• Title/Summary/Keyword: Solvent mixture

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In-sacco Degradability of Dietary Combinations Formulated with Naturally Fermented Wheat Straw as Sole Roughage

  • Pannu, M.S.;Kaushal, J.R.;Wadhwa, M.;Bakshi, M.P.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.9
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    • pp.1307-1311
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    • 2002
  • Twelve dietary combinations were prepared using 70 parts of fermented wheat straw (FWS) as the sole roughage supplemented with 30 parts of either the low protein concentrate mixture (Conc.-I), high protein concentrate mixture (conc.-II), maize grains (M), solvent extracted mustard cake (DMC), deoiled rice bran (DRB), uromol bran mixture (UBM), deep stacked poultry litter (DSPL), dried poultry droppings (DPD), M-DMC mixture (50:50), M-UBM mixture (50:50), M-DPD mixture (50:50) or M-UBM-DPD mixture (50:25:25) and evaluated by in-sacco technique. The above dietary combinations were also evaluated by changing the roughage to concentrate ratio to 60:40. The digestion kinetics for DM and CP revealed that FWS:DPD had the highest, whereas, the FWS:M-DMC had the lowest rapidly soluble fraction. The potentially degradable fraction was found to be maximum in FWS:M and minimum in FWS:DPD dietary combinations. The higher degradation rate of FWS:DRB and FWS:UBM combinations was responsible for their significantly (p<0.05) higher effective degradability as compared to other combinations. The highest undegradable fraction noted in FWS:M-UBM-DPD followed by FWS:DMC was responsible for high rumen fill values. The FWS:DRB, FWS:UBM and FWS:DPD combinations had higher potential for DM intake. The dietary combination with higher concentrate level (60:40) was responsible for higher potentially degradable fraction, which was degraded at a faster rate resulting in significantly higher effective degradability as compared to the corresponding dietary combination with low concentrate level (70:30). The low undegradable fraction in the high concentrate diet was responsible for low rumen fill values, which predicted of high potential for DM intake. Out of 24 dietary combinations, FWS with either of UBM, DRB, DMC, Maize, M-DMC or DPD in 70:30 ratio supplemented with minerals and vitamin A in comparison to conventional feeding practice (roughage and concentrate mixture) could be exploited as complete feed for different categories of ruminants.

Measurement and Prediction of Autoignition Temperature of n-Butanol+p-Xylene Mixture (노말부탄올과 파라자일렌 혼합물의 최소자연발화온도 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.1-8
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    • 2016
  • The autoignition temperature (AIT) of a substance is the lowest temperature at which the vapor ignites spontaneously from the heat of the environment. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures in the process. This study measured the AITs of n-butanol+p-xylene mixture by using ASTM E659 apparatus. The AITs of n-butanol and p-xylene which constituted binary system were $340^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs of n-butanol+p-xylene mixture were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation).

Stripping of Fe(III) from the Loaded Mixture of D2EHPA and TBP with Sulfuric Acid Containing Reducing Agents

  • Liu, Yang;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2109-2113
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    • 2014
  • Solvent extraction of Fe(III) from chloride solution by using a mixture of D2EHPA (Di-(2-ethylhexyl)-phosphoric acid) and TBP (Tri-butyl phosphate) and the reductive stripping of Fe(III) from the loaded organic were investigated. Quantitative extraction of Fe(III) from the solution (Fe concentration = 90 g/L) was accomplished in two cross-current extraction stages by using the mixture of D2EHPA and TBP. In order to facilitate the stripping efficiency, a reductive stripping method was employed by using $H_2SO_3$ or $Na_2SO_3$ as a reducing agent. The addition of $H_2SO_4$ into reducing agents led to improvement in the stripping efficiency while high concentration acid would suppress it. Both of the mixtures of $H_2SO_4+H_2SO_3$ and $H_2SO_4+Na_2SO_3$ showed good efficiency for the stripping of Fe(III), while the latter was recommended as the stripping solution based on the economics and experimental condition.

