• Title/Summary/Keyword: Specific charge

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Electrochemical Characteristics of EDLC with various Organic Electrolytes (유기전해질에 따른 EDLC의 전기화학적 특성)

  • Yang Chun-Mo;Lee J.K.;Cho W.I.;Cho B.W.;Rim Byung-O
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.113-117
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    • 2001
  • Specific capacitance and charge-discharge rate of EDLC using activated carbon electrode were affected by the compositions of electrolytes, the conditions of charge-discharge and physical properties of activated carbon materials. The activated carbon electrode was prepared by dip coating method. Charge-discharge test and electrochemical experiments were carried out for various kinds of organic electrolytes. Effects of charge and discharge current density on the specific capacitance were studied. Characteristics of leakage current, self-discharge and time-voltage curves in optimum conditions of organic electrolytes were compared with conventional $1M-Et_4NBF_4/PC$ electrolyte. The EDLC using MSP-20(specific surface area: $2000m^2/g$) electrode and $1M-LiPF_6/PC-DEC(1:1)$ was exhibited th highest specific capacitance of 130F/g and low polarization resistances. The EDLC using MSP-20 electrode at $1M-LiPF_6/PC-DEC(1:1)$ was small leak current of 0.0004A for 15min, long voltage retention of 0.8V after 100h and linear time-voltage curves with small IR-drop.

Comparison of Spray Characteristics between Conventional and Electrostatic Pressure-Swirl Nozzles

  • Laryea, G.N.;No, S.Y.
    • Journal of ILASS-Korea
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    • v.11 no.1
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    • pp.24-29
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    • 2006
  • Spray characteristics produced by conventional and electrostatic pressure-swirl nozzles for an oil burner have been studied, using kerosine as a test liquid. The charge injection mechanism is used to design the electrostatic nozzle, where specific charge density, breakup length, spray angle and mean diameter are measured and analyzed. Three nozzles with orifice diameters of 0.256, 0.308 and 0.333mm at injection pressures of 0.7, 0.9, 1.1 and 1.3 MPa are used in the study. In case of the electrostatic nozzle, voltages ranging from -5 to -12kV are applied. Comparison of the spray characteristics is made between the conventional and electrostatic nozzles. The results showed that, the electrostatic nozzle is superior to the conventional nozzle. This is due the effect of voltage on the liquid surface tension.

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Institutional Improvement of Irrigation Management System in Korea

  • Chung, Sang-Ok
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.44 no.7
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    • pp.74-82
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    • 2002
  • There are two major operation and management (O & M) systems in Korea, one by the Korea Agricultural and Rural Infrastructure Corporation (KARICO), a government corporation, and the other by non-KARICO, which includes Irrigation associations (IAs) and individual farmers under the supervision of city or county authorities. Main issues and constraints in the irrigation facility management are: (1) The dual system of the irrigation water management system; management by KARICO and that by IAs, and (2) From the commencement of KAICO in 2000, farmers were exempted from water charge. This is opposite to the international trend, which follows' user pay principle: Main specific strategies to improve irrigation management system are: (1) Introduction of water metering for water charge as well as water conservation, (2) Adoption of demand-oriented irrigation rather than supply-oriented to reduce waste of water, (3) To augment farmer's participation by forming water user associations, (4) To maintain consistency of government policy, (5) To promote roles of local governments, and (6) To reestablish the role of KARICO.

Nanostructured Ni-Mn double hydroxide for high capacitance supercapacitor application

  • Pujari, Rahul B.;Lee, Dong-Weon
    • Journal of Sensor Science and Technology
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    • v.30 no.2
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    • pp.71-75
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    • 2021
  • Recently, transition-metal-based hydroxide materials have attracted significant attention in various electrochemical applications owing to their low cost, high stability, and versatility in composition and morphology. Among these applications, transition-metal-based hydroxides have exhibited significant potential in supercapacitors owing to their multiple redox states that can considerably enhance the supercapacitance performance. In this study, nanostructured Ni-Mn double hydroxide is directly grown on a conductive substrate using an electrodeposition method. Ni-Mn double hydroxide exhibits excellent electrochemical charge-storage properties in a 1 M KOH electrolyte, such as a specific capacitance of 1364 Fg-1 at a current density of 1 mAcm-2 and a capacitance retention of 94% over 3000 charge-discharge cycles at a current density of 10 mAcm-2. The present work demonstrates a scalable, time-saving, and cost-effective approach for the preparation of Ni-Mn double hydroxide with potential application in high-charge-storage kinetics, which can also be extended for other transition-metal-based double hydroxides.

The electrochemical characteristics of EDLC with various activated carbons (다양한 활성탄 종류에 따른 EDLC 전기화학적 특성)

  • Yoon, Hong-Jin;Lee, Chang-Ho;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.225-231
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    • 2011
  • The electrochemical characteristics of electric double layer capacitor(EDLC) were investigated using various carbon materials. The physical properties such as specific surface area and mean pore size of activated carbon were analyzed by BET. The results of the activated carbon used for electrode material showed that the specific surface areas varied from 600 to 1500 $m^2$/g and mean pore sizes from 1.74 to 2.88 nm. A maximum specific capacitance of 0.30 F/$cm^2$ was obtained for the activated carbon with the highest specific surface area and ionic conductivity. Also, it was found that the electrochemical results of the cyclic charge-discharge tests were stable.

