• Bulletin of the Korean Chemical Society
• /
• v.25 no.11
• /
• pp.1645-1647
• /
• 2004

Potential energy surfaces for the reaction Al + $O_2{\to}$AlO + O have been calculated with the multireference configuration interaction (MRCI) method using molecular orbitals derived from the complete active space selfconsistent field (CASSCF) calculations. The end-on geometry is the most favourable for the reaction to take place. The small reaction barrier in the present calculation (0.11 eV) is probably an artefact related to the ionicneutral avoided crossing. The charge analysis implies that the title oxidation reaction occurs through a harpooning mechanism. Along the potential energy surface of the reaction, there are two stable intermediates of $AlO_2(C_{{\infty}v}$ and $C_{2v}$) at least 2.74 eV below the energy of reactants. The calculated enthalpy of the reaction (-0.07 eV) is in excellent agreement with the experimental value (-0.155 eV) in part due to the fortuitous cancellation of errors in AlO and $O_2$ calculations.

• Journal of the Korean Society of Safety
• /
• v.11 no.2
• /
• pp.60-66
• /
• 1996

In order to look into the internal structure and electrical properties of insulating Silicone rubbers added reinforcing fillers ; Silica(0-140 phr ), and to examine the behavior of charged particles, and the properties of thermally stimulated current (TSC) are investigated, respectively. From the TSC which are formed by applying the electric field of 2~5 ㎸/mm to specimen at temperature range from -150 to $270^{\circ}C$, the results arp as following. In the case of non-filled specimen, four peaks of $\delta$, $\gamma$ , $\beta$ and u are obtained at the temperature of $-120^{\circ}C$, $-60^{\circ}C$, $20^{\circ}C$ and $130^{\circ}C$, respectively and the case of filled specimen, three peaks of $\delta$, ${\alpha}_2$ and ${\alpha}_1$ are observed at the temperature of of $-120^{\circ}C$, $80^{\circ}C$ and $130^{\circ}C$, respectively. The origins of these peaks are that, the $\delta$ peak seems to the result from the contribution of side chain methyl radical, and the $\beta$ peak from the depolarization of space charge polarization owing to added imputity during during manufacturing specimens, and the $\beta$ peak from the orientation of $Si-CH_3$dipole, and the ${\alpha}_2$ near the temperature of $130^{\circ}C$ from carboxyl acid that is formed by the thermal oxidation of high temperature.

• The Transactions of the Korean Institute of Electrical Engineers A
• /
• v.51 no.1
• /
• pp.23-28
• /
• 2002

In order to survey the radiation characteristics of pure line noise of unwanted noise from overhead high voltage AC transmission lines, a disk type gap noise generator was manufactured. Disk size which decides capacitance between the noise generator and earth was selected through preliminary indoor experiments and analysis by using surface charge method. The capacitance is one of principal parameters related to the injection of a proper noise current into lines. On the basis of the capacitance obtained from calculation, 5mm of space was given to the gap of the noise generator to be installed o test line and an aluminum disk of 60cm radius was made. The field experiments were performed with the noise generator hung on the Kochang 765 kV full scale test line. As the results, the useful data which can be used to analysis the radiation characteristics of noise from transmission lines were obtained. Those are the directivity of antenna toward the line, lateral profiles, frequency spectra, height pattern and so on.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.49 no.9
• /
• pp.533-540
• /
• 2000

Lightning impulse $(1.2/44[\mus])$ and damped oscillating impulse $(Osc./44[\mus])$ : 0.83[MHz]) breakdown characteristics in sulphur-hexafluoride/nitrogen (SF6-N2) mixtures were investigated. The predischarge currents were observed to clarify the breakdown mechanism. th experiments were carried out under nonuniform electric fields disturbed by a needle-shaped protrusion whose length and diameter are 10[mm] and 1[mm] at total gas pressure up to 0.5[MPa] with nitrogen concentrations varying from 5 to 20[%] in the mixture. The electrical breakdowns of SF6-N2 mixtures for both the positive and negative polarities develop with steplike pulses in leader mechanism and the breakdown voltage -time (V-t) characteristics were affected by the space charge. The voltage-time curves for the negative oscillating impulse voltage were extended over the longer time range. The minimum breakdown voltages for the negative lightning and oscillating impulse voltage were higher than those for the positive ones. in particular the positive breakdown voltages were independent of the gas pressure.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.11 no.12
• /
• pp.1108-1114
• /
• 1998

