• Title/Summary/Keyword: Solution-based process

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Transformation of PEO coatings from crater to cluster-based structure with increase in DC voltage and the role of ZrO2nanoparticles

  • Rehman, Zeeshan Ur;Shin, Seong Hun;Koo, Bon Heun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.111-111
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    • 2016
  • Two step PEO ceramic coatings were formed on AZ91 magnesium alloy in $ZrO_2$ nanoparticles and $K_2ZrF_6$ based colloidal electrolyte solution for various voltages. Surface and layers tructure of the coatings was analyzed using SEM (ScanningElectronMicroscope). Structure analysis revealed that surface of the coating was transferred from individual pancake or craters-based structure to cluster-based structure with increasing the voltage of the secondary step process. Further, it was confirmed that the cluster zone was richin Zr-based complexes and formed due to high intensives parks. Increase in the Zr contents as discovered from the EDS analysis confirmed the rise in amorphous form of the Zr-based species, which justified the results of XRD where no increase in the intensity of Zr-based species was observed with increase in voltage. Potentiodynamic polarizariotion and impedance spectroscopy techniques were used to evaluate the corrosion performance of the coatings. The highest corrosion resistance was found for coatings prepared at 240V. The same specimen was found having highest and uniform vickers hardness ~1070.5 HV. The superior mechanical and electrochemical properties of the said coating can be attributed to the defect-less microstructure and the optimal role of $ZrO_2$ nanoparticles in the secondary PEO process at 240V.

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Variation of the CO2 Capture Reaction by Ammonia Solution with Temperature (온도에 따른 암모니아 용액에 의한 CO2 포집 반응의 변화 양상)

  • Kim, Soo-Yeon;Choi, Ye-Seul;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.6
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    • pp.896-904
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    • 2011
  • The features of the capture reaction of $CO_2$ by ammonia solution have been investigated along with the effect of temperature on the reaction based upon computer program-utilizing calculation and thermodynamic estimation. The stable region of $CO{_3}^{2-}$ was observed to increase with temperature and the change of the stable region of $CO{_3}^{2-}$ with temperature was greater than the temperature variation of the stable region of other carbonate species. The distribution diagram for $NH_4{^+}-NH_3$ system was constructed and the rise of temperature resulted in the decrease of the stability of $NH_4{^+}$ ion, which was thought to be due to the endothermic nature of its acidic dissociation. Considering the introduction of $Ca^{2+}$ ion in the carbon capture reaction by $NH_4{^+}$, the temperature was observed to be important in the determination of the order of reaction between carbonate ion and these cations. The removal process of $CO_2$ gas by ammonia solution was presumed to occur in open system and the temperature variations of the concentration of carbonate system species along with their total concentration were calculated for the proper control and design of the real process.

Algorithm Based on Cardinality Number of Exact Cover Problem (완전 피복 문제의 원소 수 기반 알고리즘)

  • Sang-Un Lee
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.23 no.2
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    • pp.185-191
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    • 2023
  • To the exact cover problem that remains NP-complete to which no polynomial time algorithm is made available, this paper proposes a linear time algorithm that yields an optimal solution. The proposed algorithm makes use of the set cover problem's major feature which states that "no identical element shall be included in more than one covering set". To satisfy this criterion, the proposed algorithm initially selects a subset with the minimum cardinality and deletes those that contain the cardinality identical to that of the selected subset. This process is repeatedly performed on remaining subsets until the final solution is obtained. Provided that the solution is unattainable, it selects subsets with the maximum cardinality and repeats the same process. The proposed algorithm has not only obtained the optimal solution with ease but also proved its wide applicability on N-queens problems, hence disproving the NP-completeness of the exact cover problem.

