• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.474-477
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• 1991

The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001 M M($NO_3$)$_2(M=Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Sr^{2+},\;Cd^{2+},\;and\;Pb^{2+})$ (2) a toluene membrane containing 0.01 M ligand $(DBN_3O_2$, DA18C6, DT18C6, TT18C6, HT18C6) and the surfactant span 80 (sorbitan monooleate) (3% v/v) and (3) an aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of transition metal ions from the source phase as a function of time. Cation transports for various two component or three component equimolar mixture of transition metal and $Cu^{2+}$ in a emulsion membrane system incorporating macrocyclic ligand (HT18C6) as carrier were determinded. $Cu^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution. Equilibrium constants for cation-source phase co-anion, cation macrocycle and cation-receiving phase reagent interaction are examined as parameters for the prediction of cation transport selectivities.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3387-3390
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• 2012

In this research work the potentialities of microemulsion bulk liquid membrane for the selective transport of L-tryptophan (L-Trp) and L-tyrosine (L-Tyr) are investigated at 298.15 K. Reversed micelle formed by sodium bis(2-ethylhexyl)sulfosuccinate (AOT) in dichloroethane, was used as mobile carrier to transport amino acids between a source and a receiving aqueous phase. The effects of pH, surfactant concentration and initial amino acid concentration on the extraction efficiency and transfer rate of the amino acids were studied. It is verified that for a mixture of two amino acids, L-Trp can be extracted selectively by using this type of the bulk liquid membrane with optimized condition.

• Journal of the Korean Chemical Society
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• v.20 no.3
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• pp.229-235
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• 1976

Phenylacetic acid is chlorinated photochemically in carbon disulfide and carbon tetrachloride solvents to obtain ${\alpha}$-chlorophenylacetic acid in $43{\%}$ yield (after separation and purification). The amination of ${\alpha}$-chlorophenylacetic acid yielded the desired dl-phenylglycine in $16\sim27{\%}$ yield depending on the solvent used. Sensitized photophenylation of glycine is also attempted utilizing benzoylperoxide as a phenyl radical source in benzene or acetone solvent.

• Proceedings of the IEEK Conference
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• 2000.09a
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• pp.609-612
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• 2000

본 논문에서는 음원에 관한 정보가 미지의 상황에서 마이크로폰 어레이를 사용하여 두 음원신호를 분리하는 ,시스템을 제안한다 이 시스템은 두 단계로 구성되어 있으며, 첫 번째 단계에서는 파워가 큰 제 1음원의 DOA(Direction Of Arrival)를 추정하고, AMUSE(Algorithm for Multiple Unknown Signals Extraction)법을 사용한 Blind Deconvolution에 의해 음원신호의 분리를 행한다 두 번째 단계에서는 파워가 낮은 제 2음원의 강조신호를 사용하여 DSA(Delay and Sum Array)법에 의해 제 2음원의 DOA를 추정하고,AMUSE법의 출력신호와 두 음원의 DOA를 이용하여 ANF(Adaptive Notch Filter)를 구성하고, 두 음원신호의 재 분리를 행한다. 그리고, 시뮬레이션을 통해 제안한 방법의 유효성을 검토한 결과 두 음원 신호가 분리 가능한 것이 확인되었다.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2016.06a
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• pp.224-227
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• 2016

본 논문에서는 스테레오 채널 신호 간 강도비를 이용하여 음원을 분리하는 EADRess 알고리즘과 부분기반 표현을 특징으로 한 비음수 행렬 인수분해를 통해 음원을 분리하는 NMF 가 결합된 새로운 음원분리 알고리즘을 제안한다. 입력 오디오 신호로부터 frequency-azimuth 평면 구성을 통해 식별된 방위각에 상응하는 신호 강도비로 표현되는 확률밀도함수를 이용하여 1 단계 음원분리를 수행하고, 얻어진 개별 분리음원을 대상으로 supervised NMF 및 Wiener 필터 기반 마스킹 함수를 적용함으로써 잔류 혼합성분을 제거하는 2 단계 음원분리를 수행한다. 제안된 EADRess/NMF 결합 음원분리 알고리즘의 성능을 검증하기 위하여 SASSEC 에서 제공하는 테스트 음원을 이용하여 측정한 결과, 개별 음원분리 알고리즘에 비해 SIR 이 각각 1.41dB, 10.43dB 향상된 결과를 얻었다.

