• 제목/요약/키워드: Spectrum Charge

검색결과 174건 처리시간 0.022초

3-성분 종입자법으로 제조된 ZnO-Varistor의 열화기구 (Degradation Mechanism of the ZnO-Varistor Fabricated with the content of a 3-Composition Seed grain)

  • 장경욱;박춘배;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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    • pp.97-100
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    • 1992
  • The Degradation mechanism of the ZnO-varistor fabricated with the content of a 3-Composition seed grain is discussed using the method of Thermally Stimulated Current (TSC). The spectra of TSC is measured in the temperature range of -130~270$^{\circ}C$ with a various forming electric fields E$\sub$f/, temperature T$\sub$f/ time tf, and a various rising rate of temperature. It is observed that there are appeared the peaks of ${\alpha}$, ${\alpha}$$_2$, ${\beta}$ and ${\gamma}$from high temperature in a TSC spectrum. It seems that ${\alpha}$$_1$ peak is due to thermal depolarization of donor ions forming the space charge in the depletion layer, and ${\alpha}$$_2$peak is due to the detrapping of trapped electrons in deep trap level of intergranular layer, and ${\beta}$ peak is due to the thermal exciting of carrier existing in the donor level of grain itself, and ${\gamma}$ peak is due to the thermal exciting of trapped carrier in all shallow trap site randomly distributed in the inner of sample and/or a intrinsic impurity existing in it.

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유근피(楡根皮)에 존재하는 matrix metalloproteinase-9 억제 물질의 분리 및 정제 (Separation and purification of substance having matrix metalloproteinase-9 inhibition effect in Ulmus davidiana Plancn. var. japonica Nakai)

  • 한기정;이광수;공광훈;조성희
    • 분석과학
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    • 제16권3호
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    • pp.179-184
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    • 2003
  • 극성이 다른 여러 가지 용매를 사용하여 느릅나무의 뿌리 껍질(이하 유근피)을 추출하였다. MeOH 추출물이 SK-Hep-1에서 분리된 matrix metalloproteinase-9(MMP-9)의 zymography에서 저해능을 나타내었다. 분리 정제한 물질의 분자량은 GC-MS spectrum에서 $M^+=281$인 것으로 나타났고 MMP-9의 활성은 $314.7{\mu}g/g$에서 47% 억제되는 것으로 나타났다. 그리고 SK-Hep-1 세포주는 $31.47{\mu}g/g$에서 60%의 생존율을 나타났다.

모의 GIS의 전기적 이상에 따른 방사전자파의 특성과 절연진단용 UHF 센서 설계 (Characteristics of Radiated Electromagnetic Waves in Model GIS with Electrical Trouble and Design of Insulted Diagnosis UHF Sensor)

  • 박광서
    • 조명전기설비학회논문지
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    • 제22권5호
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    • pp.47-52
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    • 2008
  • 본 논문에서는 모의 GIS 내부에 도전성 파티클, 미소돌기, 연면방전을 모의함으로 전하의 축적과 전계의 집중이 용이하도록 하여 부분방전을 모의하였다. 이때 부분방전 발생과 진전에 따른 방사전자파를 스펙트럼 분석기와 EMI EMC 측정용 안테나($30{\sim}2,000[MHz]$)를 사용하여 측정 분석하였다. 이러한 결과를 바탕으로 0.3[GHz]에서 1.7[GHz]대역에서 UHF법을 활용한 절연진단이 가능한 UHF 구형 센서를 설계하였다. 이러한 연구결과는 $SF_6$를 사용하는 실제 GIS 및 전력설비의 UHF 절연진단 시스템에 적용 가능한 UHF 진단센서로 활용할 수 있을 것이다.

$Y_2SiO_5$:Ce 청색 형광체의 표면 코팅에 따른 음극선 발광특성 (The Cathodoluminance Properties of $Y_2SiO_5$:Ce Blue Phosphor with Surface Coatings)

  • 음현중;김성우;이임렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.590-593
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    • 1999
  • $Y_2SiO_5$:Ce was considered as blue phosphor for field emission display because it had an excellent resistance against brightness saturation. But unfortunately It hadn't a sufficient brightness to be applied to FED. In this experiment It-$In_2O_3$, MgO and $SiO_2$ were coated onto $Y_2SiO_5$:Ce phosphor in order to improve the cathodoluminance(CL properties. The coating structures were identified to be the crystalline phases of $In_2O_3$ and MgO respectively. They had fine particle-like shape and were distributed on the surface of $Y_2SiO_5$:Ce phosphor. It was found that the CL efficiency of $Y_2SiO_5$:Ce phosphors were decreased after coatings with In20:j and MgO in voltage range from 500 V to 5 kV. But the brightness of $Y_2SiO_5$:Ce phosphor was increased after coating of 5 0 2 . And also the aging test showed that $In_2O_3$ coating improved the life time of $Y_2SiO_5$:Ce phosphor.

