• Title/Summary/Keyword: Sonochemistry

Search Result 35, Processing Time 0.028 seconds

A Study on the Low Temperature Preparation and the Practical Application of Ferrite Films by New Techniques. (신 기술에 의한 페라이트 막의 저온 제작과 그 응용에 관한 연구)

  • 최동진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.11 no.8
    • /
    • pp.658-663
    • /
    • 1998
  • Ferrite plating enables were grown by ferrite by plating method in solution at low temperature(<10$0^{\circ}C$). This faciltates the fabrication of new ferrite thin film devices using non- heat-resistant materials(plastic, GaAs ect) as substrates. Combining the ferrite plating with sonochemistry, application of power ultrasonic waves to stimulate chemical reactions, the crystallinity and qualities of films were improved. Modifying the reactions cell and plating conditions further improved the film quality.

  • PDF

Preparation and analysis of nickel-coated alumina by sonochemistry (음향화학법으로 니켈을 코팅한 알루미나의 제조 및 분석)

  • Kim, Jin-Woo;Choi, Sung-Woo;Lee, Chang-Seop
    • Analytical Science and Technology
    • /
    • v.24 no.2
    • /
    • pp.61-68
    • /
    • 2011
  • Ni-coated alumina was prepared by sonochemical method. To increase an efficiency of Ni coating on alumina, amorphous alumina was prepared by sol-gel method and Ni was coated to fine particles of alumina. Ni-coated alumina was prepared from various calcination temperatures ($500^{\circ}C$, $1,000^{\circ}C$), concentrations of Ni solution (0.01 M~0.2 M) and sonochemical reaction times (30 min, 2h). The prepared fine particles were characterized by X-Ray Diffractometer (XRD), Scanning Electron Microscope (SEM), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), and Particle Size Analyzer (PSA). The coating amount of Ni increased, as Ni concentration and ultrasonication time increased. The maximum amount of Ni was coated to fine particles of alumina, when Ni-coated alumina was prepared with 0.1 M concentration of Ni solution for 2 h of sonication time at $1000^{\circ}C$ of calcination temperature. The average particle size was in the range of 835.9 to 986.7 nm.

폴리에스테르 바니시에서 나노 실리카의 분산성 향상과 나노 복합체 에나멜 와이어 개발

  • Kim, Yong-Beom;Kim, Eun-Jin;Kim, Seon-Jae;Hwang, Jong-Seon;Choe, Yong-Seong;Seo, Yeong-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2009.11a
    • /
    • pp.151-151
    • /
    • 2009
  • A enameled wire may have better corona-resistance when its coating material contains nano-sized inorganic particles. However, industrial applications are still limited because an aggregation between nanofillers may happen during coating processes. In this study we use a novel scheme of surface modification with silane on silica nanoparticles using sonochemical reaction where composition and surface density of silanes can be controlled in order to reduce particle-particle attractive interaction. Functionalized nanoparticles are evenly dispersed in the matrix confirmed by SEM and energy dispersive x-ray analysis. Dielectric strength and thermal resistance of the nanocomposite wires are improved while flexibility of the wire maintains.

  • PDF

Magnetic Property of α-Fe2O3 Nanoparticles Prepared by Sonochemistry and Take-off Technique

  • Koo, Y.S.;Yun, B.K.;Jung, J.H.
    • Journal of Magnetics
    • /
    • v.15 no.1
    • /
    • pp.21-24
    • /
    • 2010
  • A new synthetic method for the formation of uniform $\alpha-Fe_2O_3$ nanoparticles was reported and their magnetic properties were investigated. The sonochemical synthesis and the subsequent take-off technique resulted in spherical shaped $\alpha-Fe_2O_3$ nanoparticles with an average diameter of 60 nm. The temperature- and applied magnetic field-dependent magnetization of the $\alpha-Fe_2O_3$ nanoparticles was explained by the sum of two contributions, i.e., the Morin transition and superparamagnetism, because the critical size for superparamagnetism was within the size variation of the nanoparticles.

Decomposition of Chlorofluorocarbon by Sonication (초음파조사에 의한 염화불화탄소(CFC)의 분해)

  • ;;Kyozo Hirai;Yasuaki Maeda
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.19 no.3
    • /
    • pp.307-314
    • /
    • 2003
  • The sonolytic decomposition of chlorofluorocarbon (CFC 113) and several alternative compounds, such as HCFC 225ca, HCFC 225cb, and HFC 134a, in.aqueous solutions was investigated. The CFC 113 with a high volatility and a low solubility in water was rapidly decomposed with increasing sonication time. The decomposition rates were influenced by the initial concentration of CFC 113, the reaction temperature, and the gas/liquid phase volume ratio but were independant of the pH of solution. The predominant pathway of the decomposition of CFC 113 by sonication was not the oxidation by OH radicals but the pyrolysis with high temperature and pressure inside of the cavitation bubble. The pyrolysis in the cavitation bubble resulted in an almost complete mineralization of CFC 113 with the high efficient formation of inorganic products (Cl$^{[-10]}$ , F$^{[-10]}$ , CO, $CO_2$). The addition of zinc powder on the decomposition of CFC 113 by sonication caused an acceleration of the decomposition. Also, HCFCs and HFC 134a were found to be readily decomposed by the pyrolysis induced from the sonication.