• Bulletin of the Korean Chemical Society
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• 제25권11호
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• pp.1645-1647
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• 2004

Potential energy surfaces for the reaction Al + $O_2{\to}$AlO + O have been calculated with the multireference configuration interaction (MRCI) method using molecular orbitals derived from the complete active space selfconsistent field (CASSCF) calculations. The end-on geometry is the most favourable for the reaction to take place. The small reaction barrier in the present calculation (0.11 eV) is probably an artefact related to the ionicneutral avoided crossing. The charge analysis implies that the title oxidation reaction occurs through a harpooning mechanism. Along the potential energy surface of the reaction, there are two stable intermediates of $AlO_2(C_{{\infty}v}$ and $C_{2v}$) at least 2.74 eV below the energy of reactants. The calculated enthalpy of the reaction (-0.07 eV) is in excellent agreement with the experimental value (-0.155 eV) in part due to the fortuitous cancellation of errors in AlO and $O_2$ calculations.

• 한국안전학회지
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• 제11권2호
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• pp.60-66
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• 1996

In order to look into the internal structure and electrical properties of insulating Silicone rubbers added reinforcing fillers ; Silica(0-140 phr ), and to examine the behavior of charged particles, and the properties of thermally stimulated current (TSC) are investigated, respectively. From the TSC which are formed by applying the electric field of 2~5 ㎸/mm to specimen at temperature range from -150 to $270^{\circ}C$, the results arp as following. In the case of non-filled specimen, four peaks of $\delta$, $\gamma$ , $\beta$ and u are obtained at the temperature of $-120^{\circ}C$, $-60^{\circ}C$, $20^{\circ}C$ and $130^{\circ}C$, respectively and the case of filled specimen, three peaks of $\delta$, ${\alpha}_2$ and ${\alpha}_1$ are observed at the temperature of of $-120^{\circ}C$, $80^{\circ}C$ and $130^{\circ}C$, respectively. The origins of these peaks are that, the $\delta$ peak seems to the result from the contribution of side chain methyl radical, and the $\beta$ peak from the depolarization of space charge polarization owing to added imputity during during manufacturing specimens, and the $\beta$ peak from the orientation of $Si-CH_3$dipole, and the ${\alpha}_2$ near the temperature of $130^{\circ}C$ from carboxyl acid that is formed by the thermal oxidation of high temperature.

• 대한전기학회논문지:전력기술부문A
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• 제51권1호
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• pp.23-28
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• 2002

In order to survey the radiation characteristics of pure line noise of unwanted noise from overhead high voltage AC transmission lines, a disk type gap noise generator was manufactured. Disk size which decides capacitance between the noise generator and earth was selected through preliminary indoor experiments and analysis by using surface charge method. The capacitance is one of principal parameters related to the injection of a proper noise current into lines. On the basis of the capacitance obtained from calculation, 5mm of space was given to the gap of the noise generator to be installed o test line and an aluminum disk of 60cm radius was made. The field experiments were performed with the noise generator hung on the Kochang 765 kV full scale test line. As the results, the useful data which can be used to analysis the radiation characteristics of noise from transmission lines were obtained. Those are the directivity of antenna toward the line, lateral profiles, frequency spectra, height pattern and so on.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권9호
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• pp.533-540
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• 2000

Lightning impulse $(1.2/44[\mus])$ and damped oscillating impulse $(Osc./44[\mus])$ : 0.83[MHz]) breakdown characteristics in sulphur-hexafluoride/nitrogen (SF6-N2) mixtures were investigated. The predischarge currents were observed to clarify the breakdown mechanism. th experiments were carried out under nonuniform electric fields disturbed by a needle-shaped protrusion whose length and diameter are 10[mm] and 1[mm] at total gas pressure up to 0.5[MPa] with nitrogen concentrations varying from 5 to 20[%] in the mixture. The electrical breakdowns of SF6-N2 mixtures for both the positive and negative polarities develop with steplike pulses in leader mechanism and the breakdown voltage -time (V-t) characteristics were affected by the space charge. The voltage-time curves for the negative oscillating impulse voltage were extended over the longer time range. The minimum breakdown voltages for the negative lightning and oscillating impulse voltage were higher than those for the positive ones. in particular the positive breakdown voltages were independent of the gas pressure.

• 한국전기전자재료학회논문지
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• 제11권12호
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• pp.1108-1114
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• 1998

$BaTiO_3$ thin films preferred c-axis orientation for the potential application of ferroelectric memory devices were deposited on silicon substrates(100) by RF sputtering and annealed at 800 and 900[$^{\circ}C$] in air. The BT(100)/BT(110) peak ratio of the sputtered sample was decreased with post-annealing in air. According to increasing with annealing temperature and time, the peak ratio of BT(100)/BT(110) was decreased and the surface density of thin film was high. Dielectric characteristics of $BaTiO_3$ thin film was measured as a function of annealing temperature and frequency. The dielectric constants were increased with annealing and decreased with frequency by space charge polarization and dipole polarization below 600[kHz]. The remanent polarization and coercive field in P-E hysteresis loop of $BaTiO_3$thin film were increased with the annealing temperature in air. The remanent polarization and coercive filed annealed at 800[$^{\circ}C$] for 1hr were 1.2[$\mu$C/$cm^2$] and 200[kV/cm]