• Natural Product Sciences
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• v.15 no.4
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• pp.246-249
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• 2009

Column chromatographic separation of the MeOH extract from the aerial parts of Thesium chinense TURCZ led to the isolation of two norsesquiterpenes (1 - 2), two phenylpropanes (3 - 4) and four flavonoids (5 - 8). Their structures were determined by spectroscopic means to be 5,6-epoxy-3-hydroxy-7-megastigmen-9-ene (1), (-)-loliolide (2), methyl-p-hydroxycinnamate (3), methyl caffeate (4), kaempferol (5), kaempferol-3-O-${\beta}$-Dglucopyranoside (6), kaepmferol-3,7-di-O-${\beta}$-D-glucopyranoside (7) and kaempferol-3-O-${\beta}$-D-glucopyranoside-6''-(3-hydroxy-3-methylglutarate) (8). Compounds 1 - 4, 7 and 8 were first isolated from this source. The isolated compounds were evaluated for their cytotoxicty in vitro using the sulforhodamin B bioassay (SRB).

• Journal of the Korean Society of Safety
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• v.12 no.3
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• pp.97-105
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• 1997

Mo-99(Molybdenum) is the only source of Tc-99m(Technetium) which is most frequently used in nuclear medical diagnostics and the demand is on the increase recently. Separation and refining of Mo-99 was investigated by adsorption and desorption on alumina. At pH=0.63, adsorption isotherm of Mo was fitted by Redlich ＆ Peterson equation using the adsorption experimental data. It was found that the pore diffusion model ($D_p=1.4{\times}10^{-6}cm^2/s, K_f/=0.4 cm/s$) agreed well with batch adsorption experimental data. RTDs(Residence Time Distributions ) were measured and axial dispersion coefficients were obtained in the fixed bed absorber according to the changes of the flow rate using 0.05% -NaCl. From the adsorption experimental data, it was shown that the behavior of breakthroughs depended on flow rate. Mo recovery yield was increased as adsorption flow rate was increased and desorption flow rate was decreased.

• Ocean Systems Engineering
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• v.2 no.1
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• pp.33-47
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• 2012

This study revealed the behavior of droplets formed through leak process in deep water. There was a threshold depth named the universal attraction depth (UAD). Droplets rose upward in the zone below the UAD called the rising zone, and settled down in the zone above the UAD called the settling zone. Three mass loss modes were identified and formulated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. The first two were active for the settling zone, and all the three were effective for the rising zone. In consequence, the life time of the droplets in the rising zone was far shorter than that of the droplets in the settling zone.

• Journal of The Korean Astronomical Society
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• v.42 no.3
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• pp.33-37
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• 2009

We propose a diagnostic that can resolve the planet/binary degeneracy of central perturbations in caustic-crossing high-magnification microlensing events. The diagnostic is based on the difference in the morphology of perturbation inside the central caustics induced by a planet and a wide-separation binary companion. We find that the contours of excess exhibit a concentric circular pattern around the caustic center for the binary-lensing case, while the contours are elongated or off-centered for the planetary case. This difference results in the distinctive features of the individual lens populations in the residual of the trough region between the two peaks of the caustic crossings, where the shape of the residual is symmetric for binary lensing while it tends to be asymmetric for planetary lensing. We determine the ranges of the planetary parameters for which the proposed diagnostic can be used. The diagnostic is complementary to previously proposed diagnostics in the sense that it is applicable to caustic-crossing events with small finite-source effect.

• Journal of information and communication convergence engineering
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• v.10 no.2
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• pp.175-180
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• 2012

This paper presents a blind watermark detection scheme for an additive watermark embedding model. The proposed estimation-correlation-based watermark detector first estimates the embedded watermark by exploiting non-Gaussian of the real-world audio signal and the mutual independence between the host-signal and the embedded watermark and then a correlation-based detector is used to determine the presence or the absence of the watermark. For watermark estimation, blind source separation (BSS) based on independent component analysis (ICA) is used. Low watermark-to-signal ratio (WSR) is one of the limitations of blind detection with the additive embedding model. The proposed detector uses two-stage processing to improve the WSR at the blind detector; the first stage removes the audio spectrum from the watermarked audio signal using linear predictive (LP) filtering and the second stage uses the resulting residue from the LP filtering stage to estimate the embedded watermark using BSS based on ICA. Simulation results show that the proposed detector performs significantly better than existing estimation-correlationbased detection schemes.