• Title/Summary/Keyword: Spectral studies

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Structural and Physicochemical Studies on DA-5018, a New Capsaicin Derivative (새로운 Capsaicin 유도체 DA-5018의 구조 및 물리화학적 성질 연구)

  • Kim, Heung-Jae;Lee, Jong-Jin;Lee, Eung-Doo;Shim, Hyun-Joo;Lee, Sang-Deuk;Ok, Kwang-Dae;Kim, Won-Bae;Park, No-Sang
    • Journal of Pharmaceutical Investigation
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    • v.27 no.2
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    • pp.119-123
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    • 1997
  • The physicochemical and structural properties of new capsaicin derivative, DA-5018, were examined. The reference standard of this compound was obtained by the recrystallization. A method for the determination of the dissociation constant of the compound is described. pH-solubility and distribution coefficient were determined by chromatographic method. Fundamental properties on thermal behaviors were investigated by TG, DTA and DSC. Structural analysis based on spectroscopic method coincided with the chemical structure of DA-5018. Approximate dissociation constant of the compound determined by UV spectral method was 9.35. Solubilities and partition coefficients in various pH buffer solution appeared pH-dependency. No crystal transition or further transition was found in the thermal analysis. This compound showed good stability, but pH 13 buffer and acetone made some degradative products.

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Filtered Coupling Measures for Variable Selection in Sparse Vector Autoregressive Modeling (필터링된 잔차를 이용한 희박벡터자기회귀모형에서의 변수 선택 측도)

  • Lee, Seungkyu;Baek, Changryong
    • The Korean Journal of Applied Statistics
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    • v.28 no.5
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    • pp.871-883
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    • 2015
  • Vector autoregressive (VAR) models in high dimension suffer from noisy estimates, unstable predictions and hard interpretation. Consequently, the sparse vector autoregressive (sVAR) model, which forces many small coefficients in VAR to exactly zero, has been suggested and proven effective for the modeling of high dimensional time series data. This paper studies coupling measures to select non-zero coefficients in sVAR. The basic idea based on the simulation study reveals that removing the effect of other variables greatly improves the performance of coupling measures. sVAR model coefficients are asymmetric; therefore, asymmetric coupling measures such as Granger causality improve computational costs. We propose two asymmetric coupling measures, filtered-cross-correlation and filtered-Granger-causality, based on the filtered residuals series. Our proposed coupling measures are proven adequate for heavy-tailed and high order sVAR models in the simulation study.

Performance of Overlay Cognitive Radio NOMA Systems with Selected Relay for Non-licensed Receiver (비면허 수신기를 위한 선택 릴레이를 갖는 오버레이 상황인지 NOMA 시스템의 성능)

  • Kim, Nam-Soo
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.19 no.5
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    • pp.39-45
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    • 2019
  • Recently, Cognitive radio (CR) has been focused for the effective utilization of the limited spectrum. Since an overlay CR system shares the given spectrum with the unlicensed system simultaneously, its spectral efficiency is high. However, most of the studies on an overlay CR system have been focused on the performance enhancement of the licensed receiver (LR). Correspondingly, the performance of the unlicensed receiver (UR) is degraded. Therefore, we propose an overlay CR NOMA system to improve the performance both of the LR and UR, which has a selected relay for the UR and adjusts the power allocation for the LR. The analytical performance of the proposed system is derived and verified the results through simulation. It is noticed that the UR can be obtained signal-to-noise ratio (SNR) gains by the selected relay, consequently, the system performance can be improved. Also, we show that the performance of the proposed system can be controlled by the number of the relays as well as the power allocation ratio. The results reveal that the required performance of the system can be satisfied with the use of the selected relay under the limited transmit power.

Ambient modal identification of structures equipped with tuned mass dampers using parallel factor blind source separation

