• 한국안광학회지
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• 제12권1호
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• pp.85-90
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• 2007

안경렌즈의 무반사 코팅물질로 사용되는 황화아연(Zinc Sulphide : ZnS)의 단일박막을 실리콘과 슬라이드 유리 기판위에 스핀코팅방법으로 증착하였다. 박막 증착 후 변입사각분광타원계(VASE : Variable Angle Spectroscopic Ellipsometer)를 사용하여 1.5~5.0 eV 광 에너지 영역에서 타원 각(ellipsometry angle) ${\Delta}$, ${\Psi}$를 측정하였다. 이 측정결과들을 Jellison Modine 분산관계식을 사용하여 최적맞춤하고, 매개변수들을 구하여 박막의 광학상수인 굴절계수 $n({\lambda})$와 소광계수 $k({\lambda})$를 결정하였다.

• 분석과학
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• 제5권4호
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• pp.455-464
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• 1992

본 논문에서는 FT-IR 분광분석법을 이용하여 여러 가지 반응조건에서 기체상 silylation 반응에 의해 생성된 silylated layer의 depth를 비파괴적으로 정량하는 방법을 제안하였다. Silylated layer의 depth는 FT-IR 스펙트럼의 특성 봉우리들(Si-O-ph, Si-C, Si-H)의 흡광도를 바탕 스펙트럼 공제법으로 측정하여 SEM의 두께 측정치와 비교하여 정량하였다. FT-IR 분광분석법을 이용한 Silylated layer의 depth 분석은 비파괴적이고 정량적인 방법으로, 이 방법은 silylation process window를 설정하는 데 적합하다는 것을 알았다.

• 대한의용생체공학회:학술대회논문집
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• 대한의용생체공학회 1997년도 춘계학술대회
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• pp.303-308
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• 1997

In this paper, we analyzed the spectroscopic properties of strip to analyzer urine qualitatively & quantitatively and make urine analyzer system stable by spectroscopy, and research the property of preamplifier unit. The analysis of spectroscopic properties of 10 pads in the strip is used for determine the wave length of light source of optic detector unit and used for basic materials which are necessary that we develop the algorithm analyzing the density grade of pad accurately. We make preamplifier unit by using the current to frequency method to measure the distribution of pad color. We implemented urine analyzer system. This system's hardware is composed of measuring unit for detect of distribution density of strip pad, main processing unit, communication unit, interface device, thermal printer, and indicator. The software consists of the program which manage the argument of test, proportion initial value of urine analyzer and calibrate analyzed result.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.73-73
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• 2010

Various organic- and bio-conjugated nanoparticles have been studied extensively for biological applications in medical diagnoses and drug delivery systems. Gold nanoparticles (AuNP) and poly(ethylene glycol) (PEG) are known biocompatible materials to be used in vivo and are becoming increasingly important in biomedical applications. In this work, we investigated the stability of PEG-conjugated AuNPs, dialysis and centrifuge effects after synthesis or pegylation of AuNPs as a function of elapsed time by using ToF-SIMS imaging technique along with dynamic light scattering (DLS), UV-visible absorption spectroscopic and statistical analyses. Roughly 15-nm-sized AuNPs were synthesized in a citrate-conjugated form, and then converted into the thiol-terminated PEG (O-[2-(3-Mercaptopropionylamino)ethyl]-O'-methylpolyethyleneglycol, M.W.=5 kDa) form. Based on our data, we will show that ToF-SIMS imaging analysis along with DLS, UV-visible absorption and statistical analyses would be a useful method to evaluate stability of PEG-conjugated AuNPs in various environmental conditions.

• Bulletin of the Korean Chemical Society
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• 제32권10호
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• pp.3650-3654
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• 2011

Two new unusual soyasaponins named 6"-O-methyldehydrosoyasaponin I(7) and desglucosylsoyasaponin $A_1$ (10) along with eight known saponins, dehydrosoyasaponin IV (1), dehydrosoyasaponin III (= impatienoside A) (2), soyasaponin III (3), dehydrosoyasaponin II (= soyasaponin Bg) (4), soyasaponin II (5), dehydrosoyasaponin I (= soyasaponin Be) (6), soyasaponin I (8), and kudzusaponin $SA_3$ (9), were isolated as their methyl esters and identified from the liquid culture of G. applanatum. Their structures were determined by chemical and spectroscopic analyses including 1D- and 2D-NMR as well as by comparison of their spectroscopic data with those of the reported in literatures. Although dehydrosoyasaponin IV was identified by LC-MS/MS method from soy protein isolate, this is the first report of the isolation of this compound. Dehydrosoyasaponin III (2) and kudzusaponin $SA_3$ (9) were also isolated for the first time from soybean. The presence of soyasaponins in Ganoderma species seems to be unusual feature. Thus, we presumed that compounds 1-10 might all be derived from the defatted soybean flour which was added to the culture medium as a nitrogen source.

• 천문학논총
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• 제30권2호
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• pp.443-445
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• 2015

We provide results of near-infrared (NIR) spectroscopic observations of 83 nearby (0.002< z <0.48) and bright (K <14 mag) type 1 active galactic nuclei (AGNs). For the observations, we used the Infrared Camera (IRC) on AKARI allowing us to obtain the spectrum in the rarely studied spectral range of $2.5-5.0{\mu}m$. The $2.5-5.0{\mu}m$ spectral region suffers less dust extinction than ultra violet (UV) or optical wavelength ranges, and contains several important emission lines such as $Br{\beta}$ ($2.63{\mu}m$), $Br{\alpha}$ ($4.05{\mu}m$), and polycyclic aromatic hydrocarbon (PAH; $3.3{\mu}m$). The sample is selected from the bright quasar surveys of Palomar Green and SNUQSO, and AGNs with black hole (BH) masses estimated from reverberation mapping method. We measure the Brackett line properties for 11 AGNs, which enable us to derive BH mass estimators and investigate circum-nuclear environments. Moreover, we perform spectral modeling to fit the hot and warm dust components by adding photometric data from SDSS, 2MASS, WISE, and ISO to the AKARI spectra, and estimate hot and warm dust temperatures of ~1100K and ~220 K, respectively.

