• Nuclear Engineering and Technology
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• v.55 no.3
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• pp.1021-1030
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• 2023

We propose an overall procedure for measuring and unfolding fast neutron spectra using a trans-stilbene scintillation detector. Detector characterization was described, including the information on energy calibration, detector resolution, and nonproportionality response. The digital charge comparison method was used for the investigation of neutron-gamma Pulse Shape Discrimination (PSD). A pair of values of 600 ns pulse width and 24 ns delay time was found as the optimized conditions for PSD. A fitting technique was introduced to increase the trans-stilbene Proton Response Function (PRF) by 28% based on comparison of the simulated and experimental electron-equivalent distributions by the Cf-252 source. The detector response matrix was constructed by Monte-Carlo simulation and the spectrum unfolding was implemented using the iterative Bayesian method. The unfolding of simulated and measured spectra of Cf-252 and AmBe neutron sources indicates reliable, stable and no-bias results. The unfolding technique was also validated by the measured cosmic-ray induced neutron flux. Our approach is promising for fast neutron detection and spectroscopy.

• Journal of the Korean Magnetics Society
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• v.21 no.2
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• pp.56-60
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• 2011

Optical properties of $T_{0.2}Fe_{2.8}O_4$ (T = V, Cr, Mn) thin films derived from ferrimagnetic $Fe_3O_4$ were investigated by spectroscopic ellipsometry in the 1~8 eV photon-energy range. The difference in optical-absorption spectrum between the ternary compounds and $Fe_3O_4$ was analyzed based on preferable sites in spinel structure and iconicity of the doped V, Cr, and Mn ions. The observed absorption spectra from $Fe_3O_4$ and the ternary compounds can be interpreted as mainly due to charge-transfer transitions of Fe d electrons characterized by absorption structures with wide energy width. Also, the observed absorption structures with narrow energy width can be interpreted as due to crystal-field transitions between different d electron configurations of tetrahedral $Fe^{3+}(d^5)$ ion. The transitions were described in terms of spin-polarized electronic states of $Fe_3O_4$.

• Journal of Astronomy and Space Sciences
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• v.28 no.4
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• pp.273-284
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• 2011

A method of stellar source selection for validating the quality of image is investigated for a low Earth orbit optical remote sensing satellite. Image performance of the optical payload needs to be validated after its launch into orbit. The stellar sources are ideal source points that can be used to validate the quality of optical images. For the image validation, stellar sources should be the brightest as possible in the charge-coupled device dynamic range. The time delayed and integration technique, which is used to observe the ground, is also performed to observe the selected stars. The relations between the incident radiance at aperture and V magnitude of a star are established using Gunn & Stryker's star catalogue of spectrum. Applying this result, an appropriate image performance index is determined, and suitable stars and areas of the sky scene are selected for the optical payload on a remote sensing satellite to observe. The result of this research can be utilized to validate the quality of optical payload of a satellite in orbit.

• Journal of the Korean Chemical Society
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• v.24 no.6
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• pp.421-425
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• 1980

The EPR absorption of furan compounds adsorbed on CuY zeolite was studied. With the adsorption of furan on CuY a new high field having a width of 8 gauss and g-factor of 2.002 appeared in EPR spectrum, while the original signal of Cu(Ⅱ) decreased. When 2-methylfuran was adsorbed on Cu(15)Y a new absorption band with a hyperfine structure appeared. With the increase of the degree of Cu(Ⅱ) ion exchange the resolution of the hyperfine structure became poor. The appearance of the new band was interpreted in terms of the formation of a charge transfer complex between Cu(Ⅱ) ion and the furan ring.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.579-581
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• 2004

Recently, claims have been made of the detection of 'warm-hot' gas in the intergalactic medium. Kaastra et al. (2003) claimed detection of ${\~} 10^6$ K material in the Coma Cluster but studies by Arnaud et al. (2001), and our analysis of the Chandra observations of Coma (Vikhlinin et al. 2001), find no evidence for a $10^6$ K gas in the cluster. Finoguenov et al. (2003) claimed the detection of $3 {\times} 10^6$ gas slightly off-center from the Coma Cluster. However, our analysis of ROSAT data from this region shows no excess in this region. We propose an alternative explanation which resolves all these conflicting reports. A number of studies (e.g. Robertson et al., 2001) have shown that the local interstellar medium undergoes charge exchange with the solar wind. The resulting recombination spectrum shows lines of O VII and O VIII (Wargelin et al. 2004). Robertson & Cravens (2003) have .shown that as much as $25\%$ of the Galactic polar flux is heliospheric recombination radiation and that this component is highly variable. Sporadic heliospheric emission could account for all the claims of detections of 'warm-hot' gas and explain the conflicts cited above.