  • Sadhu, A.;Hazraa, B.;Narasimhan, S.
    • Smart Structures and Systems
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    • v.13 no.2
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    • pp.257-280
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    • 2014
  • In this paper, a novel PARAllel FACtor (PARAFAC) decomposition based Blind Source Separation (BSS) algorithm is proposed for modal identification of structures equipped with tuned mass dampers. Tuned mass dampers (TMDs) are extremely effective vibration absorbers in tall flexible structures, but prone to get de-tuned due to accidental changes in structural properties, alteration in operating conditions, and incorrect design forecasts. Presence of closely spaced modes in structures coupled with TMDs renders output-only modal identification difficult. Over the last decade, second-order BSS algorithms have shown significant promise in the area of ambient modal identification. These methods employ joint diagonalization of covariance matrices of measurements to estimate the mixing matrix (mode shape coefficients) and sources (modal responses). Recently, PARAFAC BSS model has evolved as a powerful multi-linear algebra tool for decomposing an $n^{th}$ order tensor into a number of rank-1 tensors. This method is utilized in the context of modal identification in the present study. Covariance matrices of measurements at several lags are used to form a $3^{rd}$ order tensor and then PARAFAC decomposition is employed to obtain the desired number of components, comprising of modal responses and the mixing matrix. The strong uniqueness properties of PARAFAC models enable direct source separation with fine spectral resolution even in cases where the number of sensor observations is less compared to the number of target modes, i.e., the underdetermined case. This capability is exploited to separate closely spaced modes of the TMDs using partial measurements, and subsequently to estimate modal parameters. The proposed method is validated using extensive numerical studies comprising of multi-degree-of-freedom simulation models equipped with TMDs, as well as with an experimental set-up.

Temperature Correction of Solar Radiation on Clear Sky Using by Modified Pyranometer (특수일사계를 이용한 맑은 날 일사량의 온도 보정)

  • Zo, Il-Sung;Jeong, Myeong-Jae;Lee, Kyu-Tae;Jee, Joon-Bum;Kim, Bu-Yo
    • Journal of the Korean Solar Energy Society
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    • v.35 no.1
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    • pp.9-19
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    • 2015
  • Pyranometer have many uncertainty factors (sensitivity function, thermal offset, other spectral effect, geometric, environment, and equipment etc.) than pyrheliometer. The solution for most of the uncertainty factors have been researched, but the problem for thermal offset is being continued research so far. Under the clear sky, due to the thermal offset of pyranometer, the diffuse and global radiation have been negative value for the nighttime and lower value for the daytime, respectively. In order to understand the uncertainty of the thermal offset effect, solar radiation are observed and analyzed using Ji and Tsay method and data from modified pyranometer. As a result of performing temperature correction using the modified pyranometer, the slope (dome factor; k) and intercept ($r_0$) from a linear regression method are 0.064 and $3.457g{\cdot}m^{-2}{\cdot}k^{-1}$, respectively. And the solar radiation is decreased significantly due to the effect of thermal offset during nighttime. The solar radiation from modified pyranometer increased approximately 8% higher than its observed by general pyranometer during daytime. By the way, these results did not generalize because its result is for only single case in clear sky. Accordingly, it is to required for accurate results obtained by the various cases (clear, cloudy and rainy) with longterm observations.

One Year of GOCI-II Launch Present and Future (GOCI-II 발사 1년, 현재와 미래)

  • Choi, Jong-kuk;Park, Myung-sook;Han, Kyung-soo;Kim, Hyun-cheol;Im, Jungho
    • Korean Journal of Remote Sensing
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    • v.37 no.5_2
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    • pp.1229-1234
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    • 2021
  • GOCI-II, which succeeded the mission of GOCI, was successfully launched in February 2020 and is in operation. GOCI-II is expected to be highly useful in a wide range of fields, including detailed changes in the coastal seawater environment using improved spatial and spectral resolution, increased number of observation and full disk observation mode. This special issue introduces the assessment of the current GOCI-II data quality and the studies on the accuracy improvement and applications at this time of one year after launch and data disclosure. We expect that this issue can be an opportunity for GOCI-II data to be actively utilized not only in the ocean but also in various fields of land and atmosphere.

Case Study: Cost-effective Weed Patch Detection by Multi-Spectral Camera Mounted on Unmanned Aerial Vehicle in the Buckwheat Field

  • Kim, Dong-Wook;Kim, Yoonha;Kim, Kyung-Hwan;Kim, Hak-Jin;Chung, Yong Suk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.64 no.2
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    • pp.159-164
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    • 2019
  • Weed control is a crucial practice not only in organic farming, but also in modern agriculture because it can lead to loss in crop yield. In general, weed is distributed in patches heterogeneously in the field. These patches vary in size, shape, and density. Thus, it would be efficient if chemicals are sprayed on these patches rather than spraying uniformly in the field, which can pollute the environment and be cost prohibitive. In this sense, weed detection could be beneficial for sustainable agriculture. Studies have been conducted to detect weed patches in the field using remote sensing technologies, which can be classified into a method using image segmentation based on morphology and a method with vegetative indices based on the wavelength of light. In this study, the latter methodology has been used to detect the weed patches. As a result, it was found that the vegetative indices were easier to operate as it did not need any sophisticated algorithm for differentiating weeds from crop and soil as compared to the former method. Consequently, we demonstrated that the current method of using vegetative index is accurate enough to detect weed patches, and will be useful for farmers to control weeds with minimal use of chemicals and in a more precise manner.