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Interactions of Cationic Drugs and Cardiac Glycosides at the Hepatic Uptake Level: Studies in the Rat in Vivo, Isolated Perfused Rat Liver, Isolated Rat Hepatocytes and Oocytes Expressing oatp2

  • Dirk K.F.Meijer;Jessica E.van Montfoort
    • Archives of Pharmacal Research
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    • 제25권4호
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    • pp.397-415
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    • 2002
  • This paper deals with a crucial mechanism for interaction of basic drugs and cardiac glycosides at the hepatic uptake level. Available literature data is provided and new material is presented to picture the differential transport inhibition of bulky (type2) cationic drugs by a number of cardiac glycosides in rat liver. It is shown that the so called organic anion transporting peptide 2 (oatp2) is the likely interaction site: differential inhibition patterns as observed in oocytes expressing oatp2, could be clearly identified also in isolated rat hepatocytes, isolated perfused rat liver and the rat in vivo. The anticipation of transport interactions at the hepatic clearance level should be based on data on the relative affinities of interacting substrates for the transport systems involved along with knowledge on the pharmacokinetics of these agents as well as the chosen dose regimen in the studied species. This review highlights the importance of multispecific tranporter systems such as OATP, accommodating a broad spectrum of organic compounds of various charge, implying potential transport interactions that can affect body distribution and organ clearance.

Efficiency Factors of Singlet Oxygen Generation from Core-Modified Expanded Porphyric : Tetrathiarubyrin in Ethanol

  • 하정현;정국영;김민선;이양훈;신구;김용록
    • Bulletin of the Korean Chemical Society
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    • 제22권1호
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    • pp.63-67
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    • 2001
  • The photophysical properties and the singlet oxygen generation efficiency of tetrathiarubyrin have been investigated to elucidate the possibility of its use as a photodynamic therapy (PDT) photosensitizer by steady-state and time-resolved spectroscopic methods. The observed photophysical properties were affected by various molecular aspects, such as extended ${\pi}conjugation$, structural distortion, and internal heavy atom. The steady-state electronic absorption spectrum was red-shifted due to the extended $\pi-conjugation$, and the spin orbital coupling was enhanced by the structural distortion and the internal heavy atom effect. As a result of the enhanced spin orbital coupling, the triplet quantum yield increased to 0.90 $\pm$ 0.10 and the triplet state lifetime was shortened to 7.0 $\pm$ 1.2 ${\mu}s$. Since the triplet state decays at a relatively faster rate, the efficiency of the oxygen quenching of the triplet state decreases. The singlet oxygen quantum yield was estimated to be 0.52 $\pm$ 0.02, which is somewhat lower than expected. On the other hand, the efficiency of singlet oxygen generation during the oxygen quenching of triplet state, $f{\Delta}^T$, is near unity. Such high efficiency of singlet oxygen generation can be explained by the following two possible factors: The hydrogen bonding of ethanol which impedes the deactivation pathway of the charge transfer complex with oxygen to the ground state, the less probability of the aggregation formation.

Local Structure Refinement of the $BaFe_{1-x}Sn_xO_{3-y}$ System with Fe K-Edge X-Ray Absorption (XANES/EXAFS) Spectroscopy

  • 김민규;곽기섭;로권선;여철현
    • Bulletin of the Korean Chemical Society
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    • 제18권7호
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    • pp.743-749
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    • 1997
  • Local structure refinement of the BaFe1-xSnxO3-y system (x=0.00-0.50) has been carried out with Fe K-edge x-ray absorpion spectroscopic studies. It is found out that the Fe ions are placed in two different symmetric sites such as tetrahedral and octahedral sites in the compounds by comparison with Fe K-edge x-ray absorption near edge structure (XANES) spectrum of the γ-Fe2O3 compound as a reference. Small absorption peaks of dipole-forbiden transitions appear at a pre-edge region of 7111 eV due to the existence of Fe ions in the tetrahedral and octahedral sites. The peak intensity decreases with the substitution amount of Sn ion. Three different absorption peaks of 1s→4p dipole-allowed transition appear on the energy region between 7123 and 7131 eV. The peaks correspond to 1s→4p main transition of Fe ions in tetrahedral and octahedral sites and 1s→4p transition followed by the shakedown process of ligand to metal charge transfer. The bond distances between Fe ions in the tetrahedral site and nearest neighboring oxygen atom (Fe-4O), and those in octahedral site (Fe-6O) are determined with the extended x-ray absorption fine structure (EXAFS) analysis. Two different interatomic distances increase with the substitution amount of Sn ion and also the bond lengths of Fe-4O are shorter than those of Fe-6O in all compounds.

