• Bulletin of the Korean Chemical Society
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• v.33 no.11
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• pp.3581-3588
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• 2012

A new series of acyclic mononuclear gadolinium(III) complexes have been prepared by Schiff-base condensation derived from 5-methylsalicylaldehyde, diethylenetriamine, tris(2-aminoethyl) amine, triethylenetetramine, N,N-bis(3-aminopropyl)ethylene diamine, N,N-bis(aminopropyl) piperazine, and gadolinium nitrate. All the complexes were characterized by elemental and spectral analyses. Electronic spectra of the complexes show azomethine (CH=N) within the range of 410-420 nm. The fluorescence efficiency of Gd(III) ion in the cavity was completely quenched by the higher chain length ligands. Electrochemical studies of the complexes show irreversible one electron reduction process around -2.15 to -1.60 V The reduction potential of gadolinium(III) complexes shifts towards anodic directions respectively upon increasing the chain length. The catalytic activity of the gadolinium(III) complexes on the hydrolysis of 4-nitrophenylphosphate was determined. All gadolinium(III) complexes were screened for antibacterial activity.

• Journal of computational fluids engineering
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• v.16 no.3
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• pp.29-36
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• 2011

The natural convection in a horizontal enclosure heated from the bottom wall, cooled at the top wall, and having a square adiabatic body at its centered area was studied. Three different Prandtl numbers (0.01, 0.7 and 7) were considered for an effect of the Prandtl number on natural convection. A two-dimensional solution for unsteady natural convection was obtained, using Chebyshev spectral methodology for different Rayleigh numbers varying over the range of $10^4$ to $10^6$. It had been experimentally and numerically reported [1,2] that the heat transfer mode becomes oscillatory when Pr is out of a specific Pr band beyond the critical Ra. In this study, we reproduced this phenomenon numerically. The variation of time- and surface-averaged Nusselt numbers on the hot and cold walls for different Rayleigh numbers and Prandtl numbers was presented to show the overall heat transfer characteristics in the system. And also, the isotherms and streamline distributions were presented in detail to compare the physics related to their thermal behavior.

• Journal of the Optical Society of Korea
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• v.17 no.5
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• pp.433-440
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• 2013

We present an experimental and numerical study of spectral profiles of effective group indices of hydrogenated amorphous silicon (a-Si:H) waveguides and of their chromatic-dispersion effect on the four-wave-mixing (FWM) signal generation. The a-Si:H waveguides of 220-nm thickness and three different widths of 400, 450 and 500 nm were fabricated by using the conventional CMOS device processes on a $2-{\mu}m$ thick $SiO_2$ bottom layer deposited on 8-inch Si wafers. Mach-Zehnder interferometers (MZIs) were formed with the a-Si:H waveguides, and used for precise measurement of the effective group indices and thus for determination of the spectral profile of the waveguides' chromatic dispersion. The wavelength ranges for the FWM-signal generation were about 45, 75 and 55 nm for the 400-, 450- and 500-nm-wide waveguides, respectively, at the pump wavelength of 1532 nm. A widest wavelength range for the efficient FWM process was observed with the 450-nm-wide waveguide having a zero-dispersion near the pump wavelength.

• Nuclear Engineering and Technology
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• v.49 no.4
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• pp.825-837
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• 2017

Due to the severe impacts of recent earthquakes, the use of seismic isolation is paramount for the safety of nuclear structures. The diversity observed in seismic events demands ongoing research to analyze the devastating attributes involved, and hence to enhance the sustainability of base-isolated nuclear power plants. This study reports the seismic performance of a seismically-isolated nuclear reactor containment building (NRCB) under strong short-period ground motions (SPGMs) and long-period ground motions (LPGMs). The United States Nuclear Regulatory Commission-based design response spectrum for the seismic design of nuclear power plants is stipulated as the reference spectrum for ground motion selection. Within the period range(s) of interest, the spectral matching of selected records with the target spectrum is ensured using the spectral-compatibility approach. NRC-compliant SPGMs and LPGMs from the mega-thrust Tohoku earthquake are used to obtain the structural response of the base-isolated NRCB. To account for the lack of earthquakes in low-to-moderate seismicity zones and the gap in the artificial synthesis of long-period records, wavelet-decomposition based autoregressive moving average modeling for artificial generation of real ground motions is performed. Based on analysis results from real and simulated SPGMs versus LPGMs, the performance of NRCBs is discussed with suggestions for future research and seismic provisions.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.11 no.6
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• pp.37-43
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• 1997

Density of a dye or pigment teduces by radiant energym and dinsity change induces color change. In this paper, we habe worked out an equation to predict the color change by the radiant energy under the assumption of colorant density changing pattern by radiant energy and the color changing pattern by colorant density chane. And the damaging factors in the equation was established by experiments. To evaluate the efectiveness of the equation and the method, several samples were irradiated by common light source and color change was measured. Good coincidence between the ceasured and the calculated color change was found. And it was also found that there is a close relationhaip between the spectral damaging factor and the spectral absorptance in visible wavelength range.

