• Title/Summary/Keyword: Soot Formation and Oxidation

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Visualization of Diesel and GTL Spray Combustion and Soot Formation in a Rapid Charging Combustion Vessel with Shadowgraph Method

  • Kim, Ki-Seong;Azimov, Ulugbek;Lee, Yong-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.7
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    • pp.1019-1029
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    • 2008
  • In this study, visual investigation of sprays and flames has been performed and soot formation in Diesel and GTL fuels has been compared in a specially designed Rapid Charging Combustion Vessel (RCCV) under various ambient gas $O_2$ concentrations and two injection pressures. It has been concluded that soot in the mixing-controlled combustion of Diesel and GTL fuels has similar tendency to be formed in the leading portion of the jet boundaries. Auto-ignition delay for GTL fuel is shorter than that for diesel fuel. The temporal and special variation of soot concentration in the diesel flame jets at various $O_2$ concentrations was correlated with the heat release rate. Soot concentration appears in the regions when diffusion combustion starts, and its concentration reaches maximum at the peak of heat release curve and then decreases due to oxidation. Visualization by shadowgraph method showed that soot decreases with lower $O_2$ concentration, and higher injection pressure.

Numerical Study of PAH Formation Characteristics in Laminar Non-Premixed C2H4 Jet Flames (층류 비예혼합 C2H4 제트 화염장에서의 PAH 생성특성 해석)

  • Kim, Taehoon;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.133-134
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    • 2014
  • The full transport equation approach for laminar non-premixed flame with detailed chemistry, soot and radiation has an advantage in accuracy and describing for emission pathway, but this approach requires the excessive computational cost especially for a higher-order hydrocarbon fuel flames. On the other hand, the standard flamelet model has an efficiency and accuracy for non-premixed flame, though this model is not suitable for simulating slow processor like soot and radiation in laminar non-premixed flame situation. To overcome this limitation, modified transient flamelet model is developed which coupled with two-equation soot model involved in soot formation and evolution mechanism such as nucleation, surface growth, oxidation and agglomeration.

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Predictions on the Flame Structure and Soot Distribution in the Coflowing Laminar Diffusion Flames (동층류 축대칭 확산화염내의 화염구조 및 매연입자 분포의 예측)

  • 이정기;김상수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.8
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    • pp.1583-1594
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    • 1992
  • A numerical calculation on the flame structure and soot particle distribution in a coannular laminar diffusion flame was performed. Flame analysis model utilized basically flame sheet concepts, Shvab-Zel'dovich assumption, and one step overall irreversible reaction. It was also considered the variation of thermodynamics and transport properties, and the stagnation enthalpy was used for solving temperature field. Radiation was taken into account, since it has been found to be important in determining the flame temperature in sooty flames. For soot particle analysis, we adopted the coagulation, suface condensation, and the oxidation model in addition to tesner's two-step formation model. Equations for primary soot particle excluding the agglomeration process were solved. Based on the results, the regions of soot generation, growth, and oxidation in the flame have been observed and radiation strongly influenced flame temperature and soot distribution.

Soot Formation and Combustion in Turbulent Flames (난류 화염 내에서의 매연 입자의 생성및 재연소)

  • 정종수;신현동;이춘식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.962-978
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    • 1989
  • A new model of the combustion rates of soot particle in turbulent flames has been suggested. This model applies the combustion rate of soot particles in laminar flames and uses local time-averaged quantities in order to consider the effect of the chemical reaction on the soot combustion in turbulent flames. The proposed rate equation has been tested for two propane-air turbulent round-jet diffusion flames and gives better predictions for the soot concentration field of two flames than the model previously used, especially in low temperature regions. A modified Monte carlo Method for analyzing radiative heat transfer of a flame also has been suggested and tested, which reveals good results.

Soot Generation in a Coaxial Laminar Diffusion Flame (동축 층류 확산화염에서의 그을음 생성)

  • Shim, Sung-Hoon;Shin, Hyun-Dong
    • Journal of the Korean Society of Combustion
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    • v.7 no.3
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    • pp.9-15
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    • 2002
  • Soot generation by combustion process has been investigated with objective of understanding of chemical reaction responsible for its formation in a coaxial laminar propane jet diffusion flame. For the direct photos, as the coflowing air flow rate is reduced, the area of soot luminous zone increases at first, then becomes smaller and smaller, and even disappears. The aspects of soot deposition can be acquired by using nine $15{\mu}m$ thin SiC fibers are positioned horizontally across the flame. Deposited soots on SiC fibers show the soot inception point and growth and soot oxidation zone in a typical propane diffusion. Soot is not generated anymore in a oxidizer deficient conditions of near-extinction and flame is fully occupied by transparent blue flame. It suggests that nonsooting pyroligneous blue reaction is being dominant in a oxidizer deficient ambience. In comparison with luminosities of SiC fibers and flame itself, indirect evidence is found that the process of soot nucleation and growth is endothermic reaction. It is remarkable that there exists two adjacent regions to have antithesis characteristics; one is exothermic reaction of blue flame and another endothermic reaction zone of soot formation.