• 보건의료산업학회지
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• 제6권4호
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• pp.191-204
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• 2012

The purpose of this study was to provide basic data necessary for improvement by closely examining factors of having influence upon dental technicians' turnover. Questionnaire survey was conducted of 204 dental technicians who work at dental hospitals, clinics and dental laboratory rooms in Daegu area. The following conclusions were obtained. The satisfaction with job was high in job position in more than co-representative, in the whole and other task, and in less than 9 hours as for working hours. In the satisfaction with working environment, dissatisfaction was high in women, in the working career with 7~9 years, in chief level as for the job position in charge, in being responsible for porcelain in case of the duty field, and in more than 10 people as for the number of employees. The higher satisfaction with job satisfaction and working environment led to the lower turnover intention. Turnover intention was low in case of having ventilation fan & dust collector desk and in case of being well ventilated inside the workshop. As the above results, it is considered to be necessary for arranging institutional device of protecting dental technicians' health and reducing turnover through improving working environment such as forming comfortable environment of using the dust-collecting facilities and the ventilation facilities, wearing suitable individual protective gear and arranging the rest space.

• 설비공학논문집
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• 제17권12호
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• pp.1132-1138
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• 2005

Recently, production and use of freon substances are restrained due to depletion of ozone layer and global warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study is to find the optimal operating conditions by comparing the performance between the shell and tube type and shell and disk type heat exchangers using the ammonia refrigerant, and to verify the superiority of the shell and disk type heat exchanger that is not used in field of refrigeration and air conditioning. Finally, this study shows that the shell and disk type heat exchanger is applicable to the ammonia refrigeration system, and this system minimizes the refrigerant charge and installation space.

• 한국터널지하공간학회 논문집
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• 제13권3호
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• pp.199-214
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• 2011

균열, 누수, 박락, 철근노출, 부식, 탄산화 등은 터널 라이닝 건전도 평가항목으로 그 중에서 균열은 주요한 영향요인이다. 1980년 이후로, NATM은 터널의 굴착방법과 링폐합의 지반공학적 개념의 보급과 함께 넓게 적용되었으며, 라이닝에 발생된 균열의 연구도 진행되었으나 종균열에 제한된 연구가 주로 수행되었다. 본 논문에서는 11개의 공용중인 NATM터널의 정밀안전진단 결과를 활용하여 공간적인 위치 및 형태별로 분석하여 터널별 공통된 7개의 균열을 정의, 원인 및 분석, 사례 등을 나타내었다. 종류별 균열은 CCD스캐너 이미지를 3차원으로 분석하여 향후 NATM터널 정기점검 및 정밀안전진단 시 유익한 사례가 휠 수 있도록 하였다.

• 한국항공우주학회지
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• 제33권9호
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• pp.89-96
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• 2005

이 논문에서는 주간 항법용 별센서의 실제 활용을 목적으로 주간 대기 조건과 주간 별 감지 가능성을 논한다. 주간동안의 대기 자료를 구하기 위해 표준 대기 모델(LOWTRAN 7)을 사용했으며 그 모델로부터 배경하늘에 대한 복사와 대기투과도를 구하였다. 대기 복사량을 감소시키기 위해 광학 필터를 장착한 별센서를 가정했으며 태양 복사 효과를 나타내기 위해 별센서와 태양 사이의 다양한 분리각을 설정하였다. 별센서의 FOV에 대한 고려로서, 하늘 배경 복사의 변화와 감지가능한 별의 개수 밀도를 분석하였다. 또한 요구되는 신호 대 잡음비를 얻기 위한 노출시간과 별센서의 주간 활용 한계로서 작용하는 CCD의 복사에 의한 전자 수를 계산하였다.

• 한국항공우주학회지
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• 제31권7호
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• pp.94-99
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• 2003

액체로켓엔진의 연소 안정성 평가를 위한 압력 교란 장치인 펄스건은 내재된 화약 폭발시 충격파를 유도관을 통해 엔진 연소기 내부로 전달 발생시키게 된다. 본 연구에서는 펄스건 특성에 영향을 주는 여러 가지 인자 중 화약 충진량에 의한 충격파 특성 파악을 위해 KSR-III 주 엔진과 같은 직경 크기를 갖는 모사 챕버를 이용하였다. 펄스건 출구에서 발생하는 충격파는 축대칭의 균일한 형상의 세기를 지니고 있으며 전체적인 세기 분포는 챔버 내의 압력에 따라 변화함을 확인하였다. 펄스건의 충격파는 상온 상태 조건에서 챔버내의 공명 주파수를 가진하는 것으로 보아 실제 연소장에서도 충분한 압력 교란을 제공할 수 있을 것으로 보인다. 가장 중요한 점은 펄스건에 의해 발생하는 초기 압력 최대 값이 화약 충진량의 크기에 비례하는 경향을 보인다는 것이다.