Redox Properties of Polyaniline Films and Its Application to Lithium Secondary Batteries (Polyaniline 필름의 산화환원 특성 및 리튬 2차 전지 응용)

  • 김현철;박영철;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.144-148
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    • 1997
  • We synthesized polyaniline films electrochemically under constant current conditions, which exhibited electric conductivity as high as 100 S/cm. By charge and discharge cycling of polyaniline films, we obtained specific discharge capacity as high as 195 mAH/g using HSO$_4$- doped polyaniline. For the polyaniline synthesized using H$_2$SO$_4$ and HClO$_4$ composite electrolyte. we also obtained specific discharge capacity as high as 134 mAHg which rivals inorganic electro- active materials.

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A Study on the Improvement of Heat Transfer Performance in Low Temperature Closed Thermosyphon

  • Han, Kyu-Il;Yee, Seok-Su;Park, Sung-Hyun;Lee, Suk-Ho;Cho, Dong-Hyun
    • Journal of Mechanical Science and Technology
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    • v.16 no.9
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    • pp.1102-1111
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    • 2002
  • The study focuses on the heat transfer performance of two-phase closed thermosyphons with plain copper tube and tubes having 50, 60, 70, 80, 90 internal grooves. Three different working fluids(distilled water, methanol, ethanol) are used with various volumetric liquid fill charge ratio from 10 to 40%. Additional experimental parameters such as operating temperature and inclination angle of zero to 90 degrees are used for the comparison of heat transfer performance of the thermosyphon. Condensation and boiling heat transfer coefficients, heat flux are obtained using experimental data for each case of specific parameter. The experimental results are assessed and compared with existing correlations. The results show that working fluids, liquid fill charge ratio, number of grooves and inclination angle are very important factors for the operation of thermosyphons. The relatively high rate of heat transfer is achieved when the thermosyphon with internal grooves is used compared to that with plain tube. The optimum liquid fill charge ratio for the best heat transfer performance lies between 25% and 30%. The range of the optimum inclination angle for this study is 20$^{\circ}$~30$^{\circ}$ from the horizontal position.

A Comparative Study on the Chemicostructural Characteristics of Ecdysteroids (Ecdysteroid 화합물들의 화학구조 특성에 대한 비교연구)

  • Hwang, Gab-Soo
    • Journal of Environmental Health Sciences
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    • v.38 no.4
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    • pp.351-359
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    • 2012
  • Objectives: This study was conducted in order to investigate the specific correlation between physicochemical properties and bioactivity in ecdysteroids found in living organisms. Methods: The examined steroidal compounds were classified into three groups according to their relevance to ecdysone activity. Each compound molecule was completely drawn to automatically calculate its physicochemical parameters and docked against 20-hydroxyecdysone to calculate the total distance. Electronic charge distribution was also observed for each molecule. All procedures were conducted using a computational chemistry program. Results: Ecdysone agonists showed different ranges of parameter values, such as log P, hydrophilic-lipophilic balance (HLB), solubility parameter (SP), hydrophilic surface (HPS), hydrogen bond (HB) and Kappa 2, when compared with antagonists and steroids without ecdysone activity. They also showed a similar electronic charge distribution that is significantly different from the electron charge distribution of antagonists and steroids without ecdysone activity. The total distance values of agonists, estimated by docking them with 20-hydroxyecdysone, were relatively small but showed no correlation with binding affinity with receptor ligand. Conclusions: These results suggest that physicochemical properties such as steric and electronic effects, hydrophobicity and hydrogen bonding may operate in combination to determine the binding activity of ecdysteroids to the receptor protein.

Physico-Chemical Characterization of the Layered Double Hydroxide as Pillar Host Material (Pillar Host Material로써 Layered(Mg/Al) Double Hydroxide의 물리화학적 특성화)

  • 형경우;이용석
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.443-450
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    • 1998
  • Layered double hydroxides(LDHs) [{{{{ {Mg }_{1-x } }}{{{{ {Al }_{x } }}({{{{ {OH}_{2 } }})]ζ+({{{{ {CO }`_{3 } ^{2- } ){ }_{x/2 } }}$.${{{{ { yH}_{2 }O }} wioth variation of layer charge densitywere synthesized by co-precipitation methdo since their charge densities have a very important role to be det-ermined the physicochemical properties of layered materials. The XRD IR and thermal studies of them were discussed and the kinetic study for the decarbonation reaction was also carried out. From the results of XRD analysis we found that the lattice parameter and the unit cell volume were linearly decreased with the amount of Al substituents(x) in the vicinity of x=2∼10${\times}$1/3${\times}$10-1 but they had nearly constant values when the x are far from these vicinit. The activation energies for the decarbonation reaction of x=6.8, 10${\times}$1/3${\times}${{{{ { 10}^{-1 } }} were estimated to be 47.0, 37.6, 39.3 kcal/mol The specific surface areas(90-120 m2/g) of stable hy-drotalcite-type LDHs were dractically decreased with increasing of layer charge density.

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Numerical Study on the Crack-propagation Controlling in Blasting Using Notched Charge Hole (노치 장약공을 이용한 발파균열제어에 관한 수치해석적 연구)

  • Cho, Sang-Ho;Park, Seung-Hwan;Kim, Kwang-Yeom;Nakamura, Yuichi;Kaneko, Katsuhiko
    • Explosives and Blasting
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    • v.26 no.1
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    • pp.49-55
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    • 2008
  • Mechanical excavation techniques employing tunnel boring machines (TBM) and rock splitters have been proposed to minimize rock damage for tunnel and underground waste repository facilities. Such a mechanical excavation, however, is extremely expensive and not applicable in all cases. For these reasons, controlled blasting using notched charge holes have been suggested to achieve crack growth along specific directions and inhibit growth along other directions. This study introduces a dynamic fracture process analysis code to simulate fracture processes of rock which has a notched charge hole.