Antimutagenic Effect of the Extract Complex of Korean Anti-thirst Herb Medicines (한방 소갈약 추출물의 혼합물에 의한 항돌연변이 효과)

  • 박건영;정근옥;이경태;최종원;정현주;박희준
    • YAKHAK HOEJI
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    • v.46 no.5
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    • pp.352-357
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    • 2002
  • The three crude drugs of the Kalopanax pictus (Araliaceae) roots (K), Pueraria thunbergiana (Leguminosae) flowers (P), and the Rhus verniciflua (Anacardiaceae) heartwood(R) used for anti-thirst drugs in Oriental herb medicine were extracted with MeOH, respectively, and the successive fractionation of the extract gave EtOAc extract. Certain amount ratios of the three extracts were also prepared to compare the antimutagenicity in Ames test. In N-methyl-N(-nitro-N-nitrosoguanidine (MNNG; 0.4 (g/plate)-induced test, the activities of complex mixture were observed between the highest antimutagenic activity of K extract and the lowest P extract. In aflatoxin (AFB$_1$)-induced test, the EtOAc complex (K : P : R=l : 1 : 3) labeled E-113 decreased the revertants of Salmonella typhimurium TA100 by 95%, which activity were highest among other extracts or complexes mixture used. Fractionation of organic solvent mostly increased the antimutagenicity. These trends were also observed in the antimutagenicity test of the mixture of each active component of kalopanaxsaponin A, tectorigenin and sulfuretin. These results supported that many kinds of anti-thirst herb medicine in the prescription could effectively prevent cancer disease.

Characteristics and Dyeability of Juniperus Chinensis Extracts (향나무 추출 색소의 특성 및 염색성)

  • Nam, Ki Yeon;Lee, Jung Soon
    • Korean Journal of Human Ecology
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    • v.21 no.5
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    • pp.989-1004
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    • 2012
  • The purpose of this study was to investigate the characteristics of the pigment and the dyeability of juniperus chinensis needles, berry, bark and heartwood extracts using distilled water, methanol, normal butanol and ethyl acetate as a solvent. Ultraviolet-visible absorption spectrum bands of the extracts were measured at around 280nm to 320nm in all the solvent extracts. The maximum absorption wavelength was able to determine tannin. All the solvent extracts except for distilled water extracts were able to confirm the presence of chlorophyll. Infrared absorption spectra (FT-IR) of all parts of the extracts showed broad absorption bands of OH due to phenolic-OH, benzene CH peak of phenol chemical structure, ether-based stretching vibration peak and the peak of flavonoid compounds that appeared in all the solvent extracts. The yield of juniper needles and heartwood in distilled water and methanol extraction were effective. Extraction of berry yields in distilled water was also effective. The yield of ethanol extraction from the bark showed better efficiency. As a result of using distilled water for the dye solution, the color of the fabrics dyed with all extracts of the needles and Y series berries generally showed light Y progression with a strong red tinge. By using a mixture of 20% ethanol and 80% distilled water for the dye solution, the color of the fabrics dyed with needles and berry extracts showed Y series dominantly. The color of the fabrics dyed with Bark and heartwood extracts were dominantly R series.

A Statistical-Mechanical Model for Solutions of Monodisperse Micelles (단분산 마이셀 용액의 통계 역학적 모델)

  • Kang, Kye-Hong;Lim, Kyung-Hee
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.824-832
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    • 2008
  • micellar solution which is comprised of surfactant monomers, monodisperse micelles, and solvent(water) is studied from a statistical-mechanical point of view. The model examined in this article is for the ideal mixture of monomers, micelles, and solvent with the dielectric constant identical to that of solvent, which is an assumption common to continuum models. The model also reflects interactions between monomer and solvent molecule, and also between micelle and solvent molecule. The statistical-mechanical model under consideration yields ln $X_{CMC}=A+BT+C/T+D{\ln}T$ with $X_{CMC}$ being critical mcielle concentration (in mole fraction), being temperature, and A, B, C, D being constants which depend on the properties of the surfactant molecules. The statistical-mechanical model discussed in this article provides a theoretical basis on the thermal dependence of critical micelle concentration

Preparation of Solvent-Free Low Foaming Scouring Agents and Their Scouring Characteristics (무용제형 저기포성 정련제의 제조 및 정련특성)