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Nano-Soot Particle Formation in Inverse Diffusion Flames (인버스 확산화염에서의 나노 수트 입자 생성)

  • Lee, Eui-Ju;Shin, Hyun-Joon;Oh, Kwang-Chul;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.19-26
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    • 2003
  • Experimental measurements of flame structure and soot characteristics were performed for ethene inverse diffusion flames (IDF). IDF has been considered as the excellent flow field to study the incipient soot because soot particle do not experience the oxidation process. In this study, LIF image clarified the reaction zone of IDF with OH signal and PAH distribution. laser light scattering technique also identified the being of soot particle. To address the degree of soot maturing, C/H ratio and morphology of soot sample were investigated. From these measurements, the effect of flow residence time and temperature on soot inception could be suggested, and more details on soot characteristic in the IDF was determined according to fuel dilution and flame condition. The fuel dilution results in a decrease of temperature and enhancement of residence time, but the critical dilution mole fraction is existed for temperature not to effect on soot growth. Also, the soot inception evolved on the specific temperature and its morphology are independent of the fuel dilution ratio of fuel.

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Numerical studies for combustion processes and emissions in the DI diesel engines using EGR (EGR을 사용하는 직접분사식 디젤엔진의 연소과정 및 매연가스 배출특성에 대한 수치해석)

  • Kwon, Y.D.;Lee, J. C.;Kim, Y. M.;Kim, S. W.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.5
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    • pp.659-669
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    • 1997
  • The effects of exhaust gas recirculation on diesel engine combustion and soot/NOx emissions are numerically studied. The primary and secondary atomization is modelled using the wave instability breakup model. Autoignition of a diesel spray is modelled using the Shell ignition model. Soot formation is kinetically controlled and soot oxidation is represented by a model which account for surface chemistry. The NOx formation is based on the extended Zeldovich NOx model. Effects of injection timing and concentration of $O_{2}$ and CO$_{2}$ on the pollutant formation and the combustion process are discussed in detail.

A study on the characteristics of soots formation in spray flame for DI diesel engine (직접분사식 디젤기관의 화염 속에서 생성되는 그을음의 특성에 관한 연구)

  • 라진홍;안수길
    • Journal of Ocean Engineering and Technology
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    • v.10 no.4
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    • pp.128-140
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    • 1996
  • To analyze a formation process of the soots in spray flame in the combustion chamber, an optically accessible DI Diesel engine was used for visualization. The images of the flames and soots were visualiaed with high speed camera by Schlieren method and Light extinction method. The spray flame and soot images on the films were analyzed at the various engine operating conditions. Soot distributed widely in spray flame and its concentration was about $100g/m^3$ at the position close by nozzle tip of spray flame region, however it decreased below $20g/m^3$ at the corner of combustion chamber due to soot oxidation.

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Measurments of 2-D Image Soot Distribution for Different Piston-Shapes of a DI Diesel Engine Using Elastic Scattering, Laser-Induced Incandescence and Flame Luminosity (레이저 탄성산란법, 여기적열법, 자발광을 이용한 직분식 디젤엔진의 피스톤 형상에 따른 2차원 soot 분포 측정)

  • Noh, S.M.;Won, Y.H.;Park, J.G.;Choi, I.Y.;Chun, K.M.
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.183-193
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    • 2000
  • Soot formation and oxidation is closely related to the combustion phenomena inside a diesel engine. Laser-based diagnostics provide a means for improving our understanding of diesel combustion, because they have highly temporal and spatial ability. To understand the soot behavior we did preliminary study by taking flame luminosity photographs and 2-D images of soot distribution using Laser Elastic Scattering(LIS) and Laser-Induced Incandescence(LII). From the data we found that soot concentration was high in the bowl and disappeared from the central region in the late combustion stage and that soot exists in the flame using luminosity, LIS and LII.

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Measurments of 2-D Image Soot Distribution in Late Combustion Stage Using Elastic Scattering, Laser-Induced Incandescence and Flame Luminosity (레이저 탄성산란법, 여기적열법, 자발광을 이용한 가시화 디젤엔진의 후기연소의 2차원 soot 분포 측정)

  • Noh, S.M.;Won, Y.H.;Park, J.G.;Choi, I.Y.;Chun, K.M.
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.162-167
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    • 2000
  • Soot formation and oxidation is closely related to the combustion phenomena inside a diesel engine. Laser-based diagnostics provide a means for improving our understanding of diesel combustion, because they have highly temporal and spatial ability. To understand the soot behavior we did preliminary study by taking flame luminosity photographs and 2-D imaging soot distribution using Laser Elastic Scattering(LIS) and Laser-Induced Incandescence(LII). From the data we found that soot concentration was high in the bowl and disappeared from the central region in the late combustion stage.

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