• Title/Summary/Keyword: Spectroscopic studies

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Kinetic Studies of Aggregation of 3,3'-Dipropyl oxacarbocyanine onto Poly(styrenesulfonate) (Poly(styrenesulfonate) 용액에서 3,3'-Dipropyl oxacarbocyanine 색소분자의 회합현상에 대한 반응속도론적 연구)

  • Lee, Hong;Lim, Eun Suk;Pae, Hyun-Ock
    • Journal of the Korean Chemical Society
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    • v.39 no.8
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    • pp.604-610
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    • 1995
  • The interaction between 3,3'-dipropyl oxacarbocyanine and poly(styrenesulfonate) has been studied by means of absorption and fluorescence spectroscopic methods. The results was interpreted by stacking model. The kinetic studies of the interaction between 3,3'-dipropyl oxacarbocyanine and poly(styrenesulfonate) were carried out by the absorption and fluorescence spectroscopic stopped-flow methods. The observed relaxation effect in DPC-PSS system was described quantitatively by assuming two relaxation processes. The dependence of rate of reaction on the salt concentration of the solution was also studied. The results are consistent with the two-step mechanism.

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Photometric Reverberation Mapping of Active Galactic Nuclei with Medium-band filters and LSGT

  • Kim, Joonho;Im, Myungshin;Choi, Changsu
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.73.1-73.1
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    • 2017
  • Reverberation mapping is one of the best way to investigate structure and kinematics of broad-line regions around central supermassive black holes of active galactic nuclei (AGN). It is usually used to estimate masses of supermassive black holes. So far, reverberation mapping studies have achieved good results for dozens of AGN by spectroscopic monitoring. However, spectroscopic monitoring is time consuming and high cost. Here, we present result of photometric reverberation mapping with medium-band observation. We monitored five nearby AGN which are already studied, have short time-lag, and show bright H-alpha emission lines. Observation has been performed for ~3 months with ~3 days cadence using three medium-band filters installed in LSGT (Lee Sang Gak Telescope). We found 0.01-0.06 magnitude variations by differential photometry. Also time-lags between continuum light-curves and H-alpha emission line light-curves are calculated using Javelin software. The result shows that our study and previous studies are consistent within uncertainty range. From verification of availability in this study, photometric reverberation mapping could be used as a powerful tool to measure central supermassive black holes for large samples and high-redshift AGN in the future.

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Raman Spectroscopic Studies of $YBa_2Cu_3O_7$ Coated Conductors ($YBa_2Cu_3O_7$ Coated Conductors의 Raman 분광학 연구)

  • ChoiD Mi Kyeung;Mnh Nguyen Van;Bae J. S.;JoD William;Yang In-Sang;Ko Rock-kil;Ha Hong Soo;Park Chan
    • Progress in Superconductivity
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    • v.6 no.2
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    • pp.95-98
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    • 2005
  • We present results of Raman spectroscopic studies of superconducting $YBa_2Cu_3O_7$ (YBCO) coated conductors. Raman scattering is used to characterize optical phonon modes, oxygen content, c-axis misalignment, and second phases of the YBCO coated conductors at a micro scale. A two-dimensional mapping of Raman spectra with transport properties has been performed to elucidate the effect of local propertied on current path and superconducting phase. The information taken from the local measurement will be useful for optimizing the process condition.

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Synthesis, Spectroscopic Studies and Biological Applications of Organotin(IV) Derivatives of 3-[N-(4-Nitrophenyl)-amido]propenoic Acid and 3-[N-(4-Nitrophenyl)-amido]propanoic Acid

  • Shahid, Khadija;Shahzadi, Saira;Ali, Saqib;Mazhar, M.
    • Bulletin of the Korean Chemical Society
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    • v.27 no.1
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    • pp.44-52
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    • 2006
  • New organotin(IV) derivatives with general formulae R_2SnL_2 and R_3SnL, where R = methyl, n-butyl, n-octyl and phenyl and HL is either 3-[N-(4-nitrophenyl)amido]-propenoic acid or 3-[N-(4-nitrophenyl)amido] propanoic acid have been synthesized in 1 : 2 and 1 : 1 molar ratio by different methods. The FTIR spectra clearly demonstrated that the organotin(IV) moieties react with [O,O] atoms of the ligands. The bonding and coordination behavior in these complexes are discussed on the basis of multinuclear (^1H,\,^{13}C,\,^{119}Sn) NMR and mass spectrometric studies. Antibacterial, and antifungal screening tests were performed for these compounds and reported here. These values were compared to those of the precursors and it was found that diorganotin(IV) complexes exhibit less activity as compared to triorganotin(IV) complexes . LD_{50} data were obtained by Brine Shrimp assay method. Insecticidal activity was performed for selective compounds by contact toxicity method.

Spectroscopic Characterization of Phosphorus Doped HPHT Diamond (인이 첨가된 고온 . 고압 다이아몬드의 분광학적 특성)

  • Chung Jung In;Kim Hee-Soo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.291-297
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    • 2004
  • Phosphorus is one of the interesting impurities in diamond, because it produces n-type semiconducting character. The character has been studied with spectroscopic methods as well as electric method, but most of the diamond used for these studies are conducted by the CVD (Chemical Vapor Deposition) diamond. In this study, we synthesized the phosphorus doped HPHT (High Pressure and High Temperature) diamond and investigated the characterization using CL spectroscopy to determine how phosphorus incorporated. As a result, the undocumented peaks of 248 and 603 nm as well as the reported peaks (239 nm, 240 ~ 270 nm) at the previous studies were observed. These luminescence peaks may be due to the complex defect of phosphorus with other impurities such as boron and nitrogen.