  • Park, Hong-Soo;Ahn, Sung-Hwan;Shim, Il-Woo;Jo, Hye-Jin;Hahm, Hyun-Sik;Kim, Yeoung-Chan;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.37-44
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    • 2006
  • Solvent-free low foaming scouring agents (LFSC) were prepared by blending of 2-ethylhexylaminoethyl sulfate (2-EHAS), POE(10) octadecylbenzyl- ammonium chloride (POBAC) and Sedlan FF-200 (FF-200). As the results of several tests, 2-EHAS/POBAC/FF-200/water (8g/12g/20g/60g) mixture (LFSC-5) showed good cleaning power, penetrating ability and stability to alkali, and gave less problem in water pollution. The foaming power of LFSC-5 measured by Ross and Miles method was 8mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 18mm at $80^{\circ}C$. As a result, LFSC-5 proved a good low foaming scouring agent for fiber.

An Environment-Friendly Surface Pretreatment of ABS Plastic for Electroless Plating Using Chemical Foaming Agents

  • Kang, Dong-Ho;Choi, Jin-Chul;Choi, Jin-Moon;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.4
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    • pp.174-177
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    • 2010
  • We have developed an environment-friendly etching process, an alternative to the dichromic acid etching process, as a pretreatment of acrylonitrile-butadiene-styrene (ABS) plastic for electroless plating. In order to plate ABS plastic in an electroless way, there should be fine holes on the surface of the ABS plastic to enhance mechanically the adhesion strength between the plastic surface and the plate. To make these holes, the surface was coated uniformly with dispersed chemical foaming agents in a mixture of environmentally friendly dispersant and solvent by the methods of dipping or direct application. The solvent seeps into just below the surface and distributes the chemical foaming agents uniformly beneath the surface. After drying off the surface, the surface was heated at a temperature well below the glass transition temperature of ABS plastic. By pyrolysis, the chemical foaming agents made fine holes on the surface. In order to discover optimum conditions for the formation of fine holes, the mixing ratio of the solvent, the dispersant and the chemical foaming agent were controlled. After the etching process, the surface was plated with nickel. We tested the adhesion strength between the ABS plastic and nickel plate by the cross-cutting method. The surface morphologies of the ABS plastic before and after the etching process were observed by means of a scanning electron microscope.

A Study on the Regeneration Energy Reduction through the Process Improvement of the Carbon Dioxide Capture Process (상전이 현상을 이용한 이산화탄소 포집공정개선 및 재생에너지 절감에 대한 연구)

  • Kim, Yu-Mi;Kim, Dong-Sun;Cho, Jung-Ho
    • Clean Technology
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    • v.18 no.2
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    • pp.221-225
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    • 2012
  • In this study, simulation works for a carbon dioxide capture process using solvent absorption method have been performed for decrease of regeneration energy in applying phase transition of liquid solvent. When carbon dioxide is dissolved in 30 wt% MEA solvent, liquid mixture divided into two phase according to mole loading of dissolved carbon dioxide. Using this phenomenon, we can decrease regeneration energy about 61% than primary absorber column-stripper column process.

Alcohol-Amine Synergism in the Organic Solvent Extraction of Tungsten (텅스텐의 아민용매 추출과정에서의 알코올의 작용)

  • Lee Hoosung;Uh, Young Sun;Sohn, Youn Soo
    • Journal of the Korean Chemical Society
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    • v.16 no.6
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    • pp.361-368
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    • 1972
  • The organic solvent mixture of 5 % trioctylamine and 5 % n-octyl alcohol in n-hexane could be loaded with tungsten to 62 g $WO_3$/1 whereas the amine alone could be loaded only to 37 g $WO_3$/1. Molecular interaction between amine and tungstate ion during the solvent extraction process and the synergistic effect of alcohol in enhancing the solubility of the amine-tungstate complex have been studied by NMR spectroscopy. Tungsten has been shown to be extracted as a polymeric tungstate ion into the organic phase to form a trioctyl ammonium polytungstate salt, which was more stabilized in the hydrocarbon medium by interacting with alcohol via hydrogen bonding between the tungstate ion and alcohol.

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