• 한국광물학회지
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• 제17권4호
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• pp.291-297
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• 2004

인은 다이아몬드 내에 함유될 수 있는 흥미로운 불순물 중의 하나로서 n 타입의 반도체가 될 수 있다는 점에서 흥미롭다. 그러므로 전기적 특성 및 광학적 특성이 많이 연구되고 있지만, 대부분이 CVD (화학 기상합성) 다이아몬드에 관한 것이다. 본 연구에서는 인을 첨가한 HPHT (고압과 고온) 다이아몬드를 합성하고 인이 어떻게 함유되는가 알아보기 위하여 CL 분광기로 광학적 특성을 살펴보았다. 그 결과, 기존에 발견된 발광피크(239 nm, 240～270 nm)뿐만 아니라 248, 603 nm에서 새로운 발광피크가 발견되었다. 이러한 발광피크들은 인과 같이 혼입된 질소나 붕소와 같은 불순물이 공존하여 발생한 복합 결함에 의한 것이라고 판단된다.

• 분석과학
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• 제10권1호
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• pp.18-30
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• 1997

Si / Al비가 130 정도인 Na, TPA-ZSM-5를 저온 상압법으로 합성하였으며, 이들의 결정화 과정을 XRD, XRF, FT-IR, NMR 및 SEM을 이용하여 고찰하였다. 결정의 형성과정은 autoclave법과는 다소 다르게 나타났으나 최종 생성물의 분광학적 특성은 전형적인 ZSM-5 영역에서 나타났다. 또한 반응 도중 생성된 국부결함은 소성에 의해 제거됨을 알 수 있었으며, 저온상압하에서도 반응시간을 48시간 이내로 단축할 수 있음을 알 수 있었다.

• Journal of Biosystems Engineering
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• 제36권2호
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• pp.130-139
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• 2011

Three modes of VIS/NIR spectroscopic measurement (interactance and two modes of transmission) were compared for their ability to estimate soluble solids content (SSC) of 'Shingo' pear non-destructively. The two transmission modes are named as full- and semi-transmission, where full-transmission stands for passing of light through abdomen of pear and semi-transmission is for transit of light mainly through flesh of pear. For comparison of the modes, prediction models developed from the collected spectroscopic data by the three modes were developed and tested for comparison of their performance. Partial least square regression (PSLR) was used to develop the models and various pre-processing methods were applied to develop models of high accuracy. The experiment was repeated three times with pears produced in different regions. The experiments resulted that selection of pre-processing is very important to attain accurate models, and multiplicative scatter correction (MSC) was selected as a pre-processor of high accuracy for the three modes of spectroscopic measurement in every experiment. Except for MSC, different group of pre-processing methods were selected for the three modes of measurement in every experiment without any tendency to the tested modes of measurement and pears of different produced region. Root-mean-square error of prediction (RMSEP) of prediction models of the three modes of measurement using prepreocessor of MSC were compared for their ability to estimate SSC. The models resulted in ranges of $0.37{\sim}0.57^{\circ}Brix$, $0.65{\sim}0.72^{\circ}Brix$, $0.39{\sim}0.51^{\circ}Brix$ for interactance, full- and semi-transmission, respectively. As shown, modes of semi-transmission and interactance resulted about the same level of prediction accuracy and were noted as modes of high performance to predict SSC.

• 자원환경지질
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• 제49권5호
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• pp.335-347
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• 2016

정선 지역 고품위 석회석 광산인 강원, 충무 및 백운 광산을 대상으로 풍촌층 상부 층준의 대표적 탄산염암을 구분하고 각 유형의 전암 분석 및 VNIR-SWIR(visible near infrared-short wavelength infrared) 분광분석을 실시하여, 현장에서 고품위 석회석의 CaO 함량, 이질 불순물 및 백색도를 평가할 수 있는 분석법을 제시하였다. 동일 시료에서 분말 시료의 분광 반사도는 절단 시편에 비하여 매우 높은 분광 반사도를 보였고, 탄산염암의 분말 시료는 백색도와 분광 반사도가 0.99의 매우 높은 상관관계를 보이고 있다. 전암 분석에서 확인된 충무광산의 방해석과 백운석 분말 시료를 75:25, 50:50, 25:75 질량비로 혼합하여 각각 스펙트럼의 변화를 확인하고, 탄산염암의 CaO 함량과 흡수파장을 비교한 결과 0.98~0.99로 매우 높은 상관도를 보이고 있다. 탄산염암의 흡수파장과 화학조성은 2340 nm(55.86 wt.%)에서 2320 nm(29.71 wt.%)로 이는 $CO{_3}^{-2}$ 성분과 결합하고 있는 Ca 함량과 이를 치환하는 Mg 성분 함량의 차이에 따라 흡수 위치가 변화되는 것을 의미하며, 현장에서 분광분석을 통한 탄산염광물의 CaO 함량을 정량적으로 적용할 수 있다.