$BaTiO_3$ thin films preferred c-axis orientation for the potential application of ferroelectric memory devices were deposited on silicon substrates(100) by RF sputtering and annealed at 800 and 900[$^{\circ}C$] in air. The BT(100)/BT(110) peak ratio of the sputtered sample was decreased with post-annealing in air. According to increasing with annealing temperature and time, the peak ratio of BT(100)/BT(110) was decreased and the surface density of thin film was high. Dielectric characteristics of $BaTiO_3$ thin film was measured as a function of annealing temperature and frequency. The dielectric constants were increased with annealing and decreased with frequency by space charge polarization and dipole polarization below 600[kHz]. The remanent polarization and coercive field in P-E hysteresis loop of $BaTiO_3$thin film were increased with the annealing temperature in air. The remanent polarization and coercive filed annealed at 800[$^{\circ}C$] for 1hr were 1.2[$\mu$C/$cm^2$] and 200[kV/cm]

• The Korean Journal of Health Service Management
• /
• v.6 no.4
• /
• pp.191-204
• /
• 2012

The purpose of this study was to provide basic data necessary for improvement by closely examining factors of having influence upon dental technicians' turnover. Questionnaire survey was conducted of 204 dental technicians who work at dental hospitals, clinics and dental laboratory rooms in Daegu area. The following conclusions were obtained. The satisfaction with job was high in job position in more than co-representative, in the whole and other task, and in less than 9 hours as for working hours. In the satisfaction with working environment, dissatisfaction was high in women, in the working career with 7~9 years, in chief level as for the job position in charge, in being responsible for porcelain in case of the duty field, and in more than 10 people as for the number of employees. The higher satisfaction with job satisfaction and working environment led to the lower turnover intention. Turnover intention was low in case of having ventilation fan & dust collector desk and in case of being well ventilated inside the workshop. As the above results, it is considered to be necessary for arranging institutional device of protecting dental technicians' health and reducing turnover through improving working environment such as forming comfortable environment of using the dust-collecting facilities and the ventilation facilities, wearing suitable individual protective gear and arranging the rest space.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.17 no.12
• /
• pp.1132-1138
• /
• 2005

Recently, production and use of freon substances are restrained due to depletion of ozone layer and global warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study is to find the optimal operating conditions by comparing the performance between the shell and tube type and shell and disk type heat exchangers using the ammonia refrigerant, and to verify the superiority of the shell and disk type heat exchanger that is not used in field of refrigeration and air conditioning. Finally, this study shows that the shell and disk type heat exchanger is applicable to the ammonia refrigeration system, and this system minimizes the refrigerant charge and installation space.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.13 no.3
• /
• pp.199-214
• /
• 2011

A crack is the main cause to affect the integrity of tunnel lining as well as leakage, spalling, exposed rebar, corrosion, carbonation and so on. Since the 1980, NATM has prevailed on excavation method and geotechnical philosophy in tunnel. Although the pattern of cracks has been reported by several engineers' effort, it was only focused on longitudinal cracks of lining. Eleven operational NATM tunnels have been conducted with the precise inspection for safety and diagnosis by KISTEC (Korea Infrastructure Safety and Technology Incorporation). With those results, the crack patterns by the spatial distribution and appearance for each tunnel have been analyzed and the cause of occurrence for seven common types of cracks in NATM tunnels was classified. Additionally, the longitudinal crack on lining above duct slab was figured out by numerical simulation and field inspection. Each crack has been analyzed by CCD (Charge-Coupled Device) scanner image with 3D configuration. Each type of cracks is also explained with output of experimental and condition of construction. Defined cracks on NATM tunnels will be good example for periodical inspection and precise inspection for safety and diagnosis.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.33 no.9
• /
• pp.89-96
• /
• 2005

This paper discusses the daytime atmospheric conditions and the possibility of daytime star detection with the purpose of practical use of the star sensor for daylight navigation. In order to estimate the daytime atmospheric data, we use the standard atmospheric model (LOWTRAN 7), from which atmospheric transmittance and radiance from background sky are calculated. Assuming the star sensor with an optical filter to reduce background radiation, different separation angles between the star sensor and the sun are set up to express the effect of the solar radiation. As considerations of field of view (FOV) of the star sensor, the variation of the sky background radiation and the star density of the detectable star are analyzed. In addition, the integration time to achieve a required signal-to-noise ratio and the number of the radiation-caused electrons of the charge coupled detector(CCD) working as the limit to daylight application of the star sensor are calculated.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.31 no.7
• /
• pp.94-99
• /
• 2003

For the assessment of combustion stability of a liquid rocket engine, a device called "Pulse Gun" should be developed first, which can induce artificial perturbations that may lead to excitations of pressure oscillations in a combustion chamber. A model chamber has been used for identifying design parameters of a pulse gun that defines its characteristics. Dynamic pressure measurements showed that shock waves generated from pulse guns are axisymmetric around the axis of a pulse gun barrel. Pressure waves perturbed by a pulse gun induce resonant acoustic frequencies of a model chamber. This fact indicates that successful pressure field perturbations of the KSR-III combustion chamber can be performed by a newly developed pulse gun device. A maximum value of dynamic pressure peaks measured at the opposite point against a pulse gun outlet becomes stronger as charge mass of pulse gun powder increases.