• Journal of Soil and Groundwater Environment
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• v.19 no.3
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• pp.39-46
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• 2014

Hydraulic conductivity is an important parameter, representing permeable property of the groundwater in aquifers, in the issues of groundwater development, groundwater contamination, and groundwater flow, etc. We estimated a relationship between hydraulic conductivity and electrical properties (formation factor, chargeability, and time constant) of silty sand in the laboratory. For this study, we conducted grain size analysis, constant head permeameter test, and measured electrical resistivity and spectral induced polarization of silty sand samples collected from the riverside alluvium of the Nakdong River in Nogok-ri area, Dasan-myeon, Goryeong-gun in Gyeongbook Province, Korea. In the laboratory test, we used soil samples of approximately uniform porosity with 0.5% error range, and kept the electrical resistivity of pore water with 100 ohm-m. As a result, the relationship between effective particle size and hydraulic conductivity agrees fairly well with the existing empirical formulas. Hydraulic conductivity was correlated with formation factor, chargeability, and time constant: hydraulic conductivity increased with increasing formation factor and time constant as well as with decreasing chargeability.

• Mycobiology
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• v.35 no.3
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• pp.150-153
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• 2007

New $N_2O_2$ donor type Schiff base has been designed and synthesized by condensing acetoacetanilido-4-aminoantipyrine with 2-aminobenzoic acid in ethanol. Solid metal complexes of the Schiff base with Cu(II), Ni(II), Co(II), Mn(II), Zn(II), VO(IV), Hg(II) and Cd(II) metal ions were synthesized and characterized by elemental analyses, magnetic susceptibility, molar conduction, fast atom bombardment (FAB) mass, IR, UV-Vis, and $^1H$ NMR spectral studies. The data show that the complexes have the composition of ML type. The UV-Vis. and magnetic susceptibility data of the complexes suggest a square-planar geometry around the central metal ion except VO(IV) complex which has square-pyramidal geometry. The in vitro antifungal activities of the compounds were tested against fungi such as Aspergillus niger, Aspergillus flavus, Rhizopus stolonifer, Candida albicans, Rhizoctonia bataicola and Trichoderma harizanum. All the metal complexes showed stronger antifungal activities than the free ligand. The minimum inhibitory concentrations (MIC) of the metal complexes were found in the range of $10{\sim}31{\mu}g/ml$.

• Korean Journal of Remote Sensing
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• v.25 no.6
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• pp.507-515
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• 2009

Land surface temperature (LST) is a key environmental variable in a wide range of applications, such as weather, climate, hydrology, and ecology. However, LST is one of the most difficult surface variables to observe regularly due to the strong spatio-temporal variations. So, we have developed the LST retrieval algorithm from COMS (Communication, Ocean and Meteorological Satellite) data through the radiative transfer simulations under various atmospheric profiles (TIGR data), satellite zenith angle (SZA), spectral emissivity, and surface lapse rate conditions using MODTRAN 4. However, the LST retrieval algorithm has a tendency to overestimate and underestimate the LST for surface inversion and superadiabatic conditions, respectively. To minimize the overestimation and underestimation of LST, we also developed day/night LST algorithms separately based on the surface lapse rate (local time) and recalculated the final LST by using the weighted sum of day/night LST. The analysis results showed that the quality of weighted LST of day/night algorithms is greatly improved compared to that of LST estimated by original algorithm regardless of the surface lapse rate, spectral emissivity difference (${\Delta}{\varepsilon}$) SZA, and atmospheric conditions. In general, the improvements are greatest when the surface lapse rate and ${\Delta}{\varepsilon}$ are negatively large (strong inversion conditions and less vegetated surface).

• Structural Engineering and Mechanics
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• v.55 no.6
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• pp.1177-1202
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• 2015

In this paper, a new intensity measure of earthquakes for probabilistic seismic analysis is presented for skewed highway bridges. Three different cases of skewed bridges with different skew angles ($0^{\circ}$, $30^{\circ}$ and $45^{\circ}$) are considered. Well-known intensity measures (e.g., PGA, $S_a$) are evaluated and critically discussed based on sensitivity analysis: efficiency, practically, proficiency and sufficiency of intensity measures are considered in detail. The analyses demonstrated that the intensity measures have to take into account structural acceleration on a wide range of periods so that a new seismic intensity measure is proposed showing that it has less dispersion compared to others. Since the proposed intensity represents the average value of the $S_a$ (between a lower and upper structural period) it has been called Averaged Spectral Acceleration (ASA). Based on performed incremental dynamic analysis (IDA), the seismic analytical fragility curves of typical skewed highway bridges have been evaluated for different states of damage controlling the low dispersion of the ASA index as well as its proficiency and sufficiency.

• Journal of the Korean Solar Energy Society
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• v.31 no.2
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• pp.113-119
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• 2011

LED lighting has received much attention in recent years due to its high energy efficiency and environmental friendliness. As the color of light can be obtained by adjusting the light intensity of LEDs, the quality of visual environment can be improved. The aims of this study are to develop a wavelength adjustable LED lighting system and to examine its lighting performances. The LED lighting system and experimental cell for assessment of the lighting performance were constructed. This LED lighting system is able to materialize the various spectral power distribution and color temperature of light through the control of the four dimmers. Up to $432^4$ kinds of light combinations are possible. The range of illuminance on workplane were measured as 7~1,831 ㏓. Improvement of psychological and physical functions for occupants can be expected according to control of lighting performances.