Theoretical Study on Optimal Conditions for Absorbent Regeneration in CO2 Absorption Process (이산화탄소 흡수 공정에서 흡수액 최적 재생 조건에 대한 이론적 고찰)

  • Park, Sungyoul
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1002-1007
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    • 2012
  • The considerable portion of energy demand has been satisfied by the combustion of fossil fuel and the consequent $CO_2$ emission was considered as a main cause of global warming. As a technology option for $CO_2$ emission mitigation, absorption process has been used in $CO_2$ capture from large scale emission sources. To set up optimal operating parameters in $CO_2$ absorption and solvent regeneration units are important for the better performance of the whole $CO_2$ absorption plant. Optimal operating parameters are usually selected through a lot of actual operation data. However theoretical approach are also useful because the arbitrary change of process parameters often limited for the stability of process operation. In this paper, a theoretical approach based on vapor-liquid equilibrium was proposed to estimate optimal operating conditions of $CO_2$ absorption process. Two $CO_2$ absorption processes using 12 wt% aqueous $NH_3$ solution and 20 wt% aqueous MEA solution were investigated in this theoretical estimation of optimal operating conditions. The results showed that $CO_2$ loading of rich absorbent should be kept below 0.4 in case of 12 wt% aqueous $NH_3$ solution for $CO_2$ absorption but there was no limitation of $CO_2$ loading in case of 20 wt% aqueous MEA solution for $CO_2$ absorption. The optimal regeneration temperature was determined by theoretical approach based on $CO_2$ loadings of rich and lean absorbent, which determined to satisfy the amount of absorbed $CO_2$. The amount of heating medium at optimal regeneration temperature is also determined to meet the difference of $CO_2$ loading between rich and lean absorbent. It could be confirmed that the theoretical approach, which accurately estimate the optimal regeneration conditions of lab scale $CO_2$ absorption using 12 wt% aqueous $NH_3$ solution could estimate those of 20 wt% aqueous MEA solution and could be used for the design and operation of $CO_2$ absorption process using chemical absorbent.

Maskless Fabrication of the Silicon Stamper for PDMS Nano/Micro Channel (나노/마이크로 PDMS 채널 제작을 위한 마스크리스 실리콘 스템퍼 제작 및 레오로지 성형으로의 응용)

  • 윤성원;강충길
    • Transactions of Materials Processing
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    • v.13 no.4
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    • pp.326-333
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    • 2004
  • The nanoprobe based on lithography, mainly represented by SPM based technologies, has been recognized as a potential application to fabricate the surface nanosctructures because of its operational versatility and simplicity. However, nanoprobe based on lithography itself is not suitable for mass production because it is time a consuming method and not economical for commercial applications. One solution is to fabricate a mold that will be used for mass production processes such as nanoimprint, PDMS casting, and others. The objective of this study is to fabricate the silicon stamper for PDMS casting process by a mastless fabrication technique using the combination of nano/micro machining by Nanoindenter XP and KOH wet etching. Effect of the Berkovich tip alignment on the deformation was investigated. Grooves were machined on a silicon surface, which has native oxide on it, by constant load scratch (CLS), and they were etched in KOH solutions to investigate chemical characteristics of the machined silicon surface. After the etching process, the convex structures was made because of the etch mask effect of the mechanically affected layer generated by nanoscratch. On the basis of this fact, some line patterns with convex structures were fabricated. Achieved groove and convex structures were used as a stamper for PDMS casting process.

The Classification of e-Business Model for Successful e-Business Implementation based on the Strategic Consideration (e-비즈니스의 성공적인 실행을 위한 비즈니스 모형의 분류 유형에 관한 연구)

  • 신호균;김종천
    • Proceedings of the Korea Association of Information Systems Conference
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    • 2001.12a
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    • pp.438-450
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    • 2001
  • This study is to classify the typology of e-business model based on the practical strategic model for successful e-business implementation. For that purpose, we review the conceptual framework of e-business and collected the data from 127 companies implementing e-business. The study is conducted in three phases as follows. First, six factors consisted of 22 items are derived through factor analysis. Second, Cluster analysis is employed to group the firms into different strategic patterns. A five-cluster solution is found to maximize the distances between cluster means across the six factor patterns. The models are named as 'ascendancy and convergence', 'expansion and moderate price', 'expansion and improvement of quality', 'ascendancy and process', and 'improvement of quality' respectively. Third, ANOVA is used to examine the impact on the performance differences attributable to the models. The results of the study are; (1) the 'ascendancy and process', 'expansion and improvement of quality' and 'expansion and moderate price' models were associated with significantly higher performance levels than the 'improvement of quality' model, and (2) the hybrid strategies are needed to implement e-business successfully based on the 'ascendancy and process' model.