Shock-Resistance Responses of Frigate Equipments by Underwater Explosion

  • Kim, Hyunwoo;Choung, Joonmo
    • 한국해양공학회지
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    • 제36권3호
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    • pp.161-167
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    • 2022
  • Three-dimensional finite element analysis (3D-FEA) models have been used to evaluate the shock-resistance responses of various equipments, including armaments mounted on a warship caused by underwater explosion (UNDEX). This paper aims to check the possibility of using one-dimensional (1D) FEA models for the shock-resistance responses. A frigate was chosen for the evaluation of the shock-resistance responses by the UNDEX. The frigate was divided into the thirteen discrete segments along the length of the ship. The 1D Timoshenko beam elements were used to model the frigate. The explosive charge mass and the stand-off distance were determined based on the ship length and the keel shock factor (KSF), respectively. The UNDEX pressure fields were generated using the Geers-Hunter doubly asymptotic model. The pseudo-velocity shock response spectrum (PVSS) for the 1D-FEA model (1D-PVSS) was calculated using the acceleration history at a concerned equipment position where the digital recursive filtering algorithm was used. The 1D-PVSS was compared with the 3D-PVSS that was taken from a reference, and a relatively good agreement was found. In addition, the 1D-PVSS was compared with the design criteria specified by the German Federal Armed forces, which is called the BV043. The 1D-PVSS was proven to be relatively reasonable, reducing the computing cost dramatically.

Development and evaluation of a compact gamma camera for radiation monitoring

  • Dong-Hee Han;Seung-Jae Lee;Hak-Jae Lee;Jang-Oh Kim;Kyung-Hwan Jung;Da-Eun Kwon;Cheol-Ha Baek
    • Nuclear Engineering and Technology
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    • 제55권8호
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    • pp.2873-2878
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    • 2023
  • The purpose of this study is to perform radiation monitoring by acquiring gamma images and real-time optical images for 99mTc vial source using charge couple device (CCD) cameras equipped with the proposed compact gamma camera. The compact gamma camera measures 86×65×78.5 mm3 and weighs 934 g. It is equipped with a metal 3D printed diverging collimator manufactured in a 45 field of view (FOV) to detect the location of the source. The circuit's system uses system-on-chip (SoC) and field-programmable-gate-array (FPGA) to establish a good connection between hardware and software. In detection modules, the photodetector (multi-pixel photon counters) is tiled at 8×8 to expand the activation area and improve sensitivity. The gadolinium aluminium gallium garnet (GAGG) measuring 0.5×0.5×3.5 mm3 was arranged in 38×38 arrays. Intrinsic and extrinsic performance tests such as energy spectrum, uniformity, and system sensitivity for other radioisotopes, and sensitivity evaluation at edges within FOV were conducted. The compact gamma camera can be mounted on unmanned equipment such as drones and robots that require miniaturization and light weight, so a wide range of applications in various fields are possible.

가상 Frisch-그리드를 이용한 CdZnTe 감마선 소자 제작 (Fabrication of Virtual Frisch-Grid CdZnTe ${\gamma}$-Ray Detector)

  • 박찬선;김필수;조평곤;김정민;최종학;김기현
    • 대한방사선기술학회지:방사선기술과학
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    • 제37권4호
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    • pp.253-259
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    • 2014
  • Traveling heater method(THM) 방법을 이용하여 성장시킨 CdZnTe(CZT) 단결정 방사선 소자에 대한 고에너지(high energy) 감마선 에너지 분해능(energy resolution)을 평가하고자 $6{\times}6{\times}12mm^3$ 크기의 CZT 소자를 제작하였다. 두꺼운 방사선 소자의 경우, 전자에 비해 상대적으로 이동속도가 느린 정공(hole)으로 인해 발생하는 hole-tailing 효과가 심화되어 고에너지 영역의 에너지 분해능이 저하되는 현상이 발생한다. 전자(electron)와 정공(hole)의 두 개의 전하 운반자(charge carrier) 중에서 하나의 전하 운반자를 선택적으로 수집하여 에너지 분해능을 높이는 것이 가능하다. 가상 Frisch-그리드(virtual Frisch-grid) 소자는 소자 내부의 가중 퍼텐셜(weighting potential)을 조절하여 전자에 의한 유도전류(induced current)만을 선택적으로 이용하는 방법으로써 제작 과정과 적용이 용이하다. 본 연구에서는 THM 방법으로 성장한 큰 부피의 CZT 방사선 소자의 특성과 가상 Frisch-그리드의 효용성을 평가하였다. 가상 Frisch-그리드의 적절한 위치와 너비는 Maxwell ver.14(ANSYS, 미국)를 이용하여 모의실험으로 정하였다. $^{137}Cs$ 동위원소를 이용한 펄스 높이 스펙트럼(pulse height spectrum) 측정에서 가상 Frisch-그리드를 적용했을 때 662 keV 피크에 대해 2.2%의 에너지 분해능을 확인할 수 있었다.