• 제목/요약/키워드: Solvent treatment

검색결과 679건 처리시간 0.034초

Carrier Gas Assisted Solvent Vapor Treatment for Surface Nanostructuring of Molecular Thin Films

  • Gong, Hye-Jin;Kim, Jin-Hyun;Yim, Sang-Gyu
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.825-827
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    • 2012
  • In this study, the variation in surface morphology of copper phthalocyanine (CuPc) thin films treated with a flow of acetone vapor assisted by nitrogen carrier gas was investigated. The CuPc nanorods with similar dimensions were well dispersed throughout the whole film surfaces after ~20 min. of treatment. However, the electronic absorption spectra only changed slightly, which indicates that molecular stacking was not altered during treatment. This treating method is simple and more advantageous compared to other solvent treating technologies such as mixed solvent spray treatment using organic solvents and water since it requires relatively mild treating conditions and does not need the presence of water.

LCD 제조공정에서의 폐용매 분리처리를 위한 공정 설계 (Design of Waste Solvent Treatment Process from LCD Manufacturing Process)

  • 윤문규;이문용
    • 청정기술
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    • 제14권4호
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    • pp.275-280
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    • 2008
  • 연구에서는 LCD 제조 공정에서 배출되는 스트리퍼와 디벨로퍼 혼합 폐액(SD폐액)과 스트리퍼 폐수의 효과적 분리 및 처리를 위한 가능한 기술로서 추출공정과 증류공정의 기술적/경제적 타당성을 검토하였다. SD폐액과 스트리퍼 폐수의 추출분리를 위한 용매로 $CHCl_3$가 여러 가지 관점에서 가장 적절한 용매로 확인되었다. 또한 SD폐액 분리 회수를 위한 공정으로서 추출공정과 증류공정의 두 가지 공정에 대하여 정밀 전산모사를 수행한 결과 $CHCl_3$를 이용한 추출분리공정이 단순증류공정보다 6배 정도 에너지 소요비용이 적게 소요됨을 확인할 수 있었다.

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유동성이 우수한 분체특성을 갖는 세파졸린 나트륨 진공동결건조 분말의 제조 (Preparation of Freeze-dried Cefazolin Sodium Bulk Powder with Good Flowability)

  • 조정식;정은주
    • 약학회지
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    • 제42권3호
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    • pp.284-289
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    • 1998
  • The effect of reaction condition, solvent addition and thermal treatment on the bulk density, crystallinity and chemical properties of the freeze-dried cefazohn sodium was inves tigated to prepare the cefazolin sodium powder for injection with good flowability. Crystalline cefazolin sodium powder with high untapped-bulk density (about 45%) and low compressibility (about 40%) was obtained by solvent addition to the very highly concentrated cefazohn sodium solution followed by subsequent thermal treatment before freeze-drying. The desirable solvent was low substituted alcohol such as isopropyl alcohol and anhydrous ethanol with the final concentration of about 9%. The pH adjustment and nitrogen gas purging during the reaction did not give significant effect on the chemical properties such as content, color, transmittance and pH of the reconstituted cefazolin sodium aqueous solution.

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Development of Simple Solvent Treating Methods to Enhance the Efficiency of Small-Molecule Organic Solar Cells

  • Kim, Jin-Hyun;Heo, Il-Su;Gong, Hye-Jin;Yu, Yeon-Gyu;Yim, Sang-Gyu
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.276-276
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    • 2012
  • The interface morphology of organic active layers is known to play a crucial role in the performance of organic photovoltaic (OPV) cells. Especially, a controlled nanostructure with a large contact area between electron donor (D) and acceptor (A) layers is necessary to improve the power conversion efficiency (PCE) of the cells since the short exciton diffusion lengths in organic semiconductors limit the charge (hole and electron) separation before excitons recombination. In this work, we developed simple solvent treating methods to fabricate a nanostructured DA interface and applied them to enhance the PCE of ZnPc/C60 based small molecule OPV cells. Interestingly, it was observed that the solvent treatment on the donor layer prior to the deposition of the acceptor layer resulted in a significant decrease in PCE, which was due to an existence of undesirable voids at the DA interface. Instead, the solvent vapor treatment after the DA bilayer formation led to densely packed and well dispersed DA contacts. Consequently, 3-fold enhancement of PCE as compared to the untreated bilayer cell was accomplished.