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Fabrication of YBCO Coated Conductor by oxide-precursor-based MOD process employing IBAD substrate (IBAD 기판을 적용한 산화물 전구체 MOD 공정에 의한 YBCO Coated Conductor의 제조)

  • Kim Y. K.;Yoo J. M.;Ko J. W.;Heo S. Y.;Hong G. W.;Lee H. G.;Chung H. S.
    • Progress in Superconductivity
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    • v.6 no.2
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    • pp.142-145
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    • 2005
  • YBCO coated conductors have been fabricated with a newly developed oxide-precursor-based MOD process. The precursor solution was synthesized with low cost YBCO powders as starting materials and YBCO coated conductors have been deposited on IBAD substrate ($CeO_2$/IBAD-YSZ/SS). YBCO coated conductor prepared by dip coating shows transport $I_c$ of 15A/cm-w at 77 K. Microstructural and crystallographic analyses indicate that YBCO layer was grown in epitaxy with substrate and exhibited well-developed dense microstructure. Also discussed are processing and analysis of YBCO coated conductor by slot-die web coating method. It was shown that this oxide-based MOD process provides a low cost route to coated conductor with high $J_c$.

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The Security Constrained Economic Dispatch with Line Flow Constraints using the Multi PSO Algorithm Based on the PC Cluster System (PC 클러스터 기반의 Multi-HPSO를 이용한 안전도 제약의 경제급전)

  • Jang, Se-Hwan;Kim, Jin-Ho;Park, Jong-Bae;Park, June-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.9
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    • pp.1658-1666
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    • 2009
  • This paper proposes an approach of Mult_HPSO based on the PC cluster system to reduce or remove the stagnation on an early convergence effect of PSO, reduce an execution time and improve a search ability on an optimal solution. Hybrid PSO(HPSO) is combines the PSO(Particle Swarm Optimization) with the mutation of conventional GA(Genetic Algorithm). The conventional PSO has operated a search process in a single swarm. However, Multi_PSO operates a search process through multiple swarms, which increments diversity of expected solutions and reduces the execution time. Multiple Swarms are composed of unsynchronized PC clusters. We apply to SCED(security constrained economic dispatch) problem, a nonlinear optimization problem, which considers line flow constraints and N-1 line contingency constraints. To consider N-1 line contingency in power system, we have chosen critical line contingency through a process of Screening and Selection based on PI(performace Index). We have applied to IEEE 118 bus system for verifying a usefulness of the proposed approaches.

Version Management of Business Processes Managed by BPM (BPM에서 관리되는 업무 프로세스의 버전관리)

  • Cho, Eunmi;Bae, Hyerim
    • Journal of Korean Institute of Industrial Engineers
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    • v.32 no.2
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    • pp.126-132
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    • 2006
  • Recently, business environments have been changing quickly. To establish competitive advantage, most enterprises have been using information systems such as Enterprise Resource Planning (ERP), Supply Chain Management (SCM) and Customer Relationship Management (CRM). Many consider Business Process Management (BPM) a new innovative solution for enterprise-wide processes. As the BPM system is used more widely and matures, new techniques and functions will be developed by commercial vendors. However, they mainly focus on correctly executing process models, and user convenience has not been considered. In this paper, we have developed a new method of designing business processes, which provides users with an easy modeling interface. The method is based on version management. Version management of a process enables a history of the process model to be recorded. In order to prevent wasted storage, not all of the process versions are stored. An initial version and changes to each process are stored by automatically detecting changes. Our method enhances the convenience of the modeling business processes and thus helps the process designer. A prototype system is presented to verify the effectiveness of our method.

Numerical Experimentation of a 2-D B-Spline Higher Order Panel Method (2차원 B-스플라인 기저 고차패널법의 수치실험)

  • Chung-Ho Cho;Chang-Sup Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.37 no.3
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    • pp.27-36
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    • 2000
  • A higher order panel method based on B-spline representation for both the geometry and the velocity potential is developed for the solution of the flow around two-dimensional lifting bodies. Unlike Lee/Kerwin, who placed multiple control points on each panel and solved the overdetermined system of equation by the least square approach, the present method places only as many number of control points as required by the unknowns of the problem. Especially, a null pressure jump Kutta condition at the trailing edge is found to be effective in stabilizing the solution process and in predicting the correct solution. The new approach, is validated to be accurate through comparison with the analytic solution for a 2-D airfoil and to be less time-consuming due to fewer number of panels required than that used in Lee/Kerwin.

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