Analysis of the Spectrum Characteristics of Etched Glass Surface by Incident Angle (입사각에 따른 에칭 기판의 분광특성분석)

  • Kim, Haemaro;Lee, Don-Kyu
    • Journal of IKEEE
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    • v.23 no.3
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    • pp.1077-1081
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    • 2019
  • Lights that enter the surface of a solar cell cannot be absorbed inside all of the solar cells, and some of it is reflected off the surface of the substrate, resulting in loss. Because of this, many studies are underway to reduce reflective losses on the surface of substrates or to steam the generated charge inside the solar cell. In this paper, surface treatment for forming a rough surface by wet etching the surface of a glass substrate is advanced, and structural characteristics of the rough surface are analyzed. Then, spectral characteristics by changing the angle of the glass substrate to which light enters the company are analyzed. When the light entering the company is investigated on a etched surface, it is confirmed that the probability of re-absorbing the light inside the glass substrate by multiple reflection is increased. When entering the light while changing the angle of the glass substrate, the transmission and reflection performance of the light are not changed.

Photoacoustic imaging of occlusal incipient caries in the visible and near-infrared range

  • da Silva, Evair Josino;de Miranda, Erica Muniz;de Oliveira Mota, Claudia Cristina Brainer;Das, Avishek;Gomes, Anderson Stevens Leonidas
    • Imaging Science in Dentistry
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    • v.51 no.2
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    • pp.107-115
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    • 2021
  • Purpose: This study aimed to demonstrate the presence of dental caries through a photoacoustic imaging system with visible and near-infrared wavelengths, highlighting the differences between the 2 spectral regions. The depth at which carious tissue could be detected was also verified. Materials and Methods: Fifteen permanent molars were selected and classified as being sound or having incipient or advanced caries by visual inspection, radiography, and optical coherence tomography analysis prior to photoacoustic scanning. A photoacoustic imaging system operating with a nanosecond pulsed laser as the light excitation source at either 532 nm or 1064 nm and an acoustic transducer at 5 MHz was developed, characterized, and used. En-face and lateral(depth) photoacoustic signals were detected. Results: The results confirmed the potential of the photoacoustic method to detect caries. At both wavelengths, photoacoustic imaging effectively detected incipient and advanced caries. The reconstructed photoacoustic images confirmed that a higher intensity of the photoacoustic signal could be observed in regions with lesions, while sound surfaces showed much less photoacoustic signal. Photoacoustic signals at depths up to 4 mm at both 532 nm and 1064 nm were measured. Conclusion: The results presented here are promising and corroborate that photoacoustic imaging can be applied as a diagnostic tool in caries research. New studies should focus on developing a clinical model of photoacoustic imaging applications in dentistry, including soft tissues. The use of inexpensive light-emitting diodes together with a miniaturized detector will make photoacoustic imaging systems more flexible, user-friendly, and technologically viable.

Packaging Design of EPS Cooling Box by Theoretical Heat Flow and Random Vibration Analysis (이론적 열유동 및 랜덤 진동 해석을 적용한 EPS 보냉용기의 포장설계)

  • Kim, Su-Hyun;Park Sang-Hoon;Lee, Min-A;Jung, Hyun-Mo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.3
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    • pp.175-180
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    • 2021
  • Although it has recently been regulated for use as an eco-friendly policy in Korea, the use of EPS (Expanded Polystyrene) cooling boxes, which are used as cold chain delivery insulation boxes for fresh agricultural and livestock products, is also increasing rapidly as e-commerce logistics such as delivery have increased rapidly due to COVID-19. Studies were conducted to optimize the EPS cooling container through internal air heat flow of CFD (Computational Fluid Dynamics) analysis and FEM (Finite Element Method) random vibration analysis using domestic PSD (Power Spectral Density) profile of the EPS cooling box to which the refrigerant is applied in this study. In the analysis of the internal air heat flow by the refrigerant in the EPS cooling box, the application of vertical protrusions inside was excellent in volume heat flow and internal air temperature distribution. In addition, as a result of random vibration analysis, the internal vertical protrusion gives the rigid effect of the cooling box, so that displacement and stress generation due to vibration during transport are smaller than that of a general cooling container without protrusion. By utilizing the resonance point (frequency) of the EPS cooling box derived by the Model analysis of ANSYS Software, it can be applied to the insulation and cushion packaging design of the EPS product line, which is widely used as insulation and cushion materials.