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PTT 섬유의 염색성 (2) - 용제 처리한 PTT 섬유의 염색성 및 물성 - (Dyeing Properties of PTT Fiber (2) - Effect of Solvent Treatment on Dyeing and Physical Properties of PTT Fiber -)

  • 이두환;정동석;김호정;이문철
    • 한국염색가공학회지
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    • 제15권4호
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    • pp.8-16
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    • 2003
  • Poly(trimethylene terephthalate)(PTT) fiber was pretreated with organic solvent/water solution of various compositions. The organic solvents used in this experiment were benzyl alcohol, n-buthanol, and N,N-dimethylformamide(DMF). Density of the fibers were investigated as a measure of crystallite region. The dye uptake increased in the order of pretreatment with hot water < untreated < 5% benzyl alcohol < 100% benzyl alcohol < 90% benzyl alcohol; hot water < untreated $\risingdotseq$ 5% butanol < 100% beutanol < 90% butanol; hot water $\risingdotseq$ 5% DMF < untreated < 90% DMF < 100% DMF. The dye uptake increases with increase of crystallinity. It seems likely that the recrystallization process during the pretreatment with organic solvent/water solutions leads to an increase in the microvoid and then a large increase in the dye uptake. Also the dyeing rate increased and the dyeing transition temperature decreased with the pretreatments. The results obtained are corresponds with the plasticization of the fiber structure formed during the pretreatrnent.

Impact of Solvent pH on Direct Immobilization of Lysosome-Related Cell Organelle Extracts on TiO2 for Melanin Treatment

  • Bang, Seung Hyuck;Kim, Pil;Oh, Suk-Jung;Kim, Yang-Hoon;Min, Jiho
    • Journal of Microbiology and Biotechnology
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    • 제25권5호
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    • pp.718-722
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    • 2015
  • Techniques for immobilizing effective enzymes on nanoparticles for stabilization of the activity of free enzymes have been developing as a pharmaceutical field. In this study, we examined the effect of three different pH conditions of phosphate buffer, as a dissolving solvent for lysosomal enzymes, on the direct immobilization of lysosomal enzymes extracted from Hen's egg white and Saccharomyces cerevisiae. Titanium(IV) oxide (TiO2) nanoparticles, which are extensively used in many research fields, were used in this study. The lysosomal enzymes immobilized on TiO2 under each pH condition were evaluated to maintain the specific activity of lysosomal enzymes, so that we can determine the degree of melanin treatment in lysosomal enzymes immobilized on TiO2. We found that the immobilization efficiency and melanin treatment activity in both lysosomal enzymes extracted from Hen's egg white and S. cerevisiae were the highest in an acidic condition of phosphate buffer (pH 4). However, the immobilization efficiency and melanin treatment activity were inversely proportional to the increase in pH under alkaline conditions. In addition, enhanced immobilization efficiency was shown in TiO2 pretreated with a divalent, positively charged ion, Ca2+, and the melanin treatment activity of immobilized lysosomal enzymes on TiO2 pretreated with Ca2+ was also increased. Therefore, this result suggests that the immobilization efficiency and melanin treatment activity of lysosomal enzymes can be enhanced according to the pH conditions of the dissolving solvent.

Solvent-vapor surface treatment induced performance improvement of organic solar cells

  • Kim, Chang-Su;Kang, Jae-Wook;Kim, Do-Geun;Kim, Jong-Kuk
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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    • pp.42-43
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    • 2011
  • Improvement of the photovoltaic efficiency via exposure of organic solar cells to solvent-vapor at room temperature is reported. Carbon disulfide ($CS_2$) vapor treatment can induce Poly(3-hexylthiophene) (P3HT) self-organization into ordered structure leading to enhanced hole transport and light absorption. The power conversion efficiency (PCE) of the organic solar cells can be increased from 0.89 to 1.67% by solvent-vapor treatment.