• Bulletin of the Korean Chemical Society
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• v.25 no.2
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• pp.298-300
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• 2004

An alternative molecular porphyrin-phthalocyanine aggregate was prepared and characterized with UV-visible and X-ray absorption spectroscopies. UV-visible experiments evidence 1-dimensional porphyrin-phthalo-cyanine array formed by mixing $SnTPPCl_2 ({\lambda}_{max}=429,\;{\varepsilon}=2.4{\times10^ 5 /M{\cdot}cm)\;and\;NiPc(OBu)_8({\lambda}_{max}=744 nm,\;{\varepsilon}= 2.0{\times}10^ 5 /M{\cdot}cm)$ in solution. In the UV-visible spectrum of the porphyrin-phthalocyanine array, $(SnPNiPc)_n$, a new Q-band appeared at 844 nm with decrease of the Q-band peak of $NiPc(OBu)_8$ at 744 nm. The red-shift of Q-band evidences an alternative porphyrin-phthalocyanine array formed in solution through metal-halide interaction rather than ${\pi}-{\pi}$ facial interaction, in which nickel of $NiPc(OBu)_8$ coordinates with chloride of $SnTPPCl_2$ through self assembly. Ni K-edge XANES (X-ray absorption near edge structure) spectra also support the axial ligation of nickel to chloride. The square planar structure of $NiPc(OBu)_8$ turns to an octahedral structure in (SnPNiPcSnP) by axial ligation. A higher energy-shift (0.2 eV) of the preedge peak of (SnPNiPcSnP) indicaties partial oxidation of nickel by charge transfer from NiPc$(OBu)_8$ to SnTPPCl$_2$.

• Journal of Sensor Science and Technology
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• v.25 no.4
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• pp.264-270
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• 2016

Self-powered neutron detector (SPND) is a sensor to monitor a neutron flux proportional to a reactor power of the nuclear power plants. Since an SPND is usually installed in the reactor core and does not require additional outside power, it generates electrons itself from interaction between neutrons and a neutron-sensitive material called an emitter, such as rhodium and vanadium. This paper presents the simulations of the depletion sensitivity evaluations based on MCNP models of rhodium and vanadium SPNDs and light water reactor fuel assembly. The evaluations include the detail geometries of the detectors and fuel assembly, and the modeling of rhodium and vanadium emitter depletion using MCNP and ORIGEN-S codes, and the realistic energy spectrum of beta rays using BETA-S code. The results of the simulations show that the lifetime of an SPND can be prolonged by using vanadium SPND than rhodium SPND. Also, the methods presented here can be used to analyze a life-time of those SPNDs using various emitter materials.

• Proceedings of the KIEE Conference
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• 1998.07d
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• pp.1379-1381
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• 1998

Powder electroluminescent device (PELD) structured conventionally dielectric and phosphor layer, between electrode and their layer fabricated by screen printing splaying or spin coating method. To promote performance of PELDs, we approached the experiments for different structure and thickness variation of PELD. Thickness variation($30{\mu}m{\sim}130{\mu}m$) was taken. To investigate electrical and optical properties of PELDs, EL spectrum, transferred charge density using Sawyer-Tower's circuit brightness was measured. Variation of structure in PELDs was as follows: WK-1 (ITO/BaTiO3/ZnS:Cu/Silver paste), WK-2 (ITO/BaTiO3/ZnS:Cu/BaTiO3/ZnS:Silver paste), WK-3 (ITO/BaTiO3/ZnS:Cu/BaTiO3/Silver paste), WK-4(ITO/BaTiO3+ZnS:Cu/Silver paste) As a result, structure of the highest brightness appeared WK-4 possessed 60 ${\mu}m$ thickness. The brightness was 2719 cd/$m^2$ at 100V, 400Hz.

• Proceedings of the Korean Society of Medical Physics Conference
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• 2002.09a
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• pp.216-218
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• 2002

Fluence and LET spectrum for 290,400 MeV/u $\^$12/C and 400 MeV/u $\^$20/Ne beams have been measured by a $\Delta$E-E counter telescope. Total charge-changing cross sections are deduced from measured fluence. The measured cross sections agree with previous measurements, however, they are disagreement with a model calculation. To dose-averaged LETs, the model calculation can reproduce the measured LETs except for peak LETs at Bragg peak region.

• Journal of the Korean Chemical Society
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• v.45 no.6
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• pp.524-531
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• 2001

Micro-HPLC/IS/MS after solid phase extraction has been employed to enhance the accu-racy in the determination of toxic microcystins, such as microcystin-LR, -YR and -RR. The absorbance at 238 nm in HPLC/UV and characteristic spectra of 135 m/z and $[M+H]^+$ m/z in MS have been widely monitored to identify those microcystin-LR, -YR and -RR. In this study, new lines at 507 m/z for LR, 520 m/z for RR and 532 m/z for YR have been additionally detected in the micro-HPLC/IS/MS spectrum, corresponding to double charge. The micro-HPLC/IS/MS methodology has been applied to investigate the presence of the toxic microcystins in Taecheong lake.