrite의 Mossbauer 분광학적 연구)

  • 이충섭;주한식;이찬영;서정철
    • Journal of the Korean Magnetics Society
    • /
    • v.8 no.4
    • /
    • pp.198-202
    • /
    • 1998
  • We have studied $Al_xFe_{3-x}O_4$ produced by direct composition method using X-ray diffraction and Mssbauer spectroscopy. The cation distribution for $Al_xFe_{3-x}O_4$ was determined by the ratio of sub-spectra absorption area. The charge state of Fe atoms in octahedral site(B-site) is $Fe^{2.5+}$ based on electron hopping, $Fe^{2+}$$(Fe^{3+},Al^{3+})$ without dependency of substituted Al amounts.

  • PDF

The Study on Trapping Phenomena of Charge Carrier in Polymer (고분자내 케리아의 트랍핑 현상에 관한 연구)

  • 이덕출
    • 전기의세계
    • /
    • v.26 no.4
    • /
    • pp.68-72
    • /
    • 1977
  • The main purpose of this paper is to study on the nature of the traps in polymer. The polyethlene is typical of polymer material as to be selected for a sample. The current I$_{th}$ are obtained with an small external bias voltage from high density polyethylene which have been treated by the high-field application. Two peaks, P$_{1}$ and P$_{2}$ with maxima near 85.deg. C, respectively, appeared on the current I$_{th}$ spectrum. From the results of experiment, It is clear that The current I$_{th}$ arises from the drift, under the external field, of carriers released from the trap sites by the heating and the trap is surrounded by a potential barrier and trapping proceeds during the high-field treatment. The obtained results can suggest that polyethylene contains trap sites which have an important role in the electrical conduction and breakdown of polymeric materials.rials.

  • PDF

Properties of Powder Electroluminescent Device with $Y_2O_3 and BaTiO_3$ (유전체 종류에 따른 후막 전계발광(EL) 소자의 특성)

  • 이종찬;박춘배;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.11a
    • /
    • pp.582-585
    • /
    • 1999
  • Electroluminescence is occurred when phosphor is located in electric field. In this paper, we made powder electroluminescent device (PELD) with structured ITO film/Phosphor/Insulator/Silver paste. The transparent electrode was ITO film and green(2704-01) and orange(2702-02) and blue-preen(2703-01) were used as phosphor. The insulator was BaTiO$_3$ and $Y_2$O$_3$, bark electrode was silver paste. To investigate electrical and optical properties of PELDs, EL spectrum, Brightness . Transferred charge density using Sawyer-Towers circuit was measured.

  • PDF

A Study of Mg Capping Inside p-tert-butylcalix[4]arene Adsorbed on a Ge(100) Surface

  • Shin, Minjeong;Lee, Myungjin;Lee, Hangil
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.135-135
    • /
    • 2013
  • The electronic and adsorption structures of Mg and p-tert-butylcalix[4]arene (p-TBCA) adsorbed onto a Ge(100) surface under a variety of sample conditions were characterized using high-resolution photoemission spectroscopy (HRPES) and their corresponding DFT calculation results. Interestingly, after 0.10 ML p-TBCA molecules had been adsorbed onto a Ge(100) surface, subsequent adsorption of a small amount of metallic Mg (~0.10 ML) resulted in the formation of a capped structure inside the pre-adsorbed p-TBCA molecules. The adsorption structures resulting from further deposition of Mg (~0.50 ML) onto the Ge(100) surface were monitored based on the surface charge state and Mg 2s core level spectrum. Work function measurements clearly indicated the electronic structures of the Mg and p-TBCA adsorbed onto the Ge(100) surface. Moreover, we confirmed that three different adsorption structures are experimentally favorable at room temperature through DFT calculation results.

  • PDF