Absorption and Fluorescence Spectroscopic Behavior of Thionine in the Presence of Sodium Dodecyl Sulfate (Sodium Dodecyl Sulfate 존재하에서 Thionine의 흡수 및 형광분광학적 성질)

  • Seong Gwan Kang;Chong Hoe Park;Minjoong Yoon
    • Journal of the Korean Chemical Society
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    • v.38 no.12
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    • pp.857-863
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    • 1994
  • The absorption and fluorescence spectroscopic studies on the interaction between thionine (TH) and sodium dodecyl sulfate (SDS) have been carried out. The absorption and fluorescence spectral changes of TH with the changes of concentration of SDS are interpreted in terms of i) the aggregation of TH-SDS complex, ii) the stacking process of dye molecules by the association of the TH-SDS complex, iii) breakdown of the stacking due to the formation of dye-rich induced micelles, iv) redistribution of dye molecules in the surface of SDS micelles.

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Convolution and Deconvolution Algorithms for Large-Volume Cosmological Surveys

  • Park, KeunWoo;Rossi, Graziano
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.50.4-51
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    • 2015
  • Current and planned deep multicolor wide-area cosmological surveys will map in detail the spatial distribution of galaxies and quasars over unprecedented volumes, and provide a number of objects with photometric redshifts more than an order of magnitude bigger than that of spectroscopic redshifts. Photometric information is statistically more significant for studying cosmological evolution, dark energy, and the expansion history of the universe at a fraction of the cost of a full spectroscopic survey, but intrinsically carries a bias due to noise in the distance estimates. We provide convolution- and deconvolution-based algorithms capable of removing this bias -- thus able to exploit the full cosmological information -- in order to reconstruct intrinsic distributions and correlations between distance-dependent quantities. We then show some direct applications of our techniques to the VIMOS Public Extragalactic Redshift Survey (VIPERS) and the Sloan Digital Sky Survey (SDSS) datasets. Our methods impact a broader range of studies, when at least one distance-dependent quantity is involved; hence, they will be useful for upcoming large-volume surveys, some of which will only have photometric information.

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AKARI INFRARED CAMERA SURVEY OF THE LARGE MAGELLANIC CLOUD

  • Shimonishi, T.;Kato, D.;Ita, Y.;Onaka, T.;AKARI/IRC LMC team
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.83-85
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    • 2017
  • We conducted an unbiased near- to mid-infrared imaging and spectroscopic survey of the Large Magellanic Cloud (LMC) as a part of the AKARI Mission Program "Large-area Survey of the LMC" (LSLMC, PI: T. Onaka). An area of about 10 square degrees of the LMC was observed by five photometric bands (3.2, 7, 11, 15, and $24{\mu}m$) and a low-resolution slitless prism ($2-5{\mu}m$, R ~20) equipped with AKARI /IRC. We constructed and publicly released photometric and spectroscopic catalogues of point sources in the LMC based on the survey data. The catalogues provide a large number of near-infrared spectral data, coupled with complementary broadband photometric data. Combined use of the present AKARI LSLMC catalogues with other infrared point source catalogues of the LMC possesses scientific potential that can be applied to various astronomical studies.

A New Alkyl Alcohol Glycoside from Chrysanthemi Flos (감국(Chrysanthemi Flos)의 새로운 알킬알콜배당체 성분에 관한 연구)

  • Jung, Keun-Young;Oh, Sei-Ryang;Kim, Chun-Suk;Kim, Jung-Hee;Lee, Hyeong-Kyu
    • Korean Journal of Pharmacognosy
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    • v.27 no.1
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    • pp.15-19
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    • 1996
  • In the course of phytochemical studies of Chrysanthermi Flos(Chrysanthemum indicum L., Compositae), two compounds were isolated by repeated column chromatography. Compound 1 is identified as adenosine on the basis of spectroscopic means and comparison with an authentic standard. Compound 2 is determined to be a new alkyl alcohol glycoside, 1-octen-3-ol $3-O-{\beta}-D-xylopyranosyl(1{\rightarrow} 6)-{\beta}-D-glucopyranoside$ on the spectroscopic evidence. Compounds 1 and 2 are reported for the first time from this plant.

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Growth studies of chromium thin films using real-time spectroscopic ellipsometry (실시간 분광 엘립소미트리를 이용한 크롬 박막의 성장연구)

  • 이용달;정지용;방경윤;오혜근;안일신
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.327-332
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    • 1999
  • High speed real-time spectroscopic ellipsometry was employed in order to characterize the growth of chromium thin film. This instrument can collect 512 points of {$\Delta$(hv), $\Psi$(hv)} spectra from 1.3 to 4.5 eV with acquisition and repetition rates of 20 msec or less. When this instrument was integrated into the chromium thin film growth, we could obtain not only the information on film properties but also the details of the processes. We deduced the growth rates and the evolution of the optical properties of chromium thin films under several preparation conditions. We also demonstrated the contamination process of chromium thin films caused by air exposure.

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