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감초폴리페놀 추출효율에 있어 열처리, 에탄올 농도, 추출시간 및 용매비율이 미치는 영향 탐색 (Effect of Heat Treatment, Ethanol Content, Extraction Time and Ratio of Solvent on the Efficiency of Polyphenol Extraction from Licorice Root (Glycyrrhizauralensis))

  • 채정일;류경선;서강석;김경훈;오영균;장선식;최창원;최낙진
    • 한국유기농업학회지
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    • 제20권3호
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    • pp.399-409
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    • 2012
  • Effects of pretreatment and extraction conditions on total polyphenol yield from licorice root were investigated using statistical method. For pretreatment, heat treatment at $121^{\circ}C$ for 10 min was applied. Licorice root content in solvent (10, 20, and 30%) ethanol concentration (20, 40, and 60%) and reaction time (1, 2, and 3 h) were used as variables for extraction conditions. Two experiments, with heat treated and no treated licorice, were prepared with same experimental design. Box behnken design was employed and produced a total of 15 trials. Total polyphenol yield from licorice root was not affected by heat treatment. Among variables, licorice content in solvent showed most significant effect regardless of other variables (p<0.05). Finally, optimum conditions for the extraction of total polyphenol from licorice root was detected as following: 10% of licorice in solvent, 52% ethanol as solvent, 2 h of reaction time and non-heat treatment and the extraction yield from optimized condition was 17.6 mg/g licorice root.

상압건조 나노다공성 실리카 에어로젤에 대한 용매의 영향 (Influence of solvent on the nano porous silica aerogels prepared by ambient drying process)

  • 류성욱;김상식;오영제
    • 센서학회지
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    • 제15권5호
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    • pp.371-377
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    • 2006
  • Nano porous, transparent silica aerogels monoliths were prepared under ambient drying (1 atm, $270^{\circ}C$) condition by the combination of sol-gel process and surface modification with subsequent heat treatment. Three kinds of solvent, n-hexane, n-heptane and xylene, were selected in the point view of low surface tension and vapor pressure in order to restrain a formation of cracks during drying. Crack-free silica aerogels with over 93 % of porosity and below $0.14g/cm^3$ of density were obtained by solvent exchange and surface modification under atmosphere condition. Optimum solvent was confirmed n-heptane among these solvents through estimation of FT-IR, TGA, BET and SEM. Modified silica aerogel exhibited a higher porosity and pore size compare to unmodified aerogels. Hydrophobicity was also controled by C-H and H-OH bonding state in the gel structure and heat treatment over $400^{\circ}C$ effects to the hydrophobicity due to oxidation of C-H radicals.

염색모발에서 퍼머시술시 퍼머 1제와 앰플의 혼합사용에 대한 효과 (A Study of Effects with Using After Mixing Ample and Permanent Solvent During Permanent Wave Operating, of Dyod Hairs)

  • 이은경;최정숙
    • 한국패션뷰티학회지
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    • 제3권3호
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    • pp.56-63
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    • 2005
  • In the study of permanent waving method after mixing ample and permanent wave solvent in permanent wave the dyed humans hair are as follows; First, Permanent waving method after mixing ample and permanent wave solvent is that the better effective way in permanent wave the dyed humans hair because permanent waving cycle is constant and hair cuticle is glossy. Second, This study is not interpret in permanent wave dyed humans hair that tensile strength is effect of permanent waving method after mixing ample and permanent wave solvent. A extension degree is effect of permanent waving method after mixing ample and permanent wave solvent use indifferent ample treatment method. Third, Hair cuticle damages are a little permanent waving method after mixing ample and permanent wave solvent in permanent wave dyed humans hair.

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