• Title/Summary/Keyword: Spectral studies

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Estimating Impervious Surface Fraction of Tanchon Watershed Using Spectral Analysis (분광혼합분석 기법을 이용한 탄천유역 불투수율 평가)

  • Cho Hong-lae;Jeong Jong-chul
    • Korean Journal of Remote Sensing
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    • v.21 no.6
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    • pp.457-468
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    • 2005
  • Increasing of impervious surface resulting from urban development has negative impacts on urban environment. Therefore, it is absolutely necessary to estimate and quantify the temporal and spatial aspects of impervious area for study of urban environment. In many cases, conventional image classification methods have been used for analysis of impervious surface fraction. However, the conventional classification methods have shortcoming in estimating impervious surface. The DN value of the each pixel in imagery is mixed result of spectral character of various objects which exist in surface. But conventional image classification methods force each pixel to be allocated only one class. And also after land cover classification, it is requisite to additional work of calculating impervious percentage value in each class item. This study used the spectral mixture analysis to overcome this weakness of the conventional classification methods. Four endmembers, vegetation, soil, low albedo and high albedo were selected to compose pure land cover objects. Impervious surface fraction was estimated by adding low albedo and high albedo. The study area is the Tanchon watershed which has been rapidly changed by the intensive development of housing. Landsat imagery from 1988, 1994 to 2001 was used to estimate impervious surface fraction. The results of this study show that impervious surface fraction increased from $15.6\%$ in 1988, $20.1\%$ in 1994 to $24\%$ in 2001. Results indicate that impervious surface fraction can be estimated by spectral mixture analysis with promising accuracy.

Connection of spectral pattern of carbohydrate molecular structure to alteration of nutritional properties of coffee by-products after fermentation

  • Samadi;Xin Feng;Luciana Prates;Siti Wajizah;Zulfahrizal;Agus Arip Munawar;Weixian Zhang;Peiqiang Yu
    • Animal Bioscience
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    • v.37 no.8
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    • pp.1398-1407
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    • 2024
  • Objective: The objective of this study was to determine internal structure spectral profile of by-products from coffee processing that were affected by added-microorganism fermentation duration in relation to truly absorbed feed nutrient supply in ruminant system. Methods: The by-products from coffee processing were fermented using commercial fermentation product, consisting of various microorganisms: for 0 (control), 7, 14, 21, and 28 days. In this study, carbohydrate-related spectral profiles of coffee by-products were correlated with their chemical and nutritional properties (chemical composition, total digestible nutrient, bioenergy values, carbohydrate sub-fractions and predicted degradation and digestion parameters as well as milk value of feed). The vibrational spectra of coffee by-products samples after fermentation for 0 (control), 7, 14, 21, and 28 days were determined using a JASCO FT/IR-4200 spectroscopy coupled with accessory of attenuated total reflectance (ATR). The molecular spectral analyses with univariate approach were conducted with the OMNIC 7.3 software. Results: Molecular spectral analysis parameters in fermented and non-fermented by-products from coffee processing included structural carbohydrate, cellulosic compounds, non-structural carbohydrates, lignin compound, CH-bending, structural carbohydrate peak1, structural carbohydrate peak2, structural carbohydrate peak3, hemicellulosic compound, non-structural carbohydrate peak1, non-structural carbohydrate peak2, non-structural carbohydrate peak3. The study results show that added-microorganism fermentation induced chemical and nutritional changes of coffee by-products including carbohydrate chemical composition profiles, bioenergy value, feed milk value, carbohydrate subfractions, estimated degradable and undegradable fractions in the rumen, and intestinal digested nutrient supply in ruminant system. Conclusion: In conclusion, carbohydrate nutrition value changes by added-microorganism fermentation duration were in an agreement with the change of their spectral profile in the coffee by-products. The studies show that the vibrational ATR-FT/IR spectroscopic technique could be applied as a rapid analytical tool to evaluate fermented by-products and connect with truly digestible carbohydrate supply in ruminant system.

Comparative Studies of Methods for Continuation and Derivatives of Potential Fields (포텐셜장(場)의 상하향연속(上下向連續) 및 미분법(微分法)에 대(對)한 비교연구(比較硏究))

  • Kwon, Byung Doo
    • Economic and Environmental Geology
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    • v.14 no.2
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    • pp.93-102
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    • 1981
  • Studies of model potential fields continued upward and downward show differences depending on the method of continuation. Beginning with a magnetic field computed over a buried vertical cylinder, the field was continued to various levels by a method introduced by Henderson (Lagrangian interpolation) and by a spectral method (frequency domain analysis). Resultant fields show (1) no significant differences in upward continued values, (2) in downward continuation, accurate values are obtained with the spectral method over the central part of the anomaly, and (3) accurate values are obtained with Henderson's method on the flanks of the anomaly, while oscillations usually characterize the spectral method in this region. Essentially the same observations are made for derivative calculations. Field oscillations are empirically predicted at levels continued to approximately two-thirds of the depth of the source. Our spectral computer program output yields marked oscillations at one-half of the depth of the source. Henderson's method shows no oscillations at this depth and only minor oscillations at the top of the body (some negative values appear on the flanks of the anomaly). The Henderson output is a smooth field even if continued below the top of the body. These results suggest that the presence of oscillations cannot be used to identify the top of a buried source without careful consideration of the method used to continue the field. Use of the derivative to outline and isolate anomalies must similarly include consideration of the method of calculation.

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The Meaning of P50 Suppression : Interaction of Gamma and Alpha Waves

  • Lee, Kyungjun;Kang, Ung Gu
    • Korean Journal of Biological Psychiatry
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    • v.21 no.4
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    • pp.168-174
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    • 2014
  • Objectives Sensory gating dysfunctions in patients with schizophrenia and bipolar disorder have been investigated through two similar methods ; P50 suppression and prepulse inhibition paradigms. However, recent studies have demonstrated that the two measures are not correlated but rather constitute as distinct neural processes. Recent studies adopting spectral frequency analysis suggest that P50 suppression reflects the interaction between gamma and other frequency bands. The aim of the present study is to investigate which frequency component shows more significant interaction with gamma band. Methods A total of 108 mood disorder patients and 36 normal subjects were included in the study. The P50 responses to conditioning and test stimuli with an intra-pair interval of 500 msec were measured in the study population. According to P50 ratio (amplitude to the test stimulus/amplitude to the conditioning stimulus), the subjects with P50 ratio less than 0.2 were defined as suppressed group (SG) ; non-suppressed group (NSG) consisted of P50 ratio more than 0.8. Thirty-five and 25 subjects were included in SG and NSG, respectively. Point-to-point correlation coefficients (PPCCs) of both groups were calculated between two time-windows : the first window (S1) was defined as the time-window of one hundred millisecond after the conditioning auditory stimulus and the second window (S2) was defined as the time-window of 100 msec after the test auditory stimulus. Spectral frequency analysis was performed to investigate which frequency band results in the difference of PPCC between SG and NSG. Results Significant reduction of PPCC between S1 and S2 was observed in the SG (Pearson's r = 0.24), compared to PPCC of the NSG (r = 0.58, p < 0.05). In spectral frequency analysis, gamma band showed "phase-reset" and similar responses after the two auditory stimuli in suppressed and non-suppressed group. However in the case of alpha band, comparison showed significantly low PPCC in SG (r = -0.14) compared to NSG (r = 0.36, p < 0.05). This may be reflecting "phase-out" of alpha band against gamma band at approximately 50 msecs after the test stimulus in the SG. Conclusions Our study suggests that normal P50 suppression is caused by phase-out of alpha band against gamma band after the second auditory stimulus. Thus it is demonstrated that normal sensory gating process is constituted with attenuated alpha power, superimposed on consistent gamma response. Implications of preserved gamma and decreased alpha band in sensory gating function are discussed.

A Comparative Study of Absolute Radiometric Correction Methods for Drone-borne Hyperspectral Imagery (드론 초분광 영상 활용을 위한 절대적 대기보정 방법의 비교 분석)

  • Jeon, Eui-ik;Kim, Kyeongwoo;Cho, Seongbeen;Kim, Shunghak
    • Korean Journal of Remote Sensing
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    • v.35 no.2
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    • pp.203-215
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    • 2019
  • As hyperspectral sensors that can be mounted on drones are developed, it is possible to acquire hyperspectral imagery with high spatial and spectral resolution. Although the importance of atmospheric correction has been reduced since imagery of drones were acquired at a low altitude,studies on the conversion process from raw data to spectral reflectance should be done for studies such as estimating the concentration of surface materials using hyperspectral imagery. In this study, a vicarious radiometric calibration and an atmospheric correction algorithm based on atmospheric radiation transfer model were applied to hyperspectral data of drone and the results were compared and analyzed. The vicarious calibration method was applied to an empirical line calibration using the spectral reflectance of a tarp made of uniform material. The atmospheric correction algorithm used ATCOR-4 based Modran-5 that was widely used for the atmospheric correction of aerial hyperspectral imagery. As a result of analyzing the RMSE of the difference between the reference reflectance and the correction, the vicarious calibration using the tarp in a single period of hyperspectral image was the most accurate, but the atmospheric correction was possible according to the application purpose of using hyperspectral imagery. If the correction process of normalized spectral reflectance is carried out through the additional vicarious calibration for imagery from multiple periods in the future, accurate analysis using hyperspectral drone imagery will be possible.

An Evaluation of the Use of the Texture in Land Cover Classification Accuracy from SPOT HRV Image of Pusan Metropolitan Area (SPOT HRV 영상을 이용한 부산 지역 토지피복분류에 있어서의 질감의 기여에 관한 평가)

  • Jung, In-Chul
    • Journal of the Korean Association of Geographic Information Studies
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    • v.2 no.1
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    • pp.32-44
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    • 1999
  • Texture features can be incorporated in classification procedure to resolve class confusions. However, there have been few application-oriented studies made to evaluate the relative powers of texture analysis methods in a particular environment. This study evaluates the increases in the land-cover classification accuracy of the SPOT HRV multispectral data of Pusan Metropolitan area from texture processing. Twenty-four texture measures were derived from the SPOT HRV band 3 image. Each of these features were used in combination with the three spectral images in the classification of 10 land-cover classes. Supervised training and a Gaussian maximum likelihood classifier were used in the classification. It was found that while entropy produces the best empirical results in terms of the overall classification, other texture features can also largely improve the classification accuracies obtained by the use of the spectral images only. With the inclusion of texture, the classification for each category improves. Specially, urban built-up areas had much increase in accuracy. The results indicate that texture size 5 by 5 and 7 by 7 may be suitable at land cover classification of Pusan Metropolitan area.

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Effect of Deuterated Solvents on the Excited State Photophysical Properties of Curcumin

  • Barik, A.;Goel, N.K.;Priyadarsini, K.I.;Mohan, Hari
    • Journal of Photoscience
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    • v.11 no.3
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    • pp.95-99
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    • 2004
  • Optical absorption and emission studies have been carried out to understand the effect of deuterium on the solvent dependent photophysical properties of curcumin in deuterated solvents such as $CDCl_3,\;(CD_3)_2SO,\;(CD_3)_2CO,\;CD_3OD\;and\;CD_3CN$. Optical absorption spectral studies showed that there is no significant shift in absorption maxima compared to the non-deuterated solvent. The fluorescence maxima shows significant shift with polarity of solvent but not much affected by the deuteration. The fluorescence quantum yield of curcumin increased marginally in almost all the deuterated solvents, indicating reduction in the non-radiative pathways. The fluorescence decay was biexponential in all the solvents and the average fluorescence lifetime was not much affected with deuteration, but showed decrease with increasing solvent polarity. Based on these studies, it is concluded that intermolecular hydrogen transfer is only partially responsible for the excited state deactivation of curcumin.

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A Review: Synthesis and characterization of metals complexes with paracetamol drug

  • AL-Ayash, Salam R;AL-Noor, Taghreed H
    • Analytical Science and Technology
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    • v.35 no.4
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    • pp.143-152
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    • 2022
  • In this review, previous studies on the synthesis and characterization of the metal Complexes with paracetamol by elemental analysis, thermal analysis, (IR, NMR and UV-Vis (spectroscopy and conductivity. In reviewing these studies, the authors found that paracetamol can be coordinated through the pair of electrons on the hydroxyl O-atom, carbonyl O-atom, and N-atom of the amide group. If the paracetamol was a monodentate ligand, it will be coordinated by one of the following atoms O-hydroxyl, O-carbonyl or N-amide. But if the paracetamol was bidentate, it is coordinated by atoms (O-carbonyl and N-amide), (O-hydroxyl and N-amide) or (O-carbonyl and O-hydroxyl). The authors also found that free paracetamol and its complexes have antimicrobial activity.

Detection of Small Green Space in an Urban Area Using Airborne Hyperspectral Imagery and Spectral Angle Mapper (분광각매퍼 기법을 적용한 항공기 탑재 초분광영상의 소규모 녹지공간 탐지)

  • Kim, Tae-Woo;Choi, Don-Jeong;We, Gwang-Jae;Suh, Yong-Cheol
    • Journal of the Korean Association of Geographic Information Studies
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    • v.16 no.2
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    • pp.88-100
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    • 2013
  • Urban green space is one of most important aspects of urban infrastructure for improving the quality of life of city dwellers as it reduces the heat island effect and is used for recreation and relaxation. However, no systematic management of urban green space has been introduced in Korea as past practices focused on efficient development. A way to calculate the amount of green space needed to complement an urban area must be developed to preserve urban green space and to determine 'regulations determining the total amount of greenery'. In recent years, various studies have quantified urban green space and infrastructure using remotely sensed data. However, it is difficult to detect a myriad small green spaces in a city effectively when considering the spatial resolution of the data used in existing research. In this paper, we quantified small urban green spaces using CASI-1500 hyperspectral imagery. We calculated MCARI, a vegetation index for hyperspectral imagery, to evaluate the greenness of small green spaces. In addition, we applied image-classification methods, including the ISODATA algorithm and Spectral Angle Mapper, to detect small green spaces using supervised and unsupervised classifications. This could be used to categorize land-cover into four classes: unclassified, impervious, suspected green, and vegetation green.

Chemical Studies on Cirsium Species (V) -Chemical Constituents of the Roots of Cirsium xanthocanthum- (Cirsium속(屬) 식물(植物)의 성분(成分) 연구(硏究)(V) -가시엉겅퀴 지하부(地下部)의 성분(成分)-)

  • Lee, Yong-Choo;Park, Young-Hoon
    • Korean Journal of Pharmacognosy
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    • v.15 no.2
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    • pp.74-77
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    • 1984
  • Cirsium xanthocanthum (Compositae) is a perennial herb. From the roots of this plant which were used for arthritis, neuralgia and carbuncular abscess as folkloric remedies, linarin, mp $255{\sim}257^{\circ}$, was isolated and identified by chemical reactions and spectral data with authentic samples.

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