• Title/Summary/Keyword: Spectroscopic method

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ESTIMATION OF NITROGEN-TO-IRON ABUNDANCE RATIOS FROM LOW-RESOLUTION SPECTRA

  • Kim, Changmin;Lee, Young Sun;Beers, Timothy C.;Masseron, Thomas
    • Journal of The Korean Astronomical Society
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    • v.55 no.2
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    • pp.23-36
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    • 2022
  • We present a method to determine nitrogen abundance ratios with respect to iron ([N/Fe]) from molecular CN-band features observed in low-resolution (R ~ 2000) stellar spectra obtained by the Sloan Digital Sky Survey (SDSS) and the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST). Various tests are carried out to check the systematic and random errors of our technique, and the impact of signal-to-noise (S/N) ratios of stellar spectra on the determined [N/Fe]. We find that the uncertainty of our derived [N/Fe] is less than 0.3 dex for S/N ratios larger than 10 in the ranges Teff = [4000, 6000] K, log g = [0.0, 3.5], [Fe/H] = [-3.0, 0.0], [C/Fe] = [-1.0, +4.5], and [N/Fe] = [-1.0, +4.5], the parameter space that we are interested in to identify N-enhanced stars in the Galactic halo. A star-by-star comparison with a sample of stars with [N/Fe] estimates available from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) also suggests a similar level of uncertainty in our measured [N/Fe], after removing its systematic error. Based on these results, we conclude that our method is able to reproduce [N/Fe] from low-resolution spectroscopic data, with an uncertainty sufficiently small to discover N-rich stars that presumably originated from disrupted Galactic globular clusters.

Interaction of flavins and some alcohols on the molecular level

  • Yu, Byung-Sul;Chung, Hyun-Ho;Lee, Sang-Jong;Kim, Yang-Bae;Kim, Chong-Kook
    • Archives of Pharmacal Research
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    • v.4 no.1
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    • pp.43-51
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    • 1981
  • The effect of some alcohols on the riboflavin derivatives in non-polar solvent was studied by various spectroscopic method in order to support the view point that alcohol may directly interect with the isoalloxazine moiety of FAD, the coenzyme of D-amino-acid oxidase. The most possible association complex between alcohol and riboflavin is the 1:1 complex through the 2-C carbonyl function of the isollaxazine ring nd the hydroxyl proton of alcohol. It is appeared that methanol has a larger association constant than any other alcohols, and the association constant decreases with the carbon number increases and being bulkier in the alkyl group of alcohols.

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Crystallographic and Spectroscopic Characterization of Talc proposed Mineral Carbonation after Heat Treatment (탄산염광물화용 활석의 열처리에 따른 결정학적 분광학적 특성변화)

  • Choi, Weon-Kyung;Cho, Tae-Hwan;Lee, Jae-Keun
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.109-116
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    • 2006
  • The heat treatment characteristics of natural talc sample was investigated in diverse analytical view point. The mass decrease comes to heat treatment was resulted by the continuous and the discontinuous process and the obtained result show very similar two step profiles with 8.9 % mass decrease. The dehydroxylation of -OH groups contained talc crystal was analyzed by spectroscopic method and the crystallographic variations was also observed after heat treatment. According to XPS result, the magnesium hydroxide($Mg(OH)_2$) of untreated talc powder changed to magnesium oxides(MgO) after heat treatment.

CRT Color Transform to CIELab Color System using RGB Image Data (RGB 화상테이터를 이용한 CRT 표현색의 CIELab 표색계로의 변화에 관한 연구)

  • 안석출
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.1
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    • pp.73-91
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    • 1995
  • Spectroscopic and Photoelectric Characteristics in the Cyanine and Merocyanine Dye according to systematically change of their structures were experimentally discussed. As result, in solution, Hetero atoms(X) of Cyanine and Merocyanine dye were participated in resonance X of d obital rather than X of pobital,effected in resonance and contributed in extension of conjugated system. in solid film,new spectra,called eximer-fluorenscence,were appeared in 3-dimensional fluorenscence of high density of Cyanine dye but not of Merocyanine. The activational energy of conductivity in Merocyanine dye was lower than in cyanine, an the contrary,the drift mobility was higher and the former in photoelectric characteristics was more effec-tive than the latter. In this paper,authors invertigated the changes of dye structure by molecular obital method to confirm the results of spectroscopic and photoelectric characteristics in the Cyanine and Merocyanine Dye acco-rding to systematically cally change of their structure, and counted total energy on dihedral angle and dipol miments if dyes in S0 and S1.

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Rapid Determination of Ascorbic Acid in Red Pepper Leaves by Near-Infrared Reflectance Spectroscopic Analysis (근적외 분광분석법에 의한 고춧잎의 Ascorbic Acid 함량 측정)

    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.3
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    • pp.393-398
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    • 1998
  • The loss of ascorbic acid in dried red pepper leaves prepare with different drying methods of air-, oven-, microwave oven-, and vacuum drying with blanching or without was determined by a HPLC method. Vacuum drying showed the least loss of ascorbic acid than the other drying methods. Additionally, the feasibility of near infrared reflectance spectroscopy(NIRS) to determine the contents of ascorbic acid in the red pepper leaves was studied. NIRS was found to be an efficient way of determining ascorbic acid contents in red pepper leaves, requiring only 30 seconds of an analytical time.

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Characterization of Humic and Fulvic Acids Extracted at the Soils of Korea and Its DB Establishment (국내 토양 휴믹물질의 특성 규명 및 DB 구축에 대한 연구)

  • 이창훈;유지호;신현상;정근호;이창우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.397-400
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    • 2003
  • In this study, humic and fulvic acids in soils at the vicinity of domestic atomic power plants(NPPs), located in Yungkwang(YK), Uljin(UJ), Kori(KR), Koseong(KS), Wolseong(WS) area, and in volcanic ash soils of the Cheju island(Mt. Hanla(HL), Manjanggul(MJ)) were isolated, and characterized using chemical(elemental analysis, proton exchange capacity, molecular size distribution) and spectroscopic(UV/Vis., IR, FL, $^{13}$ C NMR spectra) methods. The results were compared with one another and compiled for their DB establishments. The humic substances distribution (humic acid, fulvic acid, Humin) in the soils were also determined by IHSS standard method. Main purpose of this study was to provide a basic data needed to evaluate the effect of humic substances on the migrational behaviour of radioactive elements in contaminated surface soil.

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Spectroscopic Measurement of Temperature Distribution in Some Plasma Jets (분광학적 방법에 의한 Plasma Jet의 온도분석 측정)

  • 전춘생;박용관;임명선
    • 전기의세계
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    • v.26 no.2
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    • pp.104-110
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    • 1977
  • This paper investigates temperature distribution of plasma jets which used argon gas, and nitrogen gas mixed with argon as working fluids in spectroscopic method, and studies correlations between them main results are as follows; 1) The temperature at the center of plasma jet increases with are current and gas flow, and decreases with magnetic flux density along the axial direction. 2) The changing rate of temperature of plasma jet in the radial direction decreases rapidly beyond 2mm from central axis. 3) Temperature drop rate of plasma jet in the central axis direction appears most apparant beyond 13mm above the nozzle exit. 4) When argon gas mixed with a small amount of nitrogen, plasma temperature increases at same are current compared with the case of argon gas only.

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Synthesis of Iminoxyl Biradical and the Spectroscopic Study (Iminoxyl Biradical의 합성과 분광학적인 연구)

  • Jung-Sung Yang;Hee Ju Chae;Chul-Hyun Yo
    • Journal of the Korean Chemical Society
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    • v.25 no.1
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    • pp.13-20
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    • 1981
  • Iminoxyl biradical may be useful biradical spin probe for the investigation of the dynamic distribution of the directors in some liquid crystal. The iminoxyl biradical has been synthesized by a new convenient method and the intermediate products of each step were identified by the measurement of melting point and spectroscopic methods such as IR, UV, NMR and Mass spectrometry. The final product, iminoxyl biradical, was identified by the electron paramagnetic resonance spectroscopy and the interaction between two spins of the radical was discussed based on the EPR peaks.

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Evaporating Particle Behaviors and plasma Parameters by Spectroscopic Method in laser Welding (레이저 용접시 분광학적 수법에 의한 증발입자의 거동과 플라즈마 물성의 계측)

  • 김윤해
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.4
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    • pp.514-522
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    • 1999
  • The laser-induced plasma affects greatly on the results of welding process. moreover selective evaporation loss of alloying elements leads to change in chemical composition of weld metal as well as the mechanical properties of welded joint. this study was undertaken to obtain a fundamental knowledge of pulsed laser welding phenomena especially evaporation mechanism of different aluminum alloys. The intensities of molecular spectra of AlO and MgO were different each other depeding on the power density of a laser beam Under the low power density condition the MgO band spectrum was predominant in intensity while the AlO spectra became much stronger with an increase in the power density. These behaviors have been attributed to the difference in evaporation phenomena of Al and Mg metals with different boiling points and latent heats of vaporization. The time-averaged plasma temperature and electron number density were determined by spectroscopic methods and consequently the obtained temperature was $3,280{\pm}150K$ and the electron number density was $1.85{\times}10^{19}\;l/m^3$.

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Spectroscopic study of Planetary hosting star HD 20794

  • Rittipruk, Pakakaew;Yushchenko, Alexander V.;Kang, Young-Woon
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.43.4-44
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    • 2016
  • We observed the high resolution spectra of a solar-neighborhood planetary hosting star HD 20794. The analysis of spectroscopic data was performed using URAN and SYNTHE programs. These spectra allow us to determine the effective temperatures, surface gravities, microturbulent velocities and, chemical abundances. Bond et al. (2008) found chemical abundance for 11 elements, but using the Spectrum synthesis method we have so far determine about 30 elements. We have derived iron metallicity $[FeI/H]=-0.42{\pm}0.03$, $[FeII/H]=-0.43{\pm}0.012$, and surface gravity, log g = 4.48, in good agreement with